(E)-3,7,11-trimethyl-2-dodecen-1,7,11-triol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (E)-3,7,11-trimethyl-2-dodecen-1,7,11-triol
• 英文别名: (E)-3,7,11-trimethyldodec-2-ene-1,7,11-triol
• 化学式: C₁₅H₃₀O₃
• 分子量: 258.401
• InChiKey: CLCHLTGVDVMBRQ-MDWZMJQESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  18
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  反式,反式-金合欢醇 在 甲基三氧化铼(VII) 双氧水 、 lithium aluminium tetrahydride 作用下， 生成 trimethyl-3,7,11 dodecadiene-2E,6E,10 diol-1,11 、 (E)-3,7,11-trimethyl-2-dodecen-1,7,11-triol 、 (2E)-3,7,11-trimethyldodeca-2,10-diene-1,7-diol
  参考文献：
  名称：

  African Elephant Sesquiterpenes. II. Identification and Synthesis of New Derivatives of 2,3-Dihydrofarnesol

  摘要：

  A search for potential semiochemicals revealed nerolidol (6), albicanol (7), and the new 2,3-dihydrofarnesol derivatives 8-10 in the temporal gland secretions of African elephants. A novel synthesis from (E,E)-farnesol (1) provided compounds 8-10 for GC-MS comparison to the natural products. This study confirms the farnesol family as frequently occurring secondary metabolites in African elephant temporal gland secretions.

  DOI：

  10.1021/np010647c

文献信息

• African Elephant Sesquiterpenes. II. Identification and Synthesis of New Derivatives of 2,3-Dihydrofarnesol
  作者：Thomas E. Goodwin、Felisia D. Brown、Richard W. Counts、Nichole C. Dowdy、Patrick L. Fraley、Randall A. Hughes、Daniel Z. Liu、Courtney D. Mashburn、Josh D. Rankin、Russell S. Roberson、Katie D. Wooley、Elizabeth L. Rasmussen、Scott W. Riddle、Heidi S. Riddle、Stefan Schulz

  DOI：10.1021/np010647c

  日期：2002.9.1

  A search for potential semiochemicals revealed nerolidol (6), albicanol (7), and the new 2,3-dihydrofarnesol derivatives 8-10 in the temporal gland secretions of African elephants. A novel synthesis from (E,E)-farnesol (1) provided compounds 8-10 for GC-MS comparison to the natural products. This study confirms the farnesol family as frequently occurring secondary metabolites in African elephant temporal gland secretions.