2-[(octadecyloxy)methyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine | 1409917-62-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-[(octadecyloxy)methyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine
• CAS: 1409917-62-9
• 化学式: C₂₅H₄₄O₃S
• 分子量: 424.689
• InChiKey: MLUHNIMHUVBMOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.17
• 重原子数：
  29.0
• 可旋转键数：
  19.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  27.69
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  2-[(octadecyloxy)methyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine 在 N-氯代丁二酰亚胺 、 溶剂黄146 作用下， 以 氯仿 为溶剂， 反应 16.0h， 以66%的产率得到5,7-dichloro-2-[(octadecyloxy)methyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine
  参考文献：
  名称：

  Chain-Growth Polymerization of 2-Chlorothiophenes Promoted by Lewis Acids

  摘要：

  Lewis acids promote the polymerization of several 2-chloroalkylenedioxythiophenes, providing high-molecular-weight conjugated polymers. The proposed mechanism is a cationic chain-growth polymerization, as confirmed by end-capping reactions and a linear correlation of molecular weight with percent conversion. The "living" character of this process was used to prepare new block copolymers.

  DOI：

  10.1021/ja308498h
• 作为产物：
  描述：

  3,4-二甲氧基噻吩 、 鲨肝醇 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 72.0h， 以88%的产率得到2-[(octadecyloxy)methyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine
  参考文献：
  名称：

  Chain-Growth Polymerization of 2-Chlorothiophenes Promoted by Lewis Acids

  摘要：

  Lewis acids promote the polymerization of several 2-chloroalkylenedioxythiophenes, providing high-molecular-weight conjugated polymers. The proposed mechanism is a cationic chain-growth polymerization, as confirmed by end-capping reactions and a linear correlation of molecular weight with percent conversion. The "living" character of this process was used to prepare new block copolymers.

  DOI：

  10.1021/ja308498h