S-benzyl (1,7,7-trimethyl-norborn-2-yl)thiocarbamate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: S-benzyl (1,7,7-trimethyl-norborn-2-yl)thiocarbamate
• 英文别名: S-benzyl N-[(1R,2R,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl]carbamothioate
• 化学式: C₁₈H₂₅NOS
• 分子量: 303.469
• InChiKey: XJSDMPCGVUAEBA-RKVPGOIHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  硫氰酸苄酯 、 (-)-莰烯 在 phosphotungstic acid 水 作用下， 以 溶剂黄146 为溶剂， 反应 4.0h， 以66%的产率得到S-benzyl (1,7,7-trimethyl-norborn-2-yl)thiocarbamate
  参考文献：
  名称：

  Synthesis of a new thiocarbamate by the reaction of benzyl thiocyanate with camphene, catalyzed by heteropoly acids

  摘要：

  The reaction of benzyl thiocyanate with camphene in the presence of heteropoly acids, 12-phosphotungstic and 12-silicotungstic, at 65 degrees C was studied. S-Benzyl (1,7,7-trimethyinorbornyl)thiocarbamate was prepared in 66% yield.

  DOI：

  10.1134/s1070427207010338

文献信息

• Synthesis of a new thiocarbamate by the reaction of benzyl thiocyanate with camphene, catalyzed by heteropoly acids
  作者：A. V. Arkhipova、K. V. Malkova、T. N. Sokolova、V. R. Kartashov

  DOI：10.1134/s1070427207010338

  日期：2007.1

  The reaction of benzyl thiocyanate with camphene in the presence of heteropoly acids, 12-phosphotungstic and 12-silicotungstic, at 65 degrees C was studied. S-Benzyl (1,7,7-trimethyinorbornyl)thiocarbamate was prepared in 66% yield.