酞菁铅 | 15187-16-3

• 物质功能分类: 无机化工 - 无机盐 - 氰化物、氰氧化物及氰络合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 中文名称: 酞菁铅
• 中文别名: 酞菁铅(II)；酞菁铅盐；PBPC
• 英文名称: lead(II) phthalocyanine
• 英文别名: phthalocyaninato lead(II)；lead (II) phthalocyanine；phthalocyaninatolead(II)；lead phthalocyaninate；lead phthalocyanine；9,18,27,36,37,39,40,41-Octaza-38lambda2-plumbadecacyclo[17.17.3.110,17.128,35.02,7.08,37.011,16.020,25.026,39.029,34]hentetraconta-1,3,5,7,9,11,13,15,17(41),18,20,22,24,26,28(40),29,31,33,35-nonadecaene；9,18,27,36,37,39,40,41-octaza-38λ2-plumbadecacyclo[17.17.3.110,17.128,35.02,7.08,37.011,16.020,25.026,39.029,34]hentetraconta-1,3,5,7,9,11,13,15,17(41),18,20,22,24,26,28(40),29,31,33,35-nonadecaene
• CAS: 15187-16-3
• 化学式: C₃₂H₁₆N₈Pb
• 分子量: 719.733
• InChiKey: WSQYJDCCFQPFJC-UHFFFAOYSA-N

物化性质

• 密度：
  1.39 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  5.75
• 重原子数：
  41
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  79.3
• 氢给体数：
  0
• 氢受体数：
  8

安全信息

• 危险等级：
  9
• 危险品标志：
  T,N
• 安全说明：
  S45,S53,S60,S61
• 危险类别码：
  R61,R33,R20/22,R50/53,R62
• WGK Germany：
  3
• 海关编码：
  29319090
• 危险品运输编号：
  UN 2291
• 危险标志：
  GHS07,GHS08,GHS09
• 危险性描述：
  H302 + H332,H360Df,H373,H410
• 危险性防范说明：
  P201,P261,P273,P304 + P340 + P312,P308 + P313,P391
• 储存条件：
  存储条件：室温下密封保存。

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : Lead(II) phthalocyanine
CAS-No. : 15187-16-3
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Reproductive toxicity (Category 1A)
Acute toxicity, Inhalation (Category 4)
Acute toxicity, Oral (Category 4)
Specific target organ toxicity - repeated exposure (Category 2)
Acute aquatic toxicity (Category 1)
Chronic aquatic toxicity (Category 1)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
May cause harm to the unborn child. Possible risk of impaired fertility. Harmful by inhalation and if
swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Danger
Hazard statement(s)
H302 Harmful if swallowed.
H332 Harmful if inhaled.
H360Df May damage the unborn child. Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard none
Statements
Restricted to professional users.
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R61 May cause harm to the unborn child.
R20/22 Also harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R62 Possible risk of impaired fertility.
S-phrase(s)
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/ Safety
data sheets.
Restricted to professional users.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Synonyms : Phthalocyanine
Formula : C32H16N8Pb
Molecular Weight : 719,72 g/mol
Component Concentration
Lead phthalocyanine
CAS-No. 15187-16-3 -
Index-No. 082-001-00-6

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Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
anemia, To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Lead oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Avoid exposure - obtain special
instructions before use.
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Z677272, Size M)
Splash protection
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Z677272, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone [phone], test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
contact the supplier of the CE approved gloves. This recommendation is advisory only and must
be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our
customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: powder
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents, Strong acids
Hazardous decomposition products
Other decomposition products - no data available

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Known human reproductive toxicant
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
no data available
Potential health effects
Inhalation Harmful if inhaled. May cause respiratory tract irritation.
Ingestion Harmful if swallowed.
Skin Harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure
anemia, To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: Not available

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
Very toxic to aquatic life.

