Linalyl chloroacetate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Linalyl chloroacetate
• 英文别名: 3,7-dimethylocta-1,6-dien-3-yl 2-chloroacetate
• 化学式: C₁₂H₁₉ClO₂
• 分子量: 230.735
• InChiKey: KOWCUAVOQZQRRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Linalyl chloroacetate 、 双十二烷基胺 、 disodium;carbonate 在 disodium;carbonate 、 乙醚 作用下， 以 甲苯 为溶剂， 反应 348.0h， 生成 N,N-didodecylglycine linalyl ester
  参考文献：
  名称：

  US05958870

  摘要：

  公开号：
• 作为产物：
  描述：

  芳樟醇 、 氯乙酰氯 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 生成 Linalyl chloroacetate
  参考文献：
  名称：

  Insecticidal properties of monoterpenoid derivatives to the house fly (diptera: Muscidae) and red flour beetle (coleoptera: Tenebrionidae)

  摘要：

  AbstractMonoterpenoid derivatives were synthesized and their insecticidal activities were evaluated against red flour beetles, Tribolium castaneum (Herbst), in fumigant bioassays and against house flies Musca domestica (L.) in topical, fumigant, and ovicidal bioassays. Acetate derivatives and haloacetate derivatives were compared with each other, and with the parent monoterpenoid to determine structure‐activity relationships. Acetate derivatives were more active than the propionate derivatives of cyclic monoterpenoids in the topical, fumigant, and ovicidal bioassays. Pivalates were topically more insecticidal than acetates to adult house flies, while the acetates had the greater ovicidal activity. Acetates and pivalates were more effective than haloacetates in the topical, red flour beetle fumigation and ovicidal bioassays. Fluoroacetates of cyclic monoterpenoids were the most effective house fly fumigants, followed by acetates, and trichloroacetates. Several derivatives were produced that displayed enhanced activity relative to the parent alcohols or phenols.

  DOI：

  10.1002/ps.2780410305

文献信息

• Betaine ester compounds of active alcohols
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0799885A1

  公开（公告）日：1997-10-08

  The present invention relates to a composition and process for preparing such a composition which provides stabilised betaine ester compounds of active alcohols in an acidic environment. In particular, it relates to an aqueous acidic composition comprising: a) a betaine ester of an active alcohol which, at a concentration of from 0.01% to 10% by weight in said composition, is predominantly in the form of micelles and/ or is capable of being incorporated into micelles, b) a surfactant, said composition comprising an acidic material in sufficient amount to render the pH of the composition of less than 7.

  本发明涉及一种组合物和制备这种组合物的工艺，它能在酸性环境中提供稳定的活性醇甜菜碱酯化合物。本发明尤其涉及一种水性酸性组合物，该组合物包括： a) 一种活性醇的甜菜碱酯，该甜菜碱酯在所述组合物中的浓度为 0.01% 至 10%（按重量计），主要以胶束形式存在，并且/或者能够与胶束结合、 b) 表面活性剂、 所述组合物包含足够量的酸性物质，使组合物的 pH 值低于 7。
• Polymeric compound comprising one or more active alcohols
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0831143A1

  公开（公告）日：1998-03-25

  The present invention relates to polymers containing at least one nitrogen atom, wherein at least one of the nitrogen atoms is linked to an ester group, said ester group bearing an active alcohol. By the present invention, a delayed release of the active alcohol is provided upon contact of the compound with an aqueous medium.

  本发明涉及含有至少一个氮原子的聚合物，其中至少一个氮原子与酯基相连，所述酯基含有活性醇。通过本发明，当化合物与水介质接触时，活性醇可延迟释放。
• EP0752465A1
  申请人：——

  公开号：EP0752465A1

  公开（公告）日：1997-01-08
• US5958870A
  申请人：——

  公开号：US5958870A

  公开（公告）日：1999-09-28
• US6184197B1
  申请人：——

  公开号：US6184197B1

  公开（公告）日：2001-02-06