3,3,3,3-四甲基-5,5,6,6-四丙氧基-1,1-螺环二茚满 | 89929-65-7

• 物质功能分类: 有机原料 - 螺环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 中文名称: 3,3,3,3-四甲基-5,5,6,6-四丙氧基-1,1-螺环二茚满
• 中文别名: 3,3,3',3'-四甲基-5,5',6,6'-四丙氧基-1,1'-螺联茚满；3,3,3',3'-四甲基-5,5',6,6'-四丙氧基-1,1'-螺环二茚满；3,3,3',3'-四甲基-5,5',6,6'-四丙氧基- 1,1'-螺环二茚满
• 英文名称: 3,3,3',3'-Tetramethyl-5,5',6,6'-tetrapropoxy-1,1'-spirobiindane
• 英文别名: 1,1,1',1'-tetramethyl-5,5',6,6'-tetrapropoxy-3,3'-spirobi[2H-indene]
• CAS: 89929-65-7
• 化学式: C₃₃H₄₈O₄
• 分子量: 508.7
• InChiKey: XFCRUFLAYQTRRX-UHFFFAOYSA-N

物化性质

• 熔点：
  82 °C
• 沸点：
  589.6±50.0 °C(Predicted)
• 密度：
  1.06±0.1 g/cm3(Predicted)
• 溶解度：
  溶于甲醇

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  37
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Benzotriazoles containing phenyl groups substituted by heteroatoms and compositions stabilized therewith
  申请人：——

  公开号：US20030004235A1

  公开（公告）日：2003-01-02

  2H-Benzotriazole UV absorbers substituted at the 3-position and/or the 5-position of the phenyl ring by a phenyl moiety which is substituted by a heteroatom are particularly photostable in automotive coatings, and are of low color and exhibit low volatility in thermoplastic compositions.

  3-位和/或5-位被苯基环上的苯基取代的2H-苯并三唑紫外线吸收剂，其被异原子取代的苯基特别在汽车涂料中具有光稳定性，并且在热塑性复合材料中具有低色度和低挥发性。
• 2H-benzotriazole UV absorbers substituted with 1,1-diphenylakyl groups and compositions stabilized therewith
  申请人：——

  公开号：US20020169239A1

  公开（公告）日：2002-11-14

  2H-Benzotriazole UV absorbers substituted at the 3-position or at the 5-position of the phenyl ring by a 1,1-diphenylalkyl moiety, particularly a 1,1-diphenylethyl group, are particularly photostable in automotive coatings, and are of low color and exhibit low volatility in thermoplastic compositions.

  在汽车涂料中，3-位置或5-位置的苯环上被1,1-二苯基烷基基团（特别是1,1-二苯乙基基团）取代的2H-苯并三唑紫外线吸收剂，具有特别的光稳定性，并且在热塑性组合物中具有低色度和低挥发性。
• Naphthyltriazines as stabilizers for organic material
  申请人：Toan Van Vien

  公开号：US20050169859A1

  公开（公告）日：2005-08-04

  Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R 1 , R 2 , R 11 , R 22 , R′ 22 , R′ 33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.

  本发明涉及一种式I的新化合物，其中E代表式或代表式，而基团R1、R2、R11、R22、R′22、R′33和R′33如权利要求1所定义。式I的化合物适用于稳定有机材料，特别是塑料材料、表面涂层、化妆品制剂、防晒剂或照相材料，以防止光、氧和/或热损害。
• DYE-FORMING COUPLER, SILVER HALIDE PHOTOGRAPHIC LIGHT-SENSITIVE MATERIAL, AND AZOMETHINE DYE COMPOUND
  申请人：UEHIRA Shigeki

  公开号：US20080214810A1

  公开（公告）日：2008-09-04

  A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye compound derived from the coupler: wherein Q is a residue that forms, together with the —N—C═N— moiety, a nitrogen-containing 6-membered ring; R A is a certain alkyl group having at least 7 carbon atoms, or -L-R 1 ; X is an aryl group; Y is a hydrogen atom, or a group capable of being split-off upon a coupling reaction; wherein, when R A is -L-R 1 , L is a divalent linking group, and R 1 is a substituent; and -L-R 1 does not represent an alkyl, alkenyl, alkynyl, or aryl group, and -L-R 1 does not represent a heterocyclic group that bonds, with a carbon atom therein, to the nitrogen atom of the nitrogen-containing 6-membered ring formed by Q and the —N—C═N— moiety.

  公式（I）的染料形成偶合剂，含有该偶合剂的银卤化物感光材料，以及从偶合剂衍生的偶氮甲基染料化合物：其中Q是一个残基，与—N—C═N—基团一起形成含氮的6元环；RA是至少有7个碳原子的特定烷基或-L-R1；X是芳基基团；Y是氢原子或能够在偶合反应中被分离的基团；当RA是-L-R1时，L是二价连接基团，R1是取代基；-L-R1不表示烷基，烯基，炔基或芳基基团，-L-R1不表示与氮含量的6元环与Q和—N—C═N—基团形成的氮原子之间结合的杂环基团。
• Stabilizer mixture
  申请人：——

  公开号：US20030096993A1

  公开（公告）日：2003-05-22

  Mixtures of compounds comprising a compound G 2 and at least one further compound from the group G 0 , G 1 , G 3 , G 4 , G 5 , G 6 , the compounds G 0 -G 6 each corresponding to formula (I) in which, in the compound G 0 , the radicals R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each hydrogen; G 1 , the radical R 1 is Q and R 2 , R 3 , R 4 , R 5 and R 6 are each hydrogen; G 2 , the radicals R 1 and R 2 independently of one another are each Q and R 3 , R 4 , R 5 and R 6 are each hydrogen; G 3 the radicals R 1 , R 2 and R 3 independently of one another are each Q and R 4 , R 5 and R 6 are each hydrogen; G 4 , the radicals R 1 , R 2 , R 3 and R 4 independently of one another are each Q and R 5 and R 6 are each hydrogen; G 5 , the radicals R 1 , R 2 , R 3 , R 4 and R 5 independently of one another are each Q and R 6 is hydrogen; G 6 , the radicals R 1 , R 2 , R 3 , R 4 , R 5 and R 6 independently of one another are each Q; and Q and the other symbols are as defined in claim 1, are effective as stabilizers for organic material with respect to damaging exposure to light, oxygen and/or heat.

  由化合物G2和来自G0、G1、G3、G4、G5、G6组的至少一种进一步化合物组成的混合物，其中化合物G0-G6分别对应于公式(I)，其中，在化合物G0中，基团R1、R2、R3、R4、R5和R6均为氢；在化合物G1中，基团R1为Q，基团R2、R3、R4、R5和R6均为氢；在化合物G2中，基团R1和R2相互独立地为Q，基团R3、R4、R5和R6均为氢；在化合物G3中，基团R1、R2和R3相互独立地为Q，基团R4、R5和R6均为氢；在化合物G4中，基团R1、R2、R3和R4相互独立地为Q，基团R5和R6均为氢；在化合物G5中，基团R1、R2、R3、R4和R5相互独立地为Q，基团R6为氢；在化合物G6中，基团R1、R2、R3、R4、R5和R6相互独立地为Q；其中Q和其他符号如权利要求1中所定义，对于有机材料具有抗光、氧和/或热损伤的稳定剂效果。

表征谱图