甲基菲-4-羧酸酯 | 18266-47-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 甲基菲-4-羧酸酯
• 英文名称: phenanthrene-4-carboxylic acid methyl ester
• 英文别名: Phenanthren-4-carbonsaeure-methylester；Phenanthren-carbonsaeure-(4)-methylester；Methyl-phenanthren-4-carboxylat；4-Methoxycarbonyl-phenanthren；Methyl-4-Phenanthroat；Methyl 4-phenanthrenecarboxylate；methyl phenanthrene-4-carboxylate
• CAS: 18266-47-2
• 化学式: C₁₆H₁₂O₂
• 分子量: 236.27
• InChiKey: YFZHEMZULMTHPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲基菲-4-羧酸酯 在 氢氧化钾 、 sodium azide 、 三氟乙酸 、 三氟乙酸酐 作用下， 生成 4-氨基菲
  参考文献：
  名称：

  A New Synthesis and Some Reactions of 4-Phenanthrenecarboxylic Acid

  摘要：

  DOI：

  10.1021/ja01558a056
• 作为产物：
  描述：

  3-烯丙基-2-羟基苯甲酸甲酯 在 四(三苯基膦)钯 potassium tert-butylate 、 N,N-二异丙基乙胺 作用下， 以 乙二醇二甲醚 、 二氯甲烷 、 水 为溶剂， 反应 54.5h， 生成 甲基菲-4-羧酸酯
  参考文献：
  名称：

  Studies towards the total synthesis of Sch 56036; isoquinolinone synthesis and the synthesis of phenanthrenes

  摘要：

  The isoquinolinone hemisphere of Sch 56036 has been prepared using a modified Pomeranz-Fritsch reaction and the synthesis of the phenanthrene core has been modelled via a Suzuki coupling and subsequent ring closing metathesis. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.07.084

文献信息

• Syntheses of phenanthrene amino alcohols as antimalarials
  作者：Leroy. Krbechek、Richard R. Riter、Richard G. Wagner、Clarence W. Huffman

  DOI：10.1021/jm00296a016

  日期：1970.3
• Robinson,C.N. et al., Journal of Heterocyclic Chemistry, 1972, vol. 9, p. 735 - 737
  作者：Robinson,C.N. et al.

  DOI：——

  日期：——
• SILICA ENCAPSULATED BIOMATERIALS
  申请人：Wackett Lawrence P.

  公开号：US20140051144A1

  公开（公告）日：2014-02-20

  The present invention relates to compositions for encapsulation of biomaterials in a silica-matrix. The present invention includes a composition for formation of a silica-matrix encapsulated biomaterial. The composition includes a reactive silicon compound and a biomaterial with a catalytic activity. When encapsulated in the silica-matrix, the biomaterial at least partially retains its catalytic activity. The present invention also relates to methods of making silica-matrix encapsulated biomaterials, and to methods of using silica-matrix encapsulated biomaterials, including methods of treating water or gas using the silica-matrix encapsulated biomaterials.
• US9790484B2
  申请人：——

  公开号：US9790484B2

  公开（公告）日：2017-10-17
• [EN] SILICA ENCAPSULATED BIOMATERIALS<br/>[FR] BIOMATÉRIAUX ENCAPSULÉS DANS DE LA SILICE
  申请人：WACKETT LAWRENCE P

  公开号：WO2012116013A2

  公开（公告）日：2012-08-30

  The present invention relates to compositions for encapsulation of biomaterials in a silica-matrix. The present invention includes a composition for formation of a silica-matrix encapsulated biomaterial. The composition includes a reactive silicon compound and a biomaterial with a catalytic activity. When encapsulated in the silica-matrix, the biomaterial at least partially retains its catalytic activity. The present invention also relates to methods of making silica-matrix encapsulated biomaterials, and to methods of using silica-matrix encapsulated biomaterials, including methods of treating water or gas using the silica-matrix encapsulated biomaterials.