N-(3-fluorophenyl)-N-(3-methylphenyl)amine | 464216-85-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(3-fluorophenyl)-N-(3-methylphenyl)amine
• 英文别名: 3-Fluoro-N-(m-tolyl)aniline；N-(3-fluorophenyl)-3-methylaniline
• CAS: 464216-85-1
• 化学式: C₁₃H₁₂FN
• 分子量: 201.243
• InChiKey: HCWIJBWJOCCNFW-UHFFFAOYSA