2,2-二甲基-3-(2-甲基-1-丙烯-1-基)环丙烷甲酰氯 | 188023-87-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 2,2-二甲基-3-(2-甲基-1-丙烯-1-基)环丙烷甲酰氯
• 英文名称: (1R)-trans-2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid chloride
• 英文别名: (1R,3-trans/cis)-chrysanthemic acid chloride；(1R)-trans-2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarbonyl chloride；(1R)-trans-2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic chloride；(1R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carbonyl chloride
• CAS: 188023-87-2
• 化学式: C₁₀H₁₅ClO
• 分子量: 186.681
• InChiKey: VNTCVNLNEOVBEE-MQWKRIRWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,3,5,6-四氟-4-甲基苯甲醇 、 2,2-二甲基-3-(2-甲基-1-丙烯-1-基)环丙烷甲酰氯 在 吡啶 作用下， 以 四氢呋喃 、 ice-water 、 乙酸乙酯 为溶剂， 以87%的产率得到profluthrin
  参考文献：
  名称：

  Ester compounds

  摘要：

  以下化学式所示的酯化合物：其中R1代表氢原子、卤素原子、C1-C3烷基（可选地被卤素原子取代）、C2-C3烯基（可选地被卤素原子取代）、C1-C3烷氧基（可选地被卤素原子取代）、C1-C3烷硫基（可选地被卤素原子取代）或（C1-C3烷氧基）甲基（可选地被卤素原子取代）、n表示1至4的整数，X表示氢原子或C1-C3烷基，具有优异的杀虫活性。

  公开号：

  US06225495B1

文献信息

• Ester compound, active agent for controlling noxious insect pests
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05550258A1

  公开（公告）日：1996-08-27

  The present invention provides an ester compound represented by a formula I: ##STR1## wherein R.sub.1 denotes a hydrogen atom or a methyl group; R.sub.2 represents a 1-methyl-2-propenyl group, a 1-methyl-2-propynyl group, a 3,3-dihalogeno-1-methyl-2-propenyl group, or a C.sub.1 -C.sub.1 6 alkyl group which may be substituted with at least one halogen atom; and R.sub.3 represents an acid residue of pyrethroids. The invention also relates to an active agent for controlling noxious insect pests containing the ester compound as an active ingredient, an intermediate for production of the ester compound and a process for producing the intermediate. The ester compound represented by the formula I has good activities for controlling noxious insect pests.

  本发明提供了一种由公式I表示的酯化合物：##STR1## 其中R1表示氢原子或甲基；R2表示1-甲基-2-丙烯基，1-甲基-2-丙炔基，3,3-二卤代-1-甲基-2-丙烯基或C1-C16的烷基，该烷基可被至少一个卤素原子取代；R3表示拟除虫菊酯的酸残基。本发明还涉及一种含有该酯化合物作为活性成分的用于控制有害昆虫的活性剂，用于生产该酯化合物的中间体以及生产该中间体的方法。公式I所表示的酯化合物对控制有害昆虫具有良好的活性。
• Ester compounds pesticidal compositions containing the same and
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05925676A1

  公开（公告）日：1999-07-20

  An ester compound represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 may be the same or different and each represent a C.sub.1 -C.sub.6 alkyl group, or other specified groups, which may be optionally substituted with one or more halogen atoms; and R.sub.3 represents a pyrethroid acid residue (a group resulting from elimination of the carboxyl group from pyrethroid acid), and a pesticidal composition containing the ester compound as an active ingredient.

  由公式##STR1##表示的酯化合物，其中R1和R2可以相同或不同，每个代表一个C1-C6烷基团，或者其他指定的团，可任选地用一个或多个卤素原子取代；R3代表拟除虫菊酯酸残基（即从拟除虫菊酯酸中消除羧基得到的团），以及包含该酯化合物作为活性成分的杀虫剂组合物。
• Ester compound, agent for controlling noxious organisms containing the
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05653990A1

  公开（公告）日：1997-08-05

  There is provided an ester compound represented by the formula I: ##STR1## wherein R.sub.1 is a methyl group or a hydrogen atom; R.sub.2 is a C.sub.1-6 haloalkyl group; and R.sub.3 is a pyrethroid acid residue, an agent for controlling noxious organisms containing the same as active ingredient and an intermediate for producing the same.

  提供了一种由公式I表示的酯化合物：##STR1## 其中R1是甲基或氢原子；R2是C1-6卤代烷基；R3是拟除虫菊酸残基，含有作为活性成分的同一控制有害生物的药剂以及用于生产该化合物的中间体。
• Ester compound, active agent for controlling noxious insect pests containing the same as active ingredient, intermediate for production of the ester compound, and process for producing the intermediate
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0643037A1

  公开（公告）日：1995-03-15

  The present invention provides an ester compound represented by a formula I: wherein R₁ denotes a hydrogen atom or a methyl group; R₂ represents a 1-methyl-2-propenyl group, a 1-methyl-2-propynyl group, a 3,3-dihalogeno-1-methyl-2-propenyl group, or a C₁-C₁6 alkyl group which may be substituted with at least one halogen atom; and R₃ represents an acid residue of pyrethroids. The invention also relates to an active agent for controlling noxious insect pests containing the ester compound as an active ingredient, an intermediate for production of the ester compound and a process for producing the intermediate. The ester compound represented by the formula I has good activities for controlling noxious insect pests.

  本发明提供了一种由式 I 代表的酯类化合物： 其中 R₁ 表示氢原子或甲基； R₂ 表示 1-甲基-2-丙烯基、1-甲基-2-丙炔基、3,3-二卤代-1-甲基-2-丙 烯基或可被至少一个卤原子取代的 C₁-C₁6 烷基；以及 R₃ 代表拟除虫菊酯的酸残基。 本发明还涉及一种含有酯类化合物作为活性成分的防治有害害虫的活性剂、一种生产酯类化合物的中间体和一种生产该中间体的工艺。式 I 所代表的酯类化合物具有良好的防治有害害虫的活性。
• Ester compound, agent for controlling noxious organisms containing the same as active ingredient, and production intermediate thereof
  申请人：SUMITOMO CHEMICAL COMPANY LIMITED

  公开号：EP0688758A1

  公开（公告）日：1995-12-27

  There is provided an ester compound represented by the formula I: wherein R₁ is a methyl group or a hydrogen atom; R₂ is a C₁₋₆ haloalkyl group; and R₃ is a pyrethroid acid residue, an agent for controlling noxious organisms containing the same as active ingredient and an intermediate for producing the same.

  本发明提供了一种由式 I 代表的酯类化合物： 其中 R₁ 是甲基或氢原子；R₂ 是 C₁₋₆卤代烷基；R₃ 是拟除虫菊酯酸残留物。