3-丁氧基-2-羟基丙基丙烯酸酯 | 13282-82-1

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物 - 羧酸酯及其衍生物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 中文名称: 3-丁氧基-2-羟基丙基丙烯酸酯
• 英文名称: 3-butoxy-2-hydroxypropyl acrylate
• 英文别名: (3-butoxy-2-hydroxypropyl) prop-2-enoate
• CAS: 13282-82-1
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: AZNUOOZUBQUQJV-UHFFFAOYSA-N

物化性质

• 沸点：
  125-126 °C(Press: 9 Torr)
• 密度：
  0.9924 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2916129000

反应信息

• 作为产物：
  描述：

  sodium;3-butoxy-2-hydroxypropan-1-olate 、 丙烯酰氯 以18%的产率得到
  参考文献：
  名称：

  KIMSANOV B. X.; XABIBULAEVA O. K., DOKL. AKAD. FANXOI PCC TOCHIKISTON, DOKL. AN TADZHSSR, 1978, 21, HO 1, 39+

  摘要：

  DOI：

文献信息

• MEMBRANE-SUPPORTED CATALYST REMOVAL IN THE EPOXIDATION OF CYCLIC UNSATURATED C12 COMPOUNDS, FOR EXAMPLE CYCLODODECENE (CDEN)
  申请人：MEIER Ralf

  公开号：US20150328619A1

  公开（公告）日：2015-11-19

  A homogeneous catalyst system is removed from a reaction mixture of two liquid phases by separating the two liquid phases with a membrane having at least one separation-active layer in such a way that the homogeneous catalyst system is at least partially concentrated in a membrane retentate; wherein the reaction mixture contains at least one partially epoxidized cyclic unsaturated compound having twelve carbon atoms; and wherein the membrane separation-active layer contains crosslinked a silicone acrylate and/or polydimethylsiloxane and/or polyimide.

  一种均相催化剂体系通过使用至少具有一个分离活性层的膜将两个液相分离的方式从反应混合物中移除，以使均相催化剂体系至少部分浓缩在膜截留物中；其中，反应混合物包含至少一种含有十二个碳原子的部分环氧化的环状不饱和化合物；且膜分离活性层含有交联的硅丙烯酸酯和/或聚二甲基硅氧烷和/或聚酰亚胺。
• Radiation curable coating compositions, process for preparing such compositions and substrates coated therewith
  申请人：MOBIL OIL CORPORATION

  公开号：EP0018776A2

  公开（公告）日：1980-11-12

  This invention describes coating compositions comprising a combination of a minor amount of high molecular weight resin of low functionality with a large proportion of monoethylenically unsaturated monomer having a relatively high glass transition temperature (Tg) to provide a coating which, when cured, will possess a degree of hardness and flexibility enabling it to withstand severe fabrication and/or flexure stresses without film failure or loss of adhesion to the substrate.

  本发明描述了一种涂料组合物，该组合物由少量低官能度的高分子量树脂和大量玻璃化转变温度（Tg）相对较高的单乙烯不饱和单体组合而成，固化后的涂料将具有一定的硬度和柔韧性，使其能够承受剧烈的制造和/或弯曲应力，而不会使涂膜失效或失去与基材的附着力。
• Radiation curable epoxy/acrylate-hydroxyl coating compositions
  申请人：MOBIL OIL CORPORATION

  公开号：EP0082603A2

  公开（公告）日：1983-06-29

  The invention provides coating compositions comprising an epoxy resin, an acrylic or methacrylic monomer containing hydroxyl functionality, and a radiation sensitive Group Via onium salt. It also provides substrates coated with such coating compositions and irradiated.

  本发明提供了由环氧树脂、含羟基官能团的丙烯酸或甲基丙烯酸单体和辐射敏感的 Via 族鎓盐组成的涂料组合物。本发明还提供了涂有此类涂层组合物并经过辐照的基底。
• Primer composition
  申请人：NEGAMI CHEMICAL INDUSTRIAL CO LTD

  公开号：EP0136074A2

  公开（公告）日：1985-04-03

  There is disclosed a primer composition comprising A] a reaction product of: (1) a hydroxyl group-containing organic compound composed of; (a) an epoxy group-containing alcohol represented by the general formula [I]: wherein, R1 is a hydrocarbon group having 1 to 15 carbon atoms, or an organic group in which the same or different hydrocarbon groups are bonded to each other by an ether bond or an ester bond; and each of mand n is a value of 1 or more; and (b) a hydroxyl group-containing (meth)acrylate represented by the formula [II]: wherein R2 is a hydrogen atom or a methyl group; R3 is a substituted or unsubstituted hydrocarbon group, or a group in which the same or different hydrocarbon groups are bonded to each other by ether bond or the ester bond, the R3 being a-valent and having at least one hydroxyl group; and a is an integer of 1 to 3; an amount of active hydrogen atoms included in the aforesaid (a) being 25 to 75% with respect to the total amount of active hydrogen atoms included in the aforesaid (1), and (2) a polyisocyanate including 70 to 100% of the theoretical amount of isocyanato groups which will react with the total amount of the active hydrogen atoms included in the aforesaid (1); [B] an amino group-containing alkoxysilane or its partially hydrolyzed condensate having 0.5 to 1.5 amino active hydrogen atoms per epoxy group included in the aforesaid (1)(a); and [C] a diluent.

