铝酞菁 | 47822-79-7

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机铝
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 中文名称: 铝酞菁
• 英文名称: aluminium phthalocyanine
• 英文别名: aluminum phthalocyanine；AlPc(1+)；AlPHC；aluminum;2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene
• CAS: 47822-79-7
• 化学式: C₃₂H₁₆AlN₈
• 分子量: 539.514
• InChiKey: HUVXQFBFIFIDDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.75
• 重原子数：
  41
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  79.3
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  aluminum acetate 、 尿素 、 phthalanhydride 在 hexaammonium heptamolybdate tetrahydrate sodium sulfate 作用下， 以 melt 为溶剂， 生成 铝酞菁
  参考文献：
  名称：

  Sulphonated phthalocyanines as effective oxidation photocatalysts for visible and UV light regions

  摘要：

  Attention was paid to the synthesis, chemical modification (sulphonation), characterisation and practical catalytic utilisation of metal free phthalocyanine and a series of phthalocyanines (PHCs) with Zn, Al, Si, Co, Ni, Cu and Ti central atoms. These organometallic compounds are referred to as highly active species due to their ability to produce singlet oxygen upon energy absorption. Photocatalytic efficiency of the prepared PHCs was tested in a model oxidation of 4-chlorophenol under illumination with visible and UV light in agreement with location of their distinctive absorption bands in both these regions. It was shown that different types of phthalocyanines revealed very different photocatalytic activities and only those with a long life-time of the excited triplet states (ZnPHC, SiPHC, AlPHC) effectively interacted with molecular oxygen to form the reactive singlet oxygen. The indispensable role of constant pH (similar to 10) was also clarified in separate experiments. Determined values of quantum yields for reactions carried out in the UV region were always higher than for reactions induced by the visible light. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2007.03.024