3-(4-methylphenyl)-2,5-hexanedione | 583887-45-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3-(4-methylphenyl)-2,5-hexanedione
• 英文别名: 3-(4-Methylphenyl)hexane-2,5-dione；3-(4-methylphenyl)hexane-2,5-dione
• CAS: 583887-45-0
• 化学式: C₁₃H₁₆O₂
• 分子量: 204.269
• InChiKey: RAWSEMFLNUWBHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Alpha-甲基苯乙烯 、 乙酸酐 在 四丁基溴化铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以40%的产率得到3-(4-methylphenyl)-2,5-hexanedione
  参考文献：
  名称：

  Novel One-Pot Vicinal Double C-Acylation of Styrenes and Methacrylates by Electroreduction

  摘要：

  Electroreduction of styrenes or alkyl methacrylates in the presence of aliphatic acid anhydrides or N-acylinnidazoles with an undivided cell equipped with zinc electrodes as the anode and the cathode brought about novel one-pot vicinal double C-acylation to afford the corresponding 1,4-diketones in satisfactory yields.

  DOI：

  10.1021/ol035020v

文献信息

• Novel One-Pot Vicinal Double C-Acylation of Styrenes and Methacrylates by Electroreduction
  作者：Yoshimasa Yamamoto、Hirofumi Maekawa、Satoshi Goda、Ikuzo Nishiguchi

  DOI：10.1021/ol035020v

  日期：2003.7.1

  Electroreduction of styrenes or alkyl methacrylates in the presence of aliphatic acid anhydrides or N-acylinnidazoles with an undivided cell equipped with zinc electrodes as the anode and the cathode brought about novel one-pot vicinal double C-acylation to afford the corresponding 1,4-diketones in satisfactory yields.