{(C5H4(CH3))Co(COD)}

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: {(C5H4(CH3))Co(COD)}
• 英文别名: (C5H4(CH3))Co(COD)
• 化学式: C₁₄H₁₉Co
• 分子量: 246.298
• InChiKey: QMPIIGZQVBVBEM-GCOBPYNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {(C5H4(CH3))Co(COD)} 、 1,6-cyclodecadiyne 以 正辛烷 为溶剂， 以1-2的产率得到(η4:η4-{3(4)}cyclobutadienophane)bis{(η5-methylcyclopentadienyl)cobalt}
  参考文献：
  名称：

  Reaction of 1,6-cyclodecadiyne and 1,8-cyclotetradecadiyne with substituted CpCo(cod)

  摘要：

  The yields of CpCo-capped cyclobutadiene superphane from 1,6-cyclodecadiyne (1) and (R-C5H4)Co(cod) varies considerably with the substituents R. Electron-withdrawing substituents give yields between 35 and 45 % while electron-donating substituents give very small yields. In the case of 1,8-cyclotetradecadiyne (2) such a dependence on R is much less pronounced. The reaction between 1 and 2 and the indenyl complex (eta5-C9H7)Co(cod) is also reported.

  DOI：

  10.1021/om00029a051
• 作为产物：
  描述：

  cobalt(III) acetylacetonate 、 甲基环戊二烯 、 1,5-环辛二烯 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以71.1%的产率得到{(C5H4(CH3))Co(COD)}
  参考文献：
  名称：

  Steuerung DER katalytischen Pyridinsynthese AUS Alkien和Nitrilien第三人以（η 6 -Borinato）-Liganden上午钴†

  摘要：

  吡啶的从炔烃和腈的催化合成的控制由（η 6 -Borinato）-Nigands在钴

  DOI：

  10.1002/hlca.19840670630

文献信息

• The preparation of finely divided metal powders and transition metal complexes using “organically solvated” magnesium
  作者：Helmut Bönnemann、Borislav Bogdanović、Rainer Brinkmann、Bernd Spliethoff、Da-Wei He

  DOI：10.1016/0022-328x(93)83004-f

  日期：1993.6

  Mg★ is an excellent in situ reducing agent for transition metal salts, giving highly reactive metal powders of Groups 8–12. In the presence of electron donor ligands, this reduction provides a useful one-step route to organotransition metal complexes. The application of 35 kHz ultrasound during the reaction improves the dispersity of the metal powders and enhances the yields of the complexes.

  用少量蒽在THF中处理市售镁粉会生成高活性形式的镁（Mg★）。Mg★是一种出色的过渡金属盐原位还原剂，可产生8-12组的高反应性金属粉末。在电子给体配体的存在下，这种还原为有机过渡金属配合物提供了有用的一步法。反应过程中施加35 kHz超声波可改善金属粉末的分散性，并提高配合物的收率。
• Cobalt(I) Olefin Complexes: Precursors for Metal–Organic Chemical Vapor Deposition of High Purity Cobalt Metal Thin Films
  作者：Jeff A. Hamilton、Thomas Pugh、Andrew L. Johnson、Andrew J. Kingsley、Stephen P. Richards

  DOI：10.1021/acs.inorgchem.6b01146

  日期：2016.7.18

  cobalt metal organic chemical vapor deposition (MOCVD) precursors. Atmospheric pressure MOCVD was employed using precursor 1, to synthesize thin films of metallic cobalt on silicon substrates under an atmosphere (760 torr) of hydrogen (H2). Analysis of the thin films deposited at substrate temperatures of 325, 350, 375, and 400 °C, respectively, by scanning electron microscopy and atomic force microscopy

  我们报告了基于环戊二烯基和二烯配体的有机金属钴（I）金属前体家族的合成和表征。描述了通过单晶X射线衍射分析确定的环戊二烯基-钴（I）二烯烃配合物的分子结构。配合物的热重分析和热稳定性研究强调了异戊二烯，二甲基丁二烯，和环己二烯衍生物[（C 5 H ^ 5）的Co（η 4 -CH 2 CHC（Me）的CH 2）]（1），[（C 5 ħ 5）的Co（η 4 -CH 2 C（Me）的C（Me）的CH 2）]（2），和[（C 5 H ^ 5）的Co（η 4 -C 6 H ^ 8）]（4）尽可能钴金属有机化学气相沉积（MOCVD）的前体。使用前驱体1进行大气压MOCVD ，以在氢气（H 2）（760托）下在硅衬底上合成金属钴薄膜。）。分别通过扫描电子显微镜和原子力显微镜对分别在325、350、375和400°C的基板温度下沉积的薄膜进行分析，揭示了与温度有关的生长特征。在这些温度下生长的薄膜是连续的
• Transannular Interactions in Mixed Superphanes with One Thiophene and One CpCo-Stabilized Cyclobutadiene Ring:  Syntheses, Structures, and Electrochemistry
  作者：Silke Gath、Rolf Gleiter、Frank Rominger、Christian Bleiholder

  DOI：10.1021/om0608206

  日期：2007.1.1

  Superphanes consisting of one thiophene ring and various substituted RCo-stabilized cyclobutadiene (CBD) rings (R = Cp, C5H4(CH3), C-5(CH3)(5), C5H4(Si(CH3)(3)), C5H4(COCH3), 8-12) and one superphane with one thiophene ring and one CpCo-stabilized cyclopentadienone ring (13) were synthesized. The starting point was a tricyclic diyne with a central thiophene ring and two condensed 4-cyclodecynes, 19. Heating of 19 with RCo(COD) yielded 8-12, whereas the heating of 19 with CpCo(CO)(2) gave 13. X-ray structural investigation of 8-13 afforded the geometrical parameters in the solid state. Cyclic voltammetry showed a strong interaction between the thiophene ring and the CpCo-stabilized cyclobutadiene part. This interaction was substantiated by comparison between the CV data of 8-12 and model systems containing only the CpCo(CBD) part.
• A correlation between 13C and 59Co NMR data and the catalytic activity of organocobalt complexes in the synthesis of pyridine derivatives
  作者：Helmut Bönnemann、Werner Brijoux、Rainer Brinkmann、Willi Meurers、Richard Mynott、Wolfgang Von Philipsborn、Thomas Egolf

  DOI：10.1016/0022-328x(84)80468-4

  日期：1984.9
• Substituirte η4-Cyclooctadien-1,5-η5-cyclopentadienyl-Cobalt-Komplexe durch Comproportionierung von Cobaltocenen und Alken-cobaltaten(1—)
  作者：Hans-Ulrich Ju¨rgens、Jens Alm

  DOI：10.1016/0022-328x(91)86341-m

  日期：1991.8

  Substituted eta-4-cyclooctadiene-1,5-eta-5-cyclopentadienyl-cobaltcomplexes cp(R)Co(COD), (2a-e), are prepared from the corresponding cobaltocenes, cp2(R)Co, (1a-e), by reaction with K(THF)1.5[Co(COD)].