3,6,6-三甲基双环-3,1,1-庚烷-2-酮 | 16022-08-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 3,6,6-三甲基双环-3,1,1-庚烷-2-酮
• 中文别名: 3,6,6-三甲基二环[3.1.1]庚烷-2-酮
• 英文名称: 3-methylnopinone
• 英文别名: 3,6,6-trimethyl-norpinan-2-one；3.6.6-Trimethyl-bicyclo-[1.1.3]-heptanon-(2)；3,6,6-Trimethyl-norpinan-2-on；Methylnopinon；3,6,6-Trimethyl-bicyclo<3.1.1>heptan-2-on；3,7,7-Trimethyl-bicyclo<3.1.1>-2-heptanon；2-Norpinanone, 3,6,6-trimethyl-；3,6,6-trimethylbicyclo[3.1.1]heptan-2-one
• CAS: 16022-08-5；30469-49-9；30469-50-2
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: WNGMDDBBDVQVEB-UHFFFAOYSA-N

物化性质

• 沸点：
  208.5±8.0 °C(Predicted)
• 密度：
  0.950±0.06 g/cm3(Predicted)
• 保留指数：
  1137;1176;1176

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 甲醇 、 氢气 、 钯 作用下， 生成 3,6,6-三甲基双环-3,1,1-庚烷-2-酮
  参考文献：
  名称：

  Koetz; Lemien, Journal fur praktische Chemie (Leipzig 1954), 1914, vol. <2> 90, p. 315

  摘要：

  DOI：

文献信息

• Salt suitable for an acid generator and a chemically amplified resist composition containing the same
  申请人：Yoshida Isao

  公开号：US20070027336A1

  公开（公告）日：2007-02-01

  The present invention provides a salt of the formula (L) A salt of the formula (L): wherein Q represents —CO— group or —C(OH)— group; ring X represents monocyclic or polycyclic hydrocarbon group having 3 to 30 carbon atoms in which a hydrogen atom is substituted with a hydroxyl group at Q position when Q is —C(OH)— group or in which two hydrogen atoms are substituted with ≡O group at Q position when Q is —CO— group, and at least one hydrogen atom in the monocylic or polycyclic hydrocarbon group may optionally be substituted with alkyl group having 1 to 6 carbon atom, alkoxy group having 1 to 6 carbon atom, perfluoroalkyl group having 1 to 4 carbon atoms, hydroxyalkyl group having 1 to 6 carbon atoms, hydroxyl group or cyano group; R 10 and R 20 each independently represent fluorine atom or perfluoroalkyl group having 1 to 6 carbon atoms; and A + represents organic counter ion. The present invention also provides a chemically amplified resist composition comprising the salt of the formula (L).

  本发明提供了一种具有公式(L)的盐：其中Q代表—CO—基团或—C(OH)—基团；环X代表具有3至30个碳原子的单环或多元环烃基团，当Q是—C(OH)—基团时，在Q位置的氢原子被羟基取代，或者当Q是—CO—基团时，在Q位置的两个氢原子被≡O基团取代，并且单环或多元环烃基团中的至少一个氢原子可以可选地被具有1至6碳原子的烷基、具有1至6碳原子的烷氧基、具有1至4碳原子的全氟烷基、具有1至6碳原子的羟基烷基、羟基或氰基取代；R10和R20各自独立地代表氟原子或具有1至6碳原子的全氟烷基；A+代表有机反离子。本发明还提供了一种包含公式(L)的盐的化学放大抗蚀剂组合物。
• Salt suitable for an acid generator and a chemically amplified positive resist composition containing the same
  申请人：Harada Yukako

  公开号：US20080081293A1

  公开（公告）日：2008-04-03

  The present invention provides a salt represented by the formula (I): wherein P 1 , P 2 and P 3 each independently represent a C1-C30 alkyl group which may be substituted with at least one selected from a hydroxyl group, a C3-C12 cyclic hydrocarbon group and a C1-C12 alkoxy group, or a C3-C30 cyclic hydrocarbon group which may be substituted with at least one selected from a hydroxyl group and a C1-C12 alkoxy group, provided that all of P 1 , P 2 and P 3 are not simultaneously phenyl groups which may be substituted, Q 1 and Q 2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, and R represents a group represented by the formula: wherein A 1 represents —OH or —Y 1 —OH, n represents an integer of 1 to 9, and Y 1 represents a divalent C1-C6 saturated aliphatic hydrocarbon group; a group represented by the formula: wherein ring X 1 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which one —CH 2 — group is substituted with —CO—, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group; a group represented by the formula: wherein ring X 2 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which a hydrogen atom of one —CH 2 — group is substituted with a hydroxyl group, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group; a group represented by the formula: wherein ring X 3 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which one —CH 2 — group is substituted with —COO—, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group, and m represents an integer of 0 to 12; or a group represented by the formula: wherein ring X 4 represents a C6-C30 polycyclic hydrocarbon group having tricycle or more, and at least one hydrogen atom in the polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group or a cyano group, and l represents an integer of 1 to 12. The present invention further provides a chemically amplified resist composition comprising the salt represented by the above-mentioned formula (I).

