Provided is a modified liquid diene-based rubber having an acryloyl group or a methacryloyl group, which is highly compatible with various monomers, such as acrylate or methacrylate having relatively high polarity, which can form a curable resin composition containing the modified liquid diene-based rubber with good workability, which has a satisfactory curing rate during curing, and which is capable of providing the curable resin composition that forms a cured product having excellent mechanical properties derived from the modified liquid diene-based rubber and having excellent adhesion to various materials. Also provided is a curable resin composition containing the modified liquid diene-based rubber. The modified liquid diene-based rubber is a modified liquid diene-based rubber (A) having, in a molecule, a modified group (a) containing a (meth) acryloyl group as a part thereof and at least one modified group (b) selected from a dicarboxylic acid monoester and a dicarboxylic acid monoamide (with the proviso that the modified group (b) contains no (meth)acryloyl group as a part thereof), wherein the functional group equivalent weights of the modified group (a) and the modified group (b) are each in the range of 700 to 40,000 g/eq.
本发明提供了一种具有
丙烯酰基或甲基
丙烯酰基的改性液态二烯基橡胶,该改性液态二烯基橡胶与各种单体(如极性相对较高的
丙烯酸酯或
甲基丙烯酸酯)具有很高的相容性,可形成含有该改性液态二烯基橡胶的可固化
树脂组合物,该组合物具有良好的加工性,在固化过程中具有令人满意的固化速率,并且能够提供可固化
树脂组合物,该组合物可形成由改性液态二烯基橡胶衍生出的具有优异机械性能且与各种材料具有优异粘附性的固化产品。此外,还提供了一种含有改性液态二烯基橡胶的可固化
树脂组合物。改性液体二烯基橡胶是一种改性液体二烯基橡胶 (A),其分子中具有一个含有(甲基)
丙烯酰基的改性基团(a)和至少一个选自二
羧酸单酯和二
羧酸单酰胺的改性基团(b)(但改性基团(b)不含(甲基)
丙烯酰基)、其中,改性基团(a)和改性基团(b)的官能团当量重量分别为 700 至 40,000 克/当量。