3-巯基丙酸十三烷基酯 | 50727-77-0

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 3-巯基丙酸十三烷基酯
• 英文名称: tridecyl (3-mercaptopropionate)
• 英文别名: TDMP；tridecyl 3-mercaptopropanoate；Propanoic acid, 3-mercapto-, tridecyl ester；tridecyl 3-sulfanylpropanoate
• CAS: 50727-77-0
• 化学式: C₁₆H₃₂O₂S
• 分子量: 288.495
• InChiKey: MJNLAPRQQJZBQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.937
• 拓扑面积：
  27.3
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  3-巯基丙酸十三烷基酯 、 2-[2-[2-[2-[2-[2-[2-[2-[2-(2-Hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate 在 aluminum oxide 作用下， 以99 %的产率得到
  参考文献：
  名称：

  US2023/286912

  摘要：

  公开号：

文献信息

• Fast-curing photosensitive composition and recording sheet
  申请人：Brother Kogyo Kabushiki Kaisha

  公开号：EP0924569A1

  公开（公告）日：1999-06-23

  A fast-curing photosensitive composition capable of being cured by irradiation with light, comprising a radical-polymerizable unsaturated compound, a photopolymerization initiator, and a thiol-containing compound.

  一种可通过光照固化的快速固化光敏组合物，由可自由基聚合的不饱和化合物、光聚合引发剂和含硫醇的化合物组成。
• INORGANIC-ORGANIC HYBRID MATERIAL, OPTICAL MATERIAL USING SAME, AND INORGANIC-ORGANIC COMPOSITE COMPOSITION
  申请人：Nippon Kasei Chemical Company Limited

  公开号：EP2586826A1

  公开（公告）日：2013-05-01

  The disclosed inorganic-organic hybrid material can realize an optical material that combines the conflicting properties of flexibility and high index of refraction, has a low degree of yellowness, and is highly transparent. Said inorganic-organic hybrid material contains both an inorganic component and an organic component, with the inorganic component constituting between 20% and 80% of the mass of the inorganic-organic hybrid material, and has an index of refraction of at least 1.60. When said inorganic-organic hybrid material is used to fabricate a strip specimen 1,000 µm thick, 5 mm wide, and 70 mm long, said specimen does not crack when wrapped 180° around a cylindrical metal rod with a diameter of 10 mm at 25°C. Also disclosed is an inorganic-organic composite composition that contains: a radiation-curable monomer; inorganic particles that have crystallite diameters between 1 and 10 nm as calculated from the half-height width of a crystalline peak as per X-ray diffraction; and a sulfur-containing organic compound. The curable monomer includes a monofunctional radiation-curable monomer and a polyfunctional radiation-curable monomer. In terms of sulfur-atom content, the sulfur-containing organic compound constitutes between 1.5% and 10% of the inorganic-organic composite composition by mass.

  所公开的无机-有机杂化材料可以实现一种兼具柔韧性和高折射率这两种相互矛盾的特性、低黄度和高透明性的光学材料。所述无机-有机杂化材料包含无机成分和有机成分，其中无机成分占无机-有机杂化材料质量的 20% 至 80%，折射率至少为 1.60。当上述无机-有机杂化材料用于制造厚度为 1,000 微米、宽度为 5 毫米、长度为 70 毫米的带状试样时，在 25°C 温度下，当试样 180° 缠绕在直径为 10 毫米的圆柱形金属棒上时，不会出现裂纹。还公开了一种无机-有机复合材料组合物，其中包含：辐射固化单体；无机颗粒，根据 X 射线衍射结晶峰的半高宽度计算，无机颗粒的结晶直径在 1 到 10 纳米之间；以及含硫有机化合物。固化单体包括单官能团辐射固化单体和多官能团辐射固化单体。就硫原子含量而言，含硫有机化合物占无机-有机复合材料组合物质量的 1.5% 至 10%。
• ACRYLIC POLYMER, METHOD FOR PRODUCING SAME, AND PLASTISOL COMPOSITION INCLUDING SAID ACRYLIC POLYMER
  申请人：Mitsubishi Rayon Co., Ltd.