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: 2291 IMDG: 2291 IATA: 2291
UN proper shipping name
ADR/RID: LEAD COMPOUND, SOLUBLE, N.O.S. (Lead phthalocyanine)
IMDG: LEAD COMPOUND, SOLUBLE, N.O.S. (Lead phthalocyanine)
IATA: Lead compound, soluble, n.o.s. (Lead phthalocyanine)
Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: yes IMDG Marine Pollutant: yes IATA: no
Special precautions for user
no data available

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SECTION 15 - REGULATORY INFORMATION
N/A

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

酞菁铅是一种有机半导体材料，具有良好的化学稳定性和热稳定性，在化工领域有着广泛的应用。

反应信息

• 作为反应物：
  描述：

  酞菁铅 在 二氧化氮 作用下， 生成 lead(II) nitrate
  参考文献：
  名称：

  Hobert, Hartmut; Weaver, Roger C.; Wright, John D., Zeitschrift fur Chemie, 1989, vol. 29, p. 454 - 455

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二氰基苯 在 butyl(2-hydroxyethyl)dimethylammonium acetate 作用下， 反应 2.0h， 生成 酞菁铅
  参考文献：
  名称：

  在特定任务的 2-羟乙基离子液体中合成酞菁和金属酞菁的便捷有效方法

  摘要：

  摘要 在任务特定的 2-羟乙基基咪唑鎓和铵离子液体中，取代的邻苯二甲腈在 100 °C 下四聚化，以中等产率得到相应的酞菁。此外，在过渡金属盐的存在下，取代的邻苯二甲腈在离子液体中的反应得到相应的金属酞菁。2-羟乙基铵离子液体比2-羟乙基咪唑鎓和非羟基官能化离子液体产生更好的酞菁收率。不同酞菁的分离和分离采用硅胶柱色谱法完成，产物采用多种光谱技术进行表征。图形概要

  DOI：

  10.1080/00397911.2013.867505

文献信息

• Synthesis, Structures, and Properties of Crystalline Salts with Radical Anions of Metal-Containing and Metal-Free Phthalocyanines
  作者：Dmitri V. Konarev、Alexey V. Kuzmin、Maxim A. Faraonov、Manabu Ishikawa、Salavat S. Khasanov、Yoshiaki Nakano、Akihiro Otsuka、Hideki Yamochi、Gunzi Saito、Rimma N. Lyubovskaya

  DOI：10.1002/chem.201404925

  日期：2015.1.12

  radical anion. Central metal atoms strongly affect EPR spectra of phthalocyanine radical anions. Instead of narrow EPR signals characteristic of metal‐free phthalocyanine radical anions [H2Pc(3−)].− (linewidth of 0.08–0.24 mT), broad EPR signals are manifested (linewidth of 2–70 mT) with g‐factors and linewidths that are strongly temperature‐dependent. Salt 11 containing the [NaIPc(2−)]− anions as well

  含金属和无金属酞菁的自由基阴离子盐[MPc（3-）] .-，其中M = Cu II，Ni II，H 2，Sn II，Pb II，Ti IV O和V IV O（1 – 10）具有四烷基铵阳离子的单晶体通过芴酮酮基钠的酞菁还原而获得。它们的形成伴随着Pc配体的还原，并影响金属酞菁自由基阴离子的分子结构以及它们的光学和磁性。自由基阴离子的特征在于短的和长C的交替 Ñ亚胺由于芳香族化合物的破坏，它在Pc配体中键合。盐1 – 10在NIR范围内显示833–1041 nm处的新谱带，而Q和Soret谱带则蓝移了0.13–0.25 eV（38–92 nm）和0.04–0.07 eV（4–13 nm）蓝移。 ， 分别。具有Ni II，Sn II，Pb II和Ti IV O的自由基阴离子具有S = 1/2自旋态，而[Cu II Pc（3-）] .-和[V IV OPc（3-）] .-含有顺磁性Cu II和V
• Crystalline salts of metal phthalocyanine radical anions [M(Pc˙³⁻)]˙⁻ (M = Cu^II, Pb^II, V^IVO, Sn^IVCl₂) with cryptand(Na⁺) cations: structure, optical and magnetic properties
  作者：Dmitri V. Konarev、Maxim A. Faraonov、Alexey V. Kuzmin、Salavat S. Khasanov、Yoshiaki Nakano、Semen I. Norko、Mikhail S. Batov、Akihiro Otsuka、Hideki Yamochi、Gunzi Saito、Rimma N. Lyubovskaya

