9,10-dihydro-10-methyl-9-(tricyclo[3.3.1.1^3,7]decylidene)acridine | 86042-97-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 9,10-dihydro-10-methyl-9-(tricyclo[3.3.1.1^3,7]decylidene)acridine
• 英文别名: 9-(2-Adamantylidene)-10-methylacridine
• CAS: 86042-97-9
• 化学式: C₂₄H₂₅N
• 分子量: 327.469
• InChiKey: KUSPPJUNKDLPSC-UHFFFAOYSA-N

物化性质

• 沸点：
  477.7±25.0 °C(Predicted)
• 密度：
  1.171±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  25
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,10-dihydro-10-methyl-9-(tricyclo[3.3.1.1^3,7]decylidene)acridine 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 生成 2-(9H-Xanthen-9-yl)-adamantan-2-ol
  参考文献：
  名称：

  A novel chemiluminescence from the reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridines and peroxyacid

  摘要：

  Reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridine (1) with more than two equivalents of m-choloroperoxybenzoic acid in CH2Cl2 affords intermediary beta-hydroxy-tertiary-alkyl peroxyester (5) decomposing to N-methylacridone and aromatic aldehyde with chemiluminescence by a CIEEL mechanism.

  DOI：

  10.1016/s0040-4039(00)73237-0
• 作为产物：
  描述：

  金刚烷酮 在 对甲苯磺酸 作用下， 生成 9,10-dihydro-10-methyl-9-(tricyclo[3.3.1.1^3,7]decylidene)acridine
  参考文献：
  名称：

  A novel chemiluminescence from the reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridines and peroxyacid

  摘要：

  Reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridine (1) with more than two equivalents of m-choloroperoxybenzoic acid in CH2Cl2 affords intermediary beta-hydroxy-tertiary-alkyl peroxyester (5) decomposing to N-methylacridone and aromatic aldehyde with chemiluminescence by a CIEEL mechanism.

  DOI：

  10.1016/s0040-4039(00)73237-0

文献信息

• Oxiranes having an acridane structure as a novel chemiluminescent precursor: synthesis and chemiluminescent studies
  作者：Kazuyuki Miyashita、Masatoshi Minagawa、Yohko Ueda、Yukie Tada、Nobuhiro Hoshino、Takeshi Imanishi

  DOI：10.1016/s0040-4020(01)00216-2

  日期：2001.4

  Oxirane derivatives having acridane and adamantane structures were designed as a novel chemiluminescent precursor and were found to have a characteristic chemiluminescent ability which is introduced by a two-step trigger reaction involving treatment with alkaline H2O2 and subsequent acidic treatment. Structural study of the oxirane derivatives showed that the CIEEL mechanism is involved in this chemiluminescent reaction and it was also found that the chemiluminescent profile is affected by the kind of acid employed in the trigger reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
• Thermal and Chemiluminescent Property of Dioxetanes Having an N-Arylacridane Structure
  作者：Takeshi Imanishi、Yohko Ueda、Ryoh Tainaka、Naoto Kuni、Masatoshi Minagawa、Nobuhiro Hoshino、Kazuyuki Miyashita

  DOI：10.3987/com-97-s(n)85

  日期：——

  Novel dioxetanes having an N-arylacridane structure were syn thesized. Studies on thermal stability and chemiluminescent property of these compounds showed that the aryl group cannot stabilize the dioxetane structure so much but can trigger the chemiluminescence by formation of the phenoxy anion.
• Metal catalysed light emission from a dioxetan
  作者：Frank McCapra、David Watmore

  DOI：10.1016/s0040-4039(00)85804-9

  日期：1982.1
• Assays utilizing sensitizer-induced production of detectable signals
  申请人：LONDON DIAGNOSTICS, INC.

  公开号：EP0345776B1

  公开（公告）日：1994-11-23
• US5516636A
  申请人：——

  公开号：US5516636A

  公开（公告）日：1996-05-14