2,3-dihydroxy-5,6-dimethyl-1,4-benzoquinone | 2188-79-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,3-dihydroxy-5,6-dimethyl-1,4-benzoquinone
• 英文别名: 2,3-Dihydroxy-5,6-dimethyl-1,4-benzochinon；2.3-Dihydroxy-5,6-dimethyl-1,4-benzochinon；5,6-Dihydroxy-2,3-dimethyl-benzochinon；3,4-Dihydroxy-6-methyltoluchinon；3,6-Dihydroxy-4,5-dimethylcyclohexa-3,5-diene-1,2-dione；2,3-dihydroxy-5,6-dimethylcyclohexa-2,5-diene-1,4-dione
• CAS: 2188-79-6
• 化学式: C₈H₈O₄
• 分子量: 168.149
• InChiKey: RRSIQEMLRDKPLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2914690090

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 2,3-dihydroxy-5,6-dimethyl-1,4-benzoquinone 生成 2,3-二甲氧基-5,6-二甲基对苯醌
  参考文献：
  名称：

  Popoff,T. et al., Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1978, vol. 32, p. 1 - 7

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3-二羟基丙酮 以 水 为溶剂， 生成 2,3-dihydroxy-5,6-dimethyl-1,4-benzoquinone
  参考文献：
  名称：

  Popoff,T. et al., Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1978, vol. 32, p. 1 - 7

  摘要：

  DOI：

文献信息

• POPOFF T.; THEANDER O.; WESTERLUND E., ACTA CHEM. SCAND. <ACSA-A4>, 1978, B 32, NO 1, 1-7
  作者：POPOFF T.、 THEANDER O.、 WESTERLUND E.

  DOI：——

  日期：——
• COORDINATION COMPOUNDS HAVING REDOX NON-INNOCENT LIGANDS AND FLOW BATTERIES CONTAINING THE SAME
  申请人：LOCKHEED MARTIN ADVANCED ENERGY STORAGE, LLC

  公开号：US20170291916A1

  公开（公告）日：2017-10-12

  Electrolyte solutions for flow batteries and other electrochemical systems can contain an active material capable of transferring more than one electron per oxidation-reduction cycle. Such active materials can include coordination compounds containing a metal center and at least one redox non-innocent ligand. Accordingly, flow batteries can include a first half-cell having a first electrolyte solution therein, where the first electrolyte solution contains a coordination compound having at least one redox non-innocent ligand coordinated to a metal center. Particular redox non-innocent ligands can include those bearing a quinone functional group, such as substituted catecholates bearing a quinone functional group. Some active materials can include compositions containing a coordination compound having at least one redox non-innocent ligand coordinated to a metal center, where the at least one redox non-innocent ligand is a substituted catecholate or a salt thereof bearing a quinone functional group.
• US4867751A
  申请人：——

  公开号：US4867751A

  公开（公告）日：1989-09-19
• US9938308B2
  申请人：——

  公开号：US9938308B2

  公开（公告）日：2018-04-10
• [EN] COORDINATION COMPOUNDS HAVING REDOX NON-INNOCENT LIGANDS AND FLOW BATTERIES CONTAINING THE SAME<br/>[FR] COMPOSÉS DE COORDINATION AYANT DES LIGANDS NON INNOCENTS REDOX ET BATTERIES REDOX CONTENANT CEUX-CI
  申请人：LOCKHEED MARTIN ADVANCED ENERGY STORAGE LLC

  公开号：WO2017176296A1

  公开（公告）日：2017-10-12

  Electrolyte solutions for flow batteries and other electrochemical systems can contain an active material capable of transferring more than one electron per oxidation-reduction cycle. Such active materials can include coordination compounds containing a metal center and at least one redox non-innocent ligand. Accordingly, flow batteries can include a first half-cell having a first electrolyte solution therein, where the first electrolyte solution contains a coordination compound having at least one redox non-innocent ligand coordinated to a metal center. Particular redox non-innocent ligands can include those bearing a quinone functional group, such as substituted catecholates bearing a quinone functional group. Some active materials can include compositions containing a coordination compound having at least one redox non-innocent ligand coordinated to a metal center, where the at least one redox non-innocent ligand is a substituted catecholate or a salt thereof bearing a quinone functional group.