酞氰镁 | 14325-24-7

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机锰
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 中文名称: 酞氰镁
• 中文别名: 酞菁化锰；酞菁化锰(II)；酞菁锰(II)；酞菁锰(II)盐
• 英文名称: manganese(II) phthalocyanin
• 英文别名: manganese(II) phthalocyanine；manganese phthalocyanine；MnPc；2,11,20,29,37,38-hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene;manganese(2+)
• CAS: 14325-24-7
• 化学式: C₃₂H₁₆MnN₈
• 分子量: 567.471
• InChiKey: ICIFYHOILPYQKB-UHFFFAOYSA-N

物化性质

• 熔点：
  >300 °C
• 暴露限值：
  OSHA: Ceiling 5 mg/m3NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
• 稳定性/保质期：
  常温常压下稳定。 避免与氧化物接触。

计算性质

• 辛醇/水分配系数(LogP)：
  6.12
• 重原子数：
  41
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.2
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• TSCA：
  Yes
• 安全说明：
  S22
• WGK Germany：
  3
• 海关编码：
  29310099
• 储存条件：
  常温下应密闭避光保存，并保持通风和干燥。

SDS

Name:	Manganese Phthalocyanine Material Safety Data Sheet
Synonym:	None
CAS:	14325-24-7

Section 1 - Chemical Product MSDS Name:Manganese Phthalocyanine Material Safety Data Sheet
Synonym:None

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
14325-24-7	Manganese,29h,31h-phthalocyaninato(2-)	ca 100	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14325-24-7: United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3 (as Mn) Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex organic compounds, as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE (as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC Mn) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: brown or brown grey
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C32H16MnN8
Molecular Weight: 567.46

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, oxides of manganese.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 14325-24-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Manganese,29h,31h-phthalocyaninato(2-)-n29,n30,n31,n32-,(sp- - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14325-24-7: No information available.
Canada
CAS# 14325-24-7 is listed on Canada's DSL List.
CAS# 14325-24-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14325-24-7 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  酞氰镁 在 O₂ 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 以47%的产率得到oxovanadium phthalocyanine
  参考文献：
  名称：

  Oxidation of manganese(II) phthalocyanine by molecular oxygen

  摘要：

  DOI：

  10.1021/ic50217a025
• 作为产物：
  描述：

  (酞菁)双(吡啶)锰(II) 以 neat (no solvent) 为溶剂， 生成 酞氰镁
  参考文献：
  名称：

  Hanack, Michael; Datz, Arnim, Chemische Berichte, 1986, vol. 119, # 4, p. 1281 - 1290

  摘要：

  DOI：
• 作为试剂：
  描述：

  8-甲基-1,2,3,4-四氢喹啉 在 酞氰镁 、 ethyl 2-(4-nitrophenyl)hydrazinecarboxylate 、 氧气 作用下， 以 乙腈 为溶剂， 反应 15.0h， 以80%的产率得到8-甲基喹啉
  参考文献：
  名称：

  氧化电位可调节有机分子及其在四氢喹啉有氧脱氢中的催化应用

  摘要：

  在这项工作中，公开了氧化电位可调节的有机分子2-苯基肼基甲酸烷基酯。在Mn（Pc）和O 2的存在下，对其氧化电位的精确调节有助于1,2,3,4-四氢喹啉的催化脱氢。

  DOI：

  10.1021/acs.orglett.8b02749

文献信息

• Reactions of dinitriles with manganese powder: First synthesis of manganese(II) octaphenylporphyrazine and a convenient synthesis of manganese(II) phthalocyanine
  作者：Mark J. Camenzind、Craig L. Hill

  DOI：10.1016/s0020-1693(00)86049-1

  日期：1985.4

  Abstract The one-step preparation of the manganese(II) tetraaza macrocyclic compounds, Mn phthalocyanine and Mn octaphenylporphyrazine from dinitriles and metallic manganese is described. The magnetic and other physical properties of the heretofore unknown Mn octaphenylporphyrazine complex are addressed.

  摘要描述了一种由二腈和金属锰一步制备锰（II）四氮杂大环化合物，Mn酞菁和Mn八苯基卟啉嗪的方法。解决了迄今未知的Mn八苯基卟啉锰配合物的磁性和其他物理性质。
• Coordination Polymer of Manganese(II) Phthalocyanine with 4,4′‐Bipyridyl: Synthesis, Crystal Structure, and Physical Properties
  作者：Alexey L. Litvinov、Alexey V. Kuzmin、Evgeniya I. Yudanova、Dmitri V. Konarev、Nikita R. Romanenko、Salavat S. Khasanov、Rimma N. Lyubovskaya

  DOI：10.1002/ejic.201600944

  日期：2016.12

  Coordination polymer of metal(II) phthalocyanine (Pc) with pyridine-containing bidentate ligand has been obtained for the first time as single crystals. It has composition Mn(II)Pc.bpy)n.(4C6H4Cl2)n (1) and contains manganese(II) phthalocyanine and 4,4`-bipyridyl (bpy). Optical and magnetic properties of the polymer have been studied. It is shown the formation of Mn(I)Pc+ and Mn(III)Pc- species under

