降冰片烷-1-基2-甲基丙-2-烯酸酯 | 111965-24-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 降冰片烷-1-基2-甲基丙-2-烯酸酯
• 英文名称: Bicyclo[2.2.1]heptan-1-yl 2-methylprop-2-enoate
• 英文别名: 1-bicyclo[2.2.1]heptanyl 2-methylprop-2-enoate
• CAS: 111965-24-3
• 化学式: C₁₁H₁₆O₂
• 分子量: 180.24
• InChiKey: FEZAQYCRLLDDBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38

文献信息

• Cosmetic composition containing a statistical polymer with a linear main chain of ethylenic nature
  申请人：Schultze Xavier

  公开号：US20070092473A1

  公开（公告）日：2007-04-26

  A cosmetic composition includes, in a physiologically acceptable medium, at least one statistical copolymer with a linear main chain of ethylenic nature, in which the copolymer: (i) has a weight-average molecular mass of between 15,000 and 600,000 g/mol, and has: (a) at least 70% by weight of “monomer units” derived from monomers for which the homopolymers are hydrophobic and have a glass transition temperature of greater than 40° C., (b) at least one “monomer unit” derived from an at least partially neutralized ionic hydrophilic monomer, (c) 0 to 25% by weight of “monomer units” derived from additional monomers for which the homopolymers have a glass transition temperature of less than 40° C., chosen from: the acrylates of formula: CH 2 ═CHCOOR 12 in which R 12 represents a linear or branched C 1 to C 12 alkyl group with the exception of a tert-butyl group, in which is (are) optionally intercalated one or more identical or different heteroatoms, the alkyl group also possibly being optionally substituted with one or more identical or different substituents chosen from hydroxyl groups and halogen atoms, and the methacrylates of formula: CH 2 ═C(CH 3 )COOR 14 in which R 14 represents a linear C 4 to C 12 alkyl group or a branched C 5 to C 12 alkyl group, and (ii) has an overall glass transition temperature of greater than or equal to 45° C.

  一种化妆品组合物，包括在生理上可接受的介质中，至少含有一种具有乙烯基性线性主链的统计共聚物，其中该共聚物：(i)具有15,000至600,000克/摩尔的重均分子量，并具有：(a)至少70%的重量来自于单体，其均聚物是亲水性的且具有大于40°C的玻璃转移温度，(b)至少一种来自于至少部分中和的离子亲水性单体的“单体单元”，(c) 0至25%的重量来自于附加单体的“单体单元”，其均聚物的玻璃转移温度小于40°C，所选单体为：公式为CH2═CHCOOR12的丙烯酸酯，其中R12表示线性或支链C1到C12烷基，除了叔丁基基团外，在其中可选地插入一个或多个相同或不同的杂原子，该烷基还可能被一个或多个相同或不同的取代基取代，所述取代基选择自羟基和卤素原子，以及公式为 ═C(CH3)COOR14的甲基丙烯酸酯，其中R14表示线性C4到C12烷基或支链C5到C12烷基，(ii)具有大于或等于45°C的总玻璃转移温度。
• Heavy-hydrogenated norbornyl (meth)acrylates, process for producing them, polymers thereof and optical members
  申请人：Sasaki Hiroki

  公开号：US20070027279A1

  公开（公告）日：2007-02-01

  A novel compound represented by a formula [1] wherein R 1 and R 2 respectively represent a light or heavy hydrogen atom, R 3 represents a light or heavy hydrogen atom or a methyl group in which tree hydrogen atoms are respectively light or heavy hydrogen atoms, and R 4 is a norbornyl group provided that four or more hydrogen atoms in the norbornyl group are heavy hydrogen atoms; and a novel polymer produced by polymerization of a composition comprising the compound are disclosed.

  本发明公开了一种新化合物，其化学式为[1]，其中R1和R2分别代表轻或重氢原子，R3代表轻或重氢原子或一个甲基基团，其中三个氢原子分别为轻或重氢原子，R4是一个诺博烯基团，其中诺博烯基团中的四个或更多氢原子是重氢原子；以及通过聚合包含该化合物的组合物而制得的一种新聚合物。
• (METH)ACRYLIC ESTER COPOLYMERS AND PROCESS FOR PRODUCING THE SAME
  申请人：NIPPON SODA CO., LTD.