  公开号：EP3144328A1

  公开（公告）日：2017-03-22

  The present invention provides a method for producing an acrylic polymer (P), said method including a step (1) of obtaining a polymer (A) by polymerizing an acrylic monomer mixture (a), and a step (2) of polymerizing an acrylic monomer mixture (b) in a dispersion liquid including the polymer (A) to form a polymer (B), and obtaining an acrylic polymer (P) including the polymer (A) and the polymer (B), wherein: the content ratio of t-butyl methacrylate is 8-32 mol% within 100 mol% of the total of the monomers included in the acrylic monomer mixture (a); the solubility parameter (SPA) of the polymer (A) is 19.90 (J/cm3)1/2 or more; the glass transition temperature of the polymer (A) is 90 °C or more; and the relationship between the solubility parameter (SPB) of the polymer (B) and the solubility parameter (SPA) satisfies belowmentioned formula (1). 0.05≤SPB−SPA≤0.55

  本发明提供了一种生产丙烯酸聚合物（P）的方法，所述方法包括步骤（1）通过聚合丙烯酸单体混合物（a）获得聚合物（A），以及步骤（2）在包括聚合物（A）的分散液中聚合丙烯酸单体混合物（b）形成聚合物（B），并获得包括聚合物（A）和聚合物（B）的丙烯酸聚合物（P），其中：甲基丙烯酸叔丁酯的含量比在丙烯酸单体混合物 (a) 所含单体总量的 100 mol% 中为 8-32 mol%； 聚合物 (A) 的溶解度参数 (SPA) 为 19.90(J/cm3)1/2或以上；聚合物(A)的玻璃化转变温度为90℃或以上；聚合物(B)的溶解度参数(SPB)与溶解度参数(SPA)之间的关系满足下述式(1)。0.05≤SPB-SPA≤0.55
• METHOD FOR PRODUCING PHOTOCHROMIC CURED BODY
  申请人：Tokuyama Corporation

  公开号：EP3269774A1

  公开（公告）日：2018-01-17

  A process for producing a photochromic cured body by curing a photochromic composition comprising (A) a polyiso (thio) cyanate compound having at least two isocyanate groups and/or isothiocyanate groups in one molecule, a poly(thi)ol compound having at least two hydroxyl groups and/or thiol groups in one molecule, (C) a mono(thi)ol compound having one hydroxy group or thiol group in one molecule, and a photochromic compound.

  一种通过固化光致变色组合物生产光致变色固化体的工艺，光致变色组合物包括：(A) 在一个分子中具有至少两个异氰酸酯基团和/或异硫氰酸酯基团的聚异（硫）氰酸酯化合物；(B) 在一个分子中具有至少两个羟基和/或硫醇基团的聚（硫）醇化合物；(C) 在一个分子中具有一个羟基或硫醇基团的单（硫）醇化合物；以及光致变色化合物。
• PHOTOCHROMIC COATING COMPOSITION
  申请人：Tokuyama Corporation

  公开号：EP3330751A1

  公开（公告）日：2018-06-06

  To provide a photochromic coating composition comprising (A) a polyrotaxane having a composite molecular structure formed by an axial molecule and a plurality of cyclic molecules clathrating the axial molecule, (B) a photochromic compound and (C) a polyurethane resin and/or precursor thereof. This composition provides a laminate which exhibits excellent photochromic properties (color optical density and fading speed), moldability and surface hardness.

  提供一种光致变色涂料组合物，该组合物包含：(A) 具有由轴向分子和包覆轴向分子的多个环状分子形成的复合分子结构的聚罗他赛；(B) 光致变色化合物；(C) 聚氨酯树脂和/或其前体。 这种组合物提供的层压板具有优异的光致变色性能（颜色光学密度和褪色速度）、成型性和表面硬度。