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Chromium(III) 2-ethylhexanoate | 3444-17-5

中文名称
——
中文别名
——
英文名称
Chromium(III) 2-ethylhexanoate
英文别名
chromium(3+);2-ethylhexanoate
Chromium(III) 2-ethylhexanoate化学式
CAS
3444-17-5
化学式
C24H45CrO6
mdl
——
分子量
481.6
InChiKey
WBKDDMYJLXVBNI-UHFFFAOYSA-K
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 沸点:
    489.1℃[at 101 325 Pa]
  • 密度:
    1,01 g/cm3
  • 闪点:
    110°C
  • 暴露限值:
    NIOSH: IDLH 25 mg/m3; TWA 0.5 mg/m3
  • LogP:
    7.64
  • 物理描述:
    Liquid
  • 稳定性/保质期:
    在常温常压下,该物质是稳定的,但对人有严重的刺激性。

计算性质

  • 辛醇/水分配系数(LogP):
    2.86
  • 重原子数:
    31
  • 可旋转键数:
    12
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.88
  • 拓扑面积:
    120
  • 氢给体数:
    0
  • 氢受体数:
    6

ADMET

毒理性
  • 副作用
ACGIH 致癌物 - 未分类。
ACGIH Carcinogen - Not Classifiable.
来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

安全信息

  • TSCA:
    Yes
  • 危险等级:
    3
  • 安全说明:
    S26,S36/37/39
  • 危险类别码:
    R36/37/38

SDS

SDS:3d4e36c8b2dd3801f4740c915f6ebab4
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Section 1: Product Identification
Chemical Name: Chromium (III) 2-ethylhexanoate, 70% in mineral spirits (8-10% Cr)
CAS Registry Number: 3444-17-5
Formula: Cr[OOCCH(C2H5)C4H9]3
EINECS Number: 222-357-3
Chemical Family: metal carboxylate
Synonym: 2-Ethylhexanoic acid, chromium salt

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 3444-17-5 70% 0.5mg/m3(as Cr) 0.5mg/m3(as Cr)
petroleum distilates 64742-46-7 30% no data no data

Section 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes, and respiratory tract.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes.
Eye Contact: Causes moderate irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may cause gastrointestinal distress, dizziness, weakness and drowsiness.
Acute Health Affects: Irritating to skin, eyes, and respiratory tract.
Chronic Health Affects: Chromium (III) salts have acted as tumorigens and mutagens in animal studies.
NTP: Yes
IARC: Yes
OSHA: No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Do not
Ingestion:
induce vomiting as serious lung damage may result if aspirated.

SECTION 5: Fire Fighting Measures
Flash Point: 230°F
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam
Combustible. If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Combustible. If involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container and store in a cool place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form: green, viscous liq.
Molecular Weight: 481.62
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: 1.01
Odor: organic odor
Solubility in Water: insoluble

SECTION 10: Stability and Reactivity
Stability: air and moisture stable liquid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: oxidizing agents
Decomposition Products: Carbon dioxide, carbon monoxide, organic vapors, and metal oxides

SECTION 11: Toxicological Information
No specific information available for title compound. For mineral spirits: Oral (rat); LD50: >34600mg/kg.
RTECS Data: Inhalation (rat); LC50: >21400mg/m3/4H. Intraperitoneal (rat); LDLo: 8560mg/kg. Administration onto the
skin (rabbit); LD50: 15400mg/kg.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound: See Category Code N090 for reporting.
Second Ingredient: none


SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

用途:用于油漆和油墨的催干剂。

反应信息

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文献信息

  • BRIGGS, JOHN R.
    作者:BRIGGS, JOHN R.
    DOI:——
    日期:——
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