4,5-epoxytricyclo[6.2.1.0^2.7]undecane

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 4,5-epoxytricyclo[6.2.1.0^2.7]undecane
• 英文别名: 5-Oxatetracyclo[7.2.1.02,8.04,6]dodecane；5-oxatetracyclo[7.2.1.02,8.04,6]dodecane
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: VCCRQQQKUQSDAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4,5-epoxytricyclo[6.2.1.0^2.7]undecane 在 水 作用下， 以25 g的产率得到4,5-dihydroxytricyclo[6.2.1.0^2.7]undecane
  参考文献：
  名称：

  JP2023/32607

  摘要：

  公开号：
• 作为产物：
  描述：

  三环[6.2.1.0(2,7)]undeca-4-ene 在 碳酸氢钠 、 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 以25.6 g的产率得到4,5-epoxytricyclo[6.2.1.0^2.7]undecane
  参考文献：
  名称：

  悬浮脂环骨架：零双折射聚碳酸酯的合成方法

  摘要：

  聚环己烯碳酸酯(PCHC) 是一种可回收、可持续的脂环族聚碳酸酯，可由CO 2合成。然而，PCHC 的光学特性（包括双折射）尚不清楚。在此，我们通过降冰片烷骨架的“融合”和“悬浮”两种方法设计了新型碳酸酯单元，以获得基于PCHC的零双折射聚碳酸酯。与PCHC相比，100%单轴拉伸降冰片烷熔融PCHC薄膜的面内延迟降低，而光弹性系数出乎意料地增加。相反，降冰片烷悬浮的PCHC的光弹性双折射下降。此外，通过环己烯碳酸酯与四环十二烷悬浮单体共聚合成的共聚物表现出几乎为零的光弹性双折射。这一结果表明，可以通过“悬浮”环状骨架而不是“融合”环状骨架来降低光弹性双折射。计算研究表明，椅环己烷骨架抑制光弹性双折射。这项研究获得的结果有可能指导低双折射聚碳酸酯和其他聚合物的设计。

  DOI：

  10.1021/acs.macromol.3c02349

文献信息

• ACTINIC-RAY- OR RADIATION-SENSITIVE RESIN COMPOSITION, ACTINIC-RAY- OR RADIATION-SENSITIVE FILM, MASK BLANK AND METHOD OF FORMING PATTERN
  申请人：FUJIFILM Corporation

  公开号：US20140242502A1

  公开（公告）日：2014-08-28

  According to one embodiment, an actinic-ray- or radiation-sensitive resin composition includes a compound (A) that contains a structure (P) containing at least one phenolic hydroxyl group and a structure (Q) containing at least one phenolic hydroxyl group whose hydrogen atom is replaced by a group (S) with a cyclic structure containing an acid crosslinking group, characterized in that the group (S) with a cyclic structure containing an acid crosslinking group is a group with a polycyclic structure or a group with a cyclic structure containing a hydroxymethyl group and/or an alkoxymethyl group.
• SEMICONDUCTOR ELEMENT AND INSULATING LAYER-FORMING COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：US20170005266A1

  公开（公告）日：2017-01-05

  Provided is a semiconductor element having a semiconductor layer and an insulating layer adjacent to the semiconductor layer, in which the insulating layer is formed of a crosslinked product of a polymer compound having a repeating unit (IA) represented by the following General Formula (IA) and a repeating unit (IB) represented by the following General Formula (IB). In General Formula (IA), R 1a represents a hydrogen atom, a halogen atom, or an alkyl group. L 1a and L 2a each independently represent a single bond or a linking group. X represents a crosslinkable group. m2a represents an integer of 1 to 5, and in a case where m2a is 2 or more, m2a number of X's may be the same or different from each other, m1a represents an integer of 1 to 5, and in a case where m1a is 2 or more, m1a number of (-L 2a -(X) m2a )'s may be the same or different from each other. In General Formula (IB), R 1b represents a hydrogen atom, a halogen atom, or an alkyl group. L 1b represents a single bond or a linking group, and Ar 1b represents an aromatic ring, m1b represents an integer of 1 to 5.
• SEMICONDUCTOR DEVICE AND INSULATING LAYER-FORMING COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：US20170054076A1

  公开（公告）日：2017-02-23

  Provided is a semiconductor device which includes a semiconductor layer and an insulating layer adjacent to the semiconductor layer, in which the insulating layer is formed of a crosslinked product of a polymer compound that has a repeating unit (IA) represented by the following Formula (IA) and a repeating unit (IB) represented by the following Formula (IB); and an insulating layer-forming composition which is used for forming an insulating layer of a semiconductor device and contains a polymer compound that has the following repeating units (IA) and (IB). In Formulae, R 1a and R 1b each independently represent a hydrogen atom, a halogen atom, or an alkyl group. L 1a , L 2a , and L 1b each independently represent a single bond or a linking group. X represents a crosslinkable group and Y B represents a decomposable group or a hydrogen atom. m1a and m2a each independently represent an integer of 1 to 5. The symbol “*” represents a bonding position of the repeating units.
• US9400430B2
  申请人：——

  公开号：US9400430B2

  公开（公告）日：2016-07-26
• US9905768B2
  申请人：——

  公开号：US9905768B2

  公开（公告）日：2018-02-27