2,3-环氧-5-乙烯基降冰片烷 | 2886-87-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 2,3-环氧-5-乙烯基降冰片烷
• 英文名称: exo-3-oxa-5-vinyl-tricyclo[3.2.1.02.4]octane
• 英文别名: exo-2,3-epoxy-5-vinyl-norbornane；2,3-Epoxy-5-vinylnorbornane；6-ethenyl-3-oxatricyclo[3.2.1.02,4]octane
• CAS: 2886-87-5
• 化学式: C₉H₁₂O
• 分子量: 136.194
• InChiKey: FSTQYCKZORHMKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2932999099

反应信息

• 作为反应物：
  描述：

  2,3-环氧-5-乙烯基降冰片烷 、 二乙醇胺 在 P_0.15Mo_1.84CoBr_0.30O_6.8 、 水 、 sodium hydroxide 作用下， 以 水 为溶剂， 以30%的产率得到3-[bis(2-hydroxyethyl)amino]-6-ethenylbicyclo-[2.2.1]heptan-2-ol
  参考文献：
  名称：

  N-取代的氨基甲氧基双环[2.2.1]庚醇及其在润滑油和油中的抗菌活性

  摘要：

  双环[2.2.1]庚烷-2,3-二醇以及其O-烯丙基和5-乙烯基衍生物的氨基甲基化，提供了一系列的N-取代的2-羟基（或烯丙氧基）-3-（氨基甲氧基） ）双环[2.2.1]庚烷在润滑油中具有很高的杀菌和杀真菌活性。

  DOI：

  10.1134/s107042801803003x
• 作为产物：
  描述：

  5-乙烯基双环[2.2.1]庚-2-烯 、 邻硝基苯磺酰氯 、 3-硝基苯磺酰氯 以78%的产率得到
  参考文献：
  名称：

  KIM, YONG, AAC;CHUNG, BONG, CHUL, J. ORG. CHEM., 1983, 48, N 9, 1562-1564

  摘要：

  DOI：

文献信息

• Preparation Of Alicyclic Diepoxides
  申请人：Bell Andrew

  公开号：US20100094030A1

  公开（公告）日：2010-04-15

  Embodiments in accordance with the present invention provide alicyclic diepoxide compounds and methods for forming such compounds. Such methods encompass charging a reaction vessel with an appropriate diene and an appropriate dienophile and causing such to react to form and recover a desired alicyclic diepoxide precursor where such precursor is subsequently epoxidized. Such compounds encompass alicyclic diepoxides having purities of at least 95 percent or at least 98 percent with respect non-isomeric residues and are essentially free of any isomeric alicyclic diepoxide residues.

  根据本发明的实施例提供了脂环二环氧化物化合物和形成这种化合物的方法。这样的方法包括向反应容器中加入适当的二烯和适当的二烯酰并使其反应以形成和回收所需的脂环二环氧化物前体，随后对该前体进行环氧化。这样的化合物包括至少95％或至少98％纯度的脂环二环氧化物，相对于非同分异构体残基，并且基本上不含任何异构的脂环二环氧化物残留物。
• NOVEL COMPOSITIONS AND METHODS TO PRODUCE TRIAZINE-ARYLHYDROXY-ALDEHYDE CONDENSATES WITH IMPROVED SOLUBILITY
  申请人：Viswanathan Ganapathy S.

  公开号：US20120046424A1

  公开（公告）日：2012-02-23

  Compositions and methods for forming condensates and resin compositions are provided. In one embodiment, a condensate is formed from a reaction mixture including a triazine monomer, an arylhydroxy monomer, an aldehyde monomer and an acid catalyst having a pKa value of greater than 3.8. The condensates contain up to 28 wt. % of nitrogen and have a melt viscosity of 3,000 cps or less at 175° C. The condensates may have a solubility of at least 80 wt. % solids dissolved in an organic solvent for 120 hours or greater. Also disclosed are methods for the manufacture of the condensate as well as the condensate's use in fire-retardant epoxy resin compositions suitable for the manufacture of laminates for electronic applications. There is also disclosed a glycidylated triazine-arylhydroxy-aldehyde condensate of this invention.

  本发明提供了形成冷凝物和树脂组合物的组合物和方法。在一种实施例中，从反应混合物中形成冷凝物，该反应混合物包括三嗪单体，芳基羟基单体，醛单体和具有大于3.8的pKa值的酸催化剂。冷凝物含有高达28重量％的氮，并且在175℃下的熔融粘度为3000 cps或更低。冷凝物可以在有机溶剂中溶解至少80重量％的固体物质，并且可以在120小时或更长时间内保持。还揭示了制造冷凝物的方法以及冷凝物在适用于制造电子应用层压板的阻燃环氧树脂组成物中的使用。还揭示了本发明的环氧基三嗪-芳基羟基-醛冷凝物。
• VINYL RESIN AND RESIN COMPOSITION
  申请人：SANYO CHEMICAL INDUSTRIES, LTD.