  本发明公开了一种底漆组合物，其中包含 A] 下列物质的反应产物 (1) 含羟基的有机化合物，由以下物质组成 (a) 由通式[I]代表的含环氧基的醇： 其中，R1 是具有 1 至 15 个碳原子的烃基，或相同或不同的烃基通过醚键或酯键相互键合 的有机基团；且每个 mand n 的值为 1 或以上；及 (b) 由式[II]代表的含羟基的(甲基)丙烯酸酯： 其中 R2 是氢原子或甲基；R3 是取代或未取代的烃基，或相同或不同的烃基通过醚键或酯键相互结合的基团，R3 是一价的且至少有一个羟基；a 是 1 至 3 的整数；前述(a)中包含的活性氢原子的量占前述(1)中包含的活性氢原子总量的 25% 至 75%，以及 (2) 多异氰酸酯，包括与上述(1)中所含活性氢原子总量发生反应的异氰酸酯基团理论量的 70 至 100%； [B] 含氨基的烷氧基硅烷或其部分水解缩合物，其对上述(1)(a)中每个环氧基团具有 0.5 至 1.5 个氨基活性氢原子；以及 [C] 稀释剂。
• Polycarbonate-modified urethane acrylate adhesive
  申请人：NEGAMI CHEMICAL INDUSTRIAL CO LTD

  公开号：EP0142228A1

  公开（公告）日：1985-05-22

  @ There is disclosed a polycarbonate-modified urethane acrylate adhesive comprising: [A] a polycarbonate-modified urethane acrylate oligomer which is a reaction product of: (1) 100 parts by weight of a hydroxyl group-containing (meth)acrylate represented by the formula [I]: wherein R' represents a hydrogen atom or a methyl group; R2 represents a substituted or unsubstituted hydrocarbon group ora group with a valence ofa having the hydrocarbon groups, which may be the same or different, bonded to each other with an ether bond or an ester bond and also having at least one hydroxyl group; and is an integer of 1 to 3, (2) 10 to 4,500 parts by weight of a bifunctional organic component comprising: (a) a polycarbonate diol represented by the formula [II]: wherein R3, which may be the same or different, represents divalent hydrocarbon groups having 2 to 15 carbon atoms or divalent groups comprising the hydrocarbon groups, which may be the same or different, bonded to each other with an ether bond or an ester bond, which hydrocarbon groups may be substituted with a halogen atom; and n is a number of 1 to 60 on the average, and (b) a bifunctional compound containing active hydrogen atom selected from the group consisting of alkylene glycol, its oxyacid ester, polyether diol, heterocyclic diol containing ether bond, polyester diol, thioether glycol and dithiol, containing 1 to 100 % by weight of(a) based on thetotal amount of the component (2); and (3) 0.005 to 50 parts by weight of an alkoxy silane containing amino group or its partial hydrolyzed condensate, and (4) a polyisocyanate containing 70 to 100 % of isocyanato groups of the theoretical amount reactive with the total active hydrogen atoms contained in the above components (1) to (3), and [B] a reactive diluent in an amount of 5 to 1,000 % by weight of the [A].

  @本发明公开了一种聚碳酸酯改性聚氨酯丙烯酸酯粘合剂，包括 [A] 聚碳酸酯改性聚氨酯丙烯酸酯低聚物，它是以下物质的反应产物： (1) 100 份(重量)由式[I]代表的含羟基的(甲基)丙烯酸酯： 其中 R'代表氢原子或甲基；R2 代表取代或未取代的烃基或具有 a 价的烃基，这些烃基可以相同或不同，彼此以醚键或酯键结合，并至少具有一个羟基；和 是 1 至 3 的整数、 (2) 10 至 4,500 重量份的双官能团有机组分，包括： (a) 由式[II]表示的聚碳酸酯二元醇： 其中 R3（可以相同或不同）代表具有 2 至 15 个碳原子的二价烃基或由烃基组成 的二价基团（可以相同或不同），彼此以醚键或酯键结合，这些烃基可以被卤素原子 取代；n 是平均为 1 至 60 的数字，以及 (b) 含有活性氢原子的双官能团化合物，选自由烷二醇、其氧酸酯、聚醚二 醇、含醚键的杂环二醇、聚酯二醇、硫醚二醇和二硫醇组成的组，以组分 （2）的总量为基准，含 1%至 100%（按重量计）的（a）；以及 (3) 0.005 至 50 重量份的含氨基的烷氧基硅烷或其部分水解缩合物，和 (4) 一种多异氰酸酯，含有与上述组分（1）至（3）所含总活性氢原子反应的理论量为 70%至 100%的异氰酸酯基团，以及 [B] 一种活性稀释剂，其用量为[A]重量的 5%至 1,000%。