4-Methoxycarbonylmethoxy-zimtsaeuremethylester | 100798-34-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: 4-Methoxycarbonylmethoxy-zimtsaeuremethylester
• 英文别名: 3-(4-methoxycarbonylmethoxy-phenyl)acrylic acid methyl ester；Methyl 3-[4-(2-methoxy-2-oxoethoxy)phenyl]prop-2-enoate
• CAS: 100798-34-3
• 化学式: C₁₃H₁₄O₅
• 分子量: 250.251
• InChiKey: CQRWZEPPEKWVQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4-羟基肉桂酸甲酯 、 氯乙酸甲酯 在 disodium hydrogenphosphate 、 potassium carbonate 、 sodium iodide 作用下， 以 丙酮 为溶剂， 反应 8.0h， 以71.4%的产率得到4-Methoxycarbonylmethoxy-zimtsaeuremethylester
  参考文献：
  名称：

  FUNCTIONALIZED PHENOLIC COMPOUNDS AND POLYMERS THEREFROM

  摘要：

  本发明涉及公式I的化合物，这些化合物是官能化酚类化合物，以及由它们形成的聚合物。从官能化酚类化合物形成的聚合物预计具有可控的降解特性，使它们能够在所需的时间范围内释放活性成分。这些聚合物还预计在各种医疗应用中有用。

  公开号：

  US20090170927A1

文献信息

• Hydroxylamine esters as polymerization initiators
  申请人：——

  公开号：US20030216494A1

  公开（公告）日：2003-11-20

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  该发明涉及新型环状和开链羟胺酯以及包括这些羟胺酯和乙烯基不饱和单体或寡聚物的可聚合组合物。该发明还涉及用作聚合引发剂以及用于控制聚丙烯降解和实现聚乙烯分子量控制增加的已知羟胺酯，所述羟胺酯来自HALS化合物和新颖羟胺酯的组合。
• POLYMER STABILIZER
  申请人：KIMURA Yoshikazu

  公开号：US20100179253A1

  公开（公告）日：2010-07-15

  A polymer stabilizer comprising the following alkoxy compound: the alkoxy compound: a compound obtained by alkoxylating at least one hydroxyl group contained in a compound of the following formula (1) containing one formyl group or carbonyl group and (n− 1 ) hydroxyl groups in the molecule with an alkyl group having 1 to 12 carbon atoms: C n H 2n O n (1) (wherein, n represents an integer of 3 or more).

  一种聚合物稳定剂，包含以下烷氧基化合物：所述烷氧基化合物是通过将含有以下通式（1）中的一个甲酰基或羰基以及分子中（n-1）个羟基的化合物中的至少一个羟基进行烷氧基化而得到的化合物，其中烷基团含有1至12个碳原子：CnH2nOn（1）（其中，n代表3或以上的整数）。
• Polyamine Derivative and Polyol Derivative
  申请人：Mita Naruyoshi

  公开号：US20080230743A1

  公开（公告）日：2008-09-25

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organic material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is a hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括上述任何一种化合物的有机材料稳定剂；一种稳定有机材料的方法；以及稳定的有机材料。通式（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子，烷基，烷氧基或酰基；R4是氢原子或烷基；n是3至16的整数）对于稳定有机材料免受光，热，氧，臭氧和电磁波（如X射线和γ射线）的损害非常有效。
• Process for the controlled increase in the molecular weight of polyethylenes
  申请人：Roth Michael

  公开号：US20080146740A1

  公开（公告）日：2008-06-19

  The invention relates to hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer and methods for achieving a controlled increase in the molecular weight of polyethylene.

  本发明涉及到羟胺酯和聚合物组成物，包括这些羟胺酯和乙烯基不饱和单体或寡聚物，以及实现聚乙烯分子量控制增加的方法。
• POLYAMINE DERIVATIVE AND POLYOL DERIVATIVE
  申请人：MITA NARUYOSHI

  公开号：US20120053270A1

  公开（公告）日：2012-03-01

  A novel polyamine derivative, or polyol derivative, having a piperidylaminotriazine skeleton; salts of such compounds; a process for producing them; an organic material stabilizer comprising any of such compounds; a method of stabilizing an organic material; and a stabilized organinc material. Compounds of the general formula: (1) (wherein X is N(R 4 ) or an oxygen atom; R 1 is an n-valent hydrocarbon group; R 2 is an hydrogen atom or an alkyl; R 3 is a hydrogen atom, an alkyl, an alkoxy or an acyl; R 4 is a hydrogen atom or an alkyl; and n is an integer of 3 to 16) are effective in the stabilization of an organic material against deterioration by light, heat, oxygen, ozone and electromagnetic waves, such as X-rays and γ-rays.

  一种新型的聚胺衍生物或聚醇衍生物，具有哌啶基氨基三嗪骨架；这些化合物的盐；一种生产它们的过程；包括任何此类化合物的有机材料稳定剂；一种稳定有机材料的方法；以及一种稳定的有机材料。通式为（1）的化合物：（其中X是N（R4）或氧原子；R1是n价碳氢基团；R2是氢原子或烷基；R3是氢原子、烷基、烷氧基或酰基；R4是氢原子或烷基；n是3到16的整数）对于通过光、热、氧、臭氧和电磁波（如X射线和γ射线）恶化的有机材料的稳定化是有效的。