  首次获得金属(II)酞菁(Pc)与含吡啶双齿配体的配位聚合物单晶。它的组成为 Mn(II)Pc.bpy)n.(4C6H4Cl2)n (1) 并含有锰 (II) 酞菁和 4,4'-联吡啶 (bpy)。已经研究了聚合物的光学和磁性能。它显示了在 bpy 的配位下形成 Mn(I)Pc+ 和 Mn(III)Pc- 物种。Mn(II) 原子在 1 中具有中间 S = 3/2 自旋态，并显示出弱的自旋铁磁耦合。
• Structure and Magnetic Properties of a Low-spin Manganese(III) Phthalocyanine Dicyanide Complex
  作者：Masaki Matsuda、Jun-Ichi Yamaura、Hiroyuki Tajima、Tamotsu Inabe

  DOI：10.1246/cl.2005.1524

  日期：2005.11

  A manganese(III) complex salt, TPP[Mn I I I (Pc)(CN) 2 ]. DCM was crystallized in dichloromethane solution (Pc = phthalocyaninato, TPP + = tetraphenylphosphonium, and DCM = dichloromethane). In the crystal, Pc molecules form a pair of one-dimensional regular chains along the c axis. The magnetic susceptibility measurement revealed Mn ions in the low-spin state (S = 1) and a spin-orbit coupling effect

  锰(III)复合盐，TPP[Mn III (Pc)(CN) 2 ]。DCM 在二氯甲烷溶液中结晶（Pc = 酞菁，TPP + = 四苯基鏻，DCM = 二氯甲烷）。在晶体中，Pc 分子沿 c 轴形成一对一维规则链。磁化率测量揭示了处于低自旋状态 (S = 1) 的 Mn 离子和由于对称配体场下角轨道矩的不完全淬灭而产生的自旋轨道耦合效应。
• A simple synthesis of symmetric phthalocyanines and their respective perfluoro and transition‐metal complexes
  作者：Ilse M. Denekamp、Florentine L.P. Veenstra、Peter Jungbacker、Gadi Rothenberg

  DOI：10.1002/aoc.4872

  日期：2019.5

  requires no specialised equipment. The complexes are isolated and characterised using X‐ray diffraction, NMR, FTIR and Raman spectroscopy and high‐resolution mass spectrometry. First, we study and present a one‐step synthesis route to a metal‐free Pc (H2PcH16), as well as to the corresponding MPcH16 complexes of Mn, Fe, Co, Ni, Cu and Zn. Then, we show that this route can also be used to make the fluorinated

  我们报告了一个简单的合成规程，从酞菁开始制备酞菁（Pcs）。此方法是常规方法，不需要专门的设备。使用X射线衍射，NMR，FTIR和拉曼光谱以及高分辨率质谱对复合物进行分离和表征。首先，我们研究并提出了一种无金属的Pc（H 2 PcH 16）以及相应的Mn，Fe，Co，Ni，Cu和Zn MPcH 16配合物的一步合成路线。然后，我们证明该途径也可用于制备氟化的PC类似物（MPcF 16）。最后，我们提出了一种新的有用的程序，用于将金属离子插入无金属的H 2 PcH 16中通过直接金属环形成相应的MPcH 16配合物。如果您要制作不同的MPcH 16复合体，则后一种方法特别有用。
• Ionic complexes simultaneously containing fullerene anions and coordination structures of metal phthalocyanines with I− and EtS− anions
  作者：D. V. Konarev、L. V. Zorina、S. S. Khasanov、E. U. Khakimova、R. N. Lyubovskaya

  DOI：10.1007/s11172-011-0168-x

  日期：2011.6

  The ionic complexes simultaneously containing negatively charged coordination structures of metal phthalocyanines and fullerene anions, viz., MnIIPc(CH3CH2S−)x·(I−)1−x}·(C60·−)· ·(PMDAE+)2·C6H4Cl2 (PMDAE is N,N,N′,N′,N′-pentamethyldiaminoethane, x = 0.87, 1) and ZnIIPc(CH3CH2S−)y·(I−)1−y}2·(C60−)2·(PMDAE+)4·(C6H4Cl2) (y = 0.5, 2) were synthesized. The both compounds were obtained as single crystals

  同时含有金属酞菁和富勒烯阴离子带负电荷的配位结构的离子配合物，即MnIIPc(CH3CH2S−)x·(I−)1−x}·(C60·−)··(PMDAE+)2·C6H4Cl2 ( PMDAE 是 N,N,N',N',N'-五甲基二氨基乙烷，x = 0.87, 1) 和 ZnIIPc(CH3CH2S−)y·(I−)1−y}2·(C60−)2·(PMDAE+ )4·(C6H4Cl2) (y = 0.5, 2) 被合成。这两种化合物均以单晶形式获得，这使得研究它们的晶体结构成为可能。在复合物 1 中，富勒烯自由基阴离子形成蜂窝状层，其中每个富勒烯都有三个相邻的富勒烯，中心到中心的富勒烯间距为 10.13-10.29 Å。C60·- 自由基阴离子之间相当长的距离导致该复合物中单体 C60·- 保留在低至 110(2) K 的温度下。在复合物 2 中，富勒烯形成由一个 CC 键连接的二聚体 (C60