  公开号：EP0942018A1

  公开（公告）日：1999-09-15

  Random or block copolymers of a (meth)acrylic ester, which comprise structural units represented by general formulae (I) and (II) and have a number-average molecular weight of 1,000 to 50,000, a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio, M w/Mn, of 1.00 to 1.40, and a ratio of the repeating structural units represented by formula (I) to those represented by formula (II) of 1/9 to 9/1 (wherein R1 and R2 each independently represents hydrogen or methyl; R3 represents an optionally substituted C7-15 alicyclic group or an alkyl group having the alicyclic group; and R4 represents hydrogen, an optionally substituted C1-12 alkyl, optionally substituted C3-6 alicyclic or heterocyclic group, or substituted silyl group having a C1-8 alkyl and/or aryl group). The copolymers have each a unimodal narrow molecular weight distribution and an essential skeleton having at least one segment with a controlled structure comprising (meth)acrylic ester units each having an organic group containing a bulky alicyclic group.

  (甲基)丙烯酸酯的无规或嵌段共聚物，它包括通式(I)和(II)所代表的结构单元，其数均分子量为1,000至50,000，重均分子量(Mw)与数均分子量(Mn)之比M w/Mn为1.00至1.40，以及由式(I)表示的重复结构单元与由式(II)表示的重复结构单元之比为1/9至9/1（其中R1和R2各自独立地代表氢或甲基；R3代表任选取代的C7-15脂环基或具有脂环基的烷基；R4代表氢、任选取代的C1-12烷基、任选取代的C3-6脂环基或杂环基、或具有C1-8烷基和/或芳基的取代硅烷基）。共聚物具有单峰窄分子量分布，其基本骨架至少有一个具有受控结构的区段，该受控结构由(甲基)丙烯酸酯单元组成，每个单元都具有含有一个大脂环基团的有机基团。
• HIGH VISCOSITY INDEX COMB POLYMER VISCOSITY MODIFIERS AND METHODS OF MODIFYING LUBRICANT VISCOSITY USING SAME
  申请人：Infineum International Limited

  公开号：EP3839017A1

  公开（公告）日：2021-06-23

  A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer (which repeat units may comprise from 7.0 wt% to 18 wt% of the repeat units of the comb copolymer viscosity modifier); (b) a C3-C8 alkyl (alk)acrylate ester monomer (which repeat units may comprise from 40 wt% to 71 wt% or from 45 wt% to 64 wt% of the repeat units of the comb copolymer viscosity modifier); and (c) a C12-C24 alkyl (alk)acrylate ester monomer, wherein repeat units based on the C12-C24 alkyl (alk)acrylate ester monomer comprise at least 21.0 wt% (and optionally up to 35.0 wt%) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity, are also contemplated herein.

  梳状共聚物粘指剂可通过聚合制成，至少或主要由以下单体组成：(a) 氢化聚丁二烯基（烷基）丙烯酸酯大单体（其重复单元可占梳状共聚物粘指剂重复单元的 7.0 wt% 至 18 wt%）；(b) C3-C8 烷基（烷基）丙烯酸酯单体（其重复单元可占梳状共聚物粘指剂重复单元的 7.(b) C3-C8 烷基(烷基)丙烯酸酯单体(其重复单元可占梳状共聚物粘指剂重复单元的 40% 至 71% 或 45% 至 64%)；(c) C12-C24 烷基(烷基)丙烯酸酯单体，其中基于 C12-C24 烷基(烷基)丙烯酸酯单体的重复单元占至少 21.0 wt%（可选最多 35.0 wt%）的组合共聚物粘指剂重复单元。本文还考虑了包含梳状共聚物粘指剂的润滑剂组合物及其用途和粘度调节方法。
• Thermosetting composition, and method for manufacturing thermoset resin
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10668650B2

  公开（公告）日：2020-06-02

  A thermosetting composition comprising: (A) a (meth)acrylate compound having a viscosity at 25° C. of 1 to 300 mPa·s with which a substituted or unsubstituted aliphatic hydrocarbon group including 6 or more carbon atoms is ester-bonded; (B) spherical silica; and (C) a white pigment, and having a shear viscosity at 25° C. and 10 s−1 of 1 Pa·s or more and 500 Pa·s or less and a shear velocity at 25° C. and 100 s−1 of 0.3 Pa·s or more and 100 Pa·s or less.

  一种热固性组合物，包括：(A)(甲基)丙烯酸酯化合物，其在 25 摄氏度时的粘度为 1 至 300 mPa-s，包括 6 个或更多碳原子的取代或未取代脂族烃基与之酯键合；(B)球形二氧化硅；以及(C)白色颜料，其在 25 摄氏度和 10-1 时的剪切粘度为 1 Pa-s 或以上和 500 Pa-s 或以下，在 25 摄氏度和 100-1 时的剪切速度为 0.3 Pa-s 或以上和 100 Pa-s 或以下。和 10 s-1 时的剪切粘度为 1 Pa-s 或以上和 500 Pa-s 或以下，以及在 25° C. 和 100 s-1 时的剪切速度为 0.3 Pa-s 或以上和 100 Pa-s 或以下。