  公开号：US20150119497A1

  公开（公告）日：2015-04-30

  The present invention aims to provide a vinyl resin which, with a polyurethane resin, is capable of providing a film excellent in mechanical strength, weather resistance, solvent resistance, and water resistance. The vinyl resin (V1) of the present invention is obtainable by polymerizing monomer components including a monomer (X) represented by the formula (1): wherein M 1 is a hydroxy group or a residue of an active hydrogen-containing organic compound having a valence of 1 to 20 from which c number of active hydrogen atoms are removed; c is 1 if M 1 is a hydroxy group, or c is an integer satisfying 1≦c≦(valence of M 1 ) if M 1 is a residue of an active hydrogen-containing organic compound having a valence of 1 to 20 from which c number of active hydrogen atoms are removed; R 1 is an ethylenic unsaturated bond-containing group, and when the formula (1) includes multiple R1's, they may be the same as or different from each other; M 2 is a hydroxy group or a residue of an active hydrogen-containing organic compound having a valence of 1 to 20 from which one active hydrogen atom is removed, and when the formula (1) includes multiple M 2 's, they may be the same as or different from each other, and M 2 and M 1 may be the same as or different from each other; L is a residue of an aromatic polycarboxylic acid having 3 or more carboxyl groups from which all the carboxyl groups are removed, the aromatic ring of L is constituted by carbon atoms, and each of the carbon atoms may optionally have a halogen atom and/or a substituent which is not a carboxyl group, but at least one of the carbon atoms has a hydrogen atom; a and b are each an integer of 0 or greater and they satisfy 2≦(a+b)≦(d−2), when the formula (1) includes multiple a's, they may be the same as or different from each other and at least one of c number of a's is not 0, and when the formula (1) includes multiple b's, they may be the same as or different from each other; and d is the number of hydrogen atoms bonded to the carbon atoms constituting the aromatic ring assuming that all the substituents including the carboxyl groups of the aromatic polycarboxylic acid are replaced by hydrogen atoms, in other words, the number of moieties capable of being replaced by a substituent on the aromatic ring.

  本发明旨在提供一种乙烯基树脂，该树脂与聚氨酯树脂一起使用，能够提供机械强度、耐候性、耐溶剂性和耐水性优异的膜。本发明的乙烯基树脂（V1）可通过聚合单体组分获得，该组分包括由式（1）表示的单体（X）：其中M1是具有1到20个活性氢原子的具有价为1到20的活性氢含有机化合物的羟基或残基，从中去除了c个活性氢原子，则当M1是羟基时，c为1，或当M1是具有价为1到20的活性氢含有机化合物的残基时，c是满足1≤c≤（M1的价）的整数；R1是含有乙烯基不饱和键的基团，当式（1）包括多个R1时，它们可以相同或不同；M2是具有1到20个活性氢原子的具有价为1到20的活性氢含有机化合物的羟基或残基，从中去除了一个活性氢原子，当式（1）包括多个M2时，它们可以相同或不同，且M2和M1可以相同或不同；L是具有3个或更多羧基的芳香族多羧酸的残基，L的芳香环由碳原子构成，每个碳原子可以选择性地具有卤素原子和/或不是羧基的取代基，但至少有一个碳原子具有氢原子；a和b分别是大于或等于0的整数，它们满足2≤（a+b）≤（d-2），当式（1）包括多个a时，它们可以相同或不同，并且c个a中至少有一个不为0，当式（1）包括多个b时，它们可以相同或不同；d是假设芳香环上包括羧基的所有取代基都被氢原子取代的碳原子上结合的氢原子数，换句话说，是能够被芳香环上取代基替换的基团数。
• Novel terpene derived functional silanes
  申请人：PCR GROUP, INC.

  公开号：EP0179355A2

  公开（公告）日：1986-04-30

  Novel epoxyterpenylsilanes containing chiral centers have been prepared in a two-step synthesis. Terpenes, such as myrcene, dihydromyrcene, limonene, 5-ethylidene-2-norbornene and 5-vinyl-2-norbornene; are first epoxidized to the terpene oxide which is then condensed with alkoxy or alkylalkoxysilanes in the presence of a hydrosilation catalyst.

  通过两步合成法制备出了含有手性中心的新型环氧三萜硅烷。 萜烯，如月桂烯、二氢月桂烯、柠檬烯、5-亚乙基-2-降冰片烯和 5-乙烯基-2-降冰片烯，首先环氧化成氧化萜烯，然后在氢化催化剂的作用下与烷氧基或烷基烷氧基硅烷缩合。
• Polyether compounds, epoxy resins and processes for production thereof
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0303759A2

  公开（公告）日：1989-02-22

  Disclosed as a polyether compound having ether groups and vinyl double bonds represented by formula (I) and an epoxy resin represented by formula (II) wherein R' represents a residue group of an organic compound having active hydrogen atoms, n1 through nℓ each represents 0 or an integer of from 1 to 100, the sum of integers represented by n1 through nt is from 1 to 100, and ℓ represents an integer of from 1 to 100, and A represents or a mixture of and -R2-O-wherein R2 represents a residue group of mono epoxy compound, and B represents or a mixture of and -R2 -0- wherein X represents a -CH=CH2, or group, wherein R3 represents a hydrogen atom, an alkyl group, an alkyl carbonyl group, or an arylcarbonyl group, provided that the epoxy resin represented by formula (II) contains at least one In a further aspect, the invention relates to processes for production thereof.

  公开了一种具有由式（I）表示的醚基和乙烯基双键的聚醚化合物 和式 (II) 所代表的环氧树脂 其中 R' 代表具有活泼氢原子的有机化合物的残基，n1 至 nℓ 各代表 0 或 1 至 100 的整数，n1 至 nt 所代表的整数之和为 1 至 100，ℓ 代表 1 至 100 的整数，A 代表 0 或 1 至 100 的整数。 代表 1 至 100 的整数，A 代表 或 和-R2-O-的混合物，其中 R2 代表单环氧化合物的残基，B 代表 的混合物 和 -R2 -0- 其中 X 代表 -CH=CH2，或 基团，其中 R3 代表氢原子、烷基、烷基羰基或芳基羰基，条件是式(II)代表的环氧树脂 至少含有一个-CH=CH2，或-CH=CH2，或-CH=CH2，或-CH=CH2，或-CH=CH2。 在另一方面，本发明涉及其生产工艺。