  DOI：10.1039/c7nj00530j

  日期：——

  formed in salts 4 and 5, which are parallel to the ac plane and have an effective π–π interaction between the Pc˙3− macrocycles. The using of smaller cryptand[2,2,1](Na+) cations in 5, instead of larger cryptand[2,2,2](Na+) cations in 4, allows one to obtain more closely packed Pc layers. Reduction in the salts was centered on the Pc macrocycles, providing alternation of the C–N (imine) bonds in Pc due

  的金属酞菁自由基阴离子盐穴状配体- [2,2,2]（钠+）} [M（PC 3- ）]˙ - ·C 6 H ^ 4氯2（M =铜II（1），铅II（2），V IV O（3）和Sn IV氯2（4））和穴状配体[2,2,1]（钠+）} [Sn的IV氯2（PC 3- ）]˙ - ·C 6 H 4 Cl 2（5已获得单晶。酞菁平面形成通道以容纳1-3中的cryptand [2,2,2]（Na +）阳离子和溶剂C 6 H 4 Cl 2分子。在盐4和5中形成几乎方形的酞菁层，它们与ac平面平行，并且在Pc 3-大环之间具有有效的π-π相互作用。在使用更小的穴状配体的[2,2,1]（钠+）阳离子5，而不是较大的穴状配体- [2,2,2]（钠+）阳离子4允许一个人获得更紧密堆积的Pc层。盐的还原集中在Pc大环上，由于芳香度的部分损失，使得Pc中的C–N（亚胺）键交替出现。在946-1006 nm的NIR
• SYNTHESIS OF METALLOPHTHALOCYANINES FROM PHTHALONITRILE WITH STRONG ORGANIC BASES
  作者：Haruhiko Tomoda、Shojiro Saito、Shinsaku Shiraishi

  DOI：10.1246/cl.1983.313

  日期：1983.3.5

  Several metallophthalocyanines (MPc: M=Ni(II), Co(II), Zn(II), Pb(II), Fe(II), Sn(II), Cd(II), Mg(II), and Mn(III)) were obtained by heating phthalonitrile with metal salts in alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Metal acetylacetonates as well as metal halides were available as metal sources for preparation of metallophthalocyanines by this method.

  几种金属酞菁（MPc：M=Ni(II)、Co(II)、Zn(II)、Pb(II)、Fe(II)、Sn(II)、Cd(II)、Mg(II) 和 Mn( III)) 是通过在 1,8-二氮杂双环 [5.4.0] 十一碳 - 7-烯存在下加热邻苯二甲腈与金属盐的醇获得的。金属乙酰丙酮化物以及金属卤化物可用作通过该方法制备金属酞菁的金属来源。
• Barrett, P. A.; Dent, C. E.; Lindstead, R., Journal of the Chemical Society
  作者：Barrett, P. A.、Dent, C. E.、Lindstead, R.

  DOI：——

  日期：——
• Low-temperature synthesis of phthalocyanine and its metal complexes
  作者：B. I. Kharisov、U. Ortiz Mendez、J. Rivera de la Rosa

  DOI：10.1134/s1070328406090016

  日期：2006.9

  Conditions for synthesizing unsubstituted phthalocyanine and its metal complexes from phthalonitrile at low temperatures (0-50 degrees C) are optimized. Phthalocyanine and phthalocyaninates are produced under these conditions using activated Rieke metals, metals on inert substrate, sources of "soluble" metals in the form of unstable metal complexes, zeolites, solid-phase electrosynthesis of phthalonitrile, and UV irradiation. The use of pyrophoric metals is found to be the most efficient due to a large number of defects in their structure favoring the initial stage of phthalonitrile cyclization on a metal matrix. The suggested mechanism of formation of phthalocyanine macrocycle assumes participation of metal agglomerates occurring in activated metals.

表征谱图