  本发明提供了一种盐，其表示为公式（I）：其中P1、P2和P3各自独立地表示一个C1-C30烷基基团，该基团可以被至少一个羟基、一个C3-C12环烃基团和一个C1-C12烷氧基中的至少一个取代，或者一个C3-C30环烃基团，该基团可以被至少一个羟基和一个C1-C12烷氧基中的至少一个取代，前提是P1、P2和P3均不同时为可以被取代的苯基；Q1和Q2各自独立地表示氟原子或者C1-C6全氟烷基基团，R表示由以下公式表示的一个基团：其中A1表示—OH或—Y1—OH，n表示1到9之间的整数，Y1表示二价的C1-C6饱和脂肪族碳氢基团；一个由以下公式表示的基团：其中环X1表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团被—CO—取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代；一个由以下公式表示的基团：其中环X2表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团的氢原子被羟基取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代；一个由以下公式表示的基团：其中环X3表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团被—COO—取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代，m表示0到12之间的整数；或者一个由以下公式表示的基团：其中环X4表示一个具有三环或更多的C6-C30多环碳氢基团，多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团或氰基取代，l表示1到12之间的整数。本发明还提供了一种化学增感抗蚀组合物，其包含上述公式（I）表示的盐。
• Infrared Matrix Isolation and Theoretical Studies of Reactions of Ozone with Bicyclic Alkenes: α-Pinene, Norbornene, and Norbornadiene
  作者：Roger W. Kugel、Bruce S. Ault

  DOI：10.1021/jp510883k

  日期：2015.1.15

  The reactions of ozone with three bicyclic alkenes, α-pinene, norbornene, and norbornadiene, were studied by low-temperature (14 K), argon matrix isolation infrared spectroscopy including 18O isotope-labeling studies. Theoretical calculations of some of the proposed reaction intermediates and products were carried out using the Gaussian 09 suite of programs, applying density functional theory (DFT)

  通过低温（14 K），氩气基质分离红外光谱法研究了臭氧与三种双环烯烃α-pine烯，降冰片烯和降冰片二烯的反应，包括18O同位素标记研究。使用高斯09程序套件，应用密度泛函理论（DFT），B3LYP泛函和6-311G ++（d，2p）基础集，对某些拟议的反应中间体和产物进行了理论计算。在α-pine烯/臭氧系统中，在这些实验的双喷射或合并喷射沉积条件下，α-pine烯与臭氧之间的热反应太慢而无法观察到。但是，对含有α-pine烯和臭氧的氩气基质进行红光（λ≥600 nm）照射会导致出现新的红外峰，该峰很容易分配给α-pine烯与O（3）的反应产物。P）由臭氧光解产生：α-pine烯氧化物（带有环氧化物）和两个异构酮。降冰片烯和降冰片二烯均在与氩气的双喷射或合并喷射沉积过程中与气相中的臭氧反应。在红外光谱中观察到的新峰被分配给降冰片烯和降冰片二烯的主要臭氧化物，Criegee中间体和次要臭氧化物，表明这些反应大部分是通过“经典”
• CHEMICALLY AMPLIFIED POSITIVE RESIST COMPOSITION
  申请人：Kamabuchi Akira

  公开号：US20090286937A1

  公开（公告）日：2009-11-19

  The present invention provides a chemically amplified positive composition comprising a resin which comprises a structural unit having an acid-labile group in a side chain and a structural unit represented by the formula (I): wherein R 1 represents a hydrogen atom etc., R′ and R″ are independently a hydrogen atom etc., k represents an integer of 1 to 12, R is independently a C1-C6 alkyl group etc. and x represents an integer of 0 to 7, and an acid generator represented by the formula (V): wherein Y 1 and Y 2 each independently represent a fluorine atom etc., R12 represents a C1-C30 linear, branched chain or cyclic hydrocarbon group which may be substituted, and A + represents an organic counter ion.

  本发明提供了一种化学增感正性组合物，包括一个树脂，该树脂包括一个侧链中含有酸敏感基团的结构单元和一个由式(I)表示的结构单元：其中R1代表氢原子等，R'和R"各自独立地代表氢原子等，k表示1到12的整数，R独立地代表C1-C6烷基等，x表示0到7的整数，以及由式(V)表示的酸发生剂：其中Y1和Y2各自独立地代表氟原子等，R12代表C1-C30线性、支链或环烃基，可以被取代，A+代表有机对离子。
• A salt suitable for an acid generator and a chemically amplified resist composition containing the same
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1873143B1

  公开（公告）日：2009-04-15