3,3',7,7'-tetramethyldi-6-octenylamine | 24381-83-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3,3',7,7'-tetramethyldi-6-octenylamine
• 英文别名: bis(3,7-dimethyloct-6-en-1-yl)amine；Bis-<3.7-dimethyl-oct-6-enyl>-amin；N-(3,7-dimethyloct-6-enyl)-3,7-dimethyloct-6-en-1-amine
• CAS: 24381-83-7
• 化学式: C₂₀H₃₉N
• 分子量: 293.536
• InChiKey: LNIOKVSJURVNLM-UHFFFAOYSA-N

物化性质

• 沸点：
  378.7±31.0 °C(Predicted)
• 密度：
  0.826±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N.N-Bis-<3.7-dimethyl-oct-6-enyl>-O-methyl-isoharnstoff 在 溶剂黄146 作用下， 生成 3,3',7,7'-tetramethyldi-6-octenylamine
  参考文献：
  名称：

  Mild and effective two-step conversion of disubstituted cyanamides to secondary amines

  摘要：

  DOI：

  10.1021/jo00986a036

文献信息

• Kozlov, N. G.; Vyalimyae, T. K.; Popova, L. A., Journal of general chemistry of the USSR, 1987, vol. 57, p. 2442 - 2447
  作者：Kozlov, N. G.、Vyalimyae, T. K.、Popova, L. A.、Makhnach, S. A.、Kozlova, T. E.

  DOI：——

  日期：——
• Secondary amines from cyanmides a new method for removing the-CN group
  作者：A. Donetti、A. Omodei-Sale′、A. Mantegani

  DOI：10.1016/s0040-4039(00)99753-3

  日期：1969.1
• Synthesis of primary amines from the renewable compound citronellal via biphasic reductive amination
  作者：A. Behr、A. Wintzer、C. Lübke、M. Müller

  DOI：10.1016/j.molcata.2015.04.006

  日期：2015.8

  The reductive amination of the natural product citronellal with ammonia is presented as a new and atom economic way to its primary amine derivatives. The aqueous ammonia phase contains the homogeneous catalytic system [Rh(cod)Cl](2)/TPPTS in a biphasic solvent system, whereas the starting material and the products remain in the apolar solvent phase. This concept supresses side reactions effectively, achieving a high yield of primary amines of up to 87%. Systematic investigations demonstrate that the cleavage of the secondary imine as an undesired by-product is necessary in achieving high selectivites, which can be controlled by the reaction conditions. Surfactants, ionic liquids or native cyclodextrins and their derivates prove to be useful phase transfer agents for optimising the interaction between the organic and the aqueous phase. The use of the ionic liquid [DecMIM]Br and the cyclodextrin derivative methyl-beta-cyclodextrin provided especially fast and accurate phase separation. (C) 2015 Elsevier B.V. All rights reserved.
• KOZLOV, N. G.;VYALIMYAEH, T. K.;POPOVA, L. A.;MAXNACH, S. A.;KOZLOVA, T. +, ZH. OBSHCH. XIMII, 57,(1987) N 12, 2739-2744
  作者：KOZLOV, N. G.、VYALIMYAEH, T. K.、POPOVA, L. A.、MAXNACH, S. A.、KOZLOVA, T. +

  DOI：——

  日期：——
• Mild and effective two-step conversion of disubstituted cyanamides to secondary amines
  作者：Arturo Donetti、Elio Bellora

  DOI：10.1021/jo00986a036

  日期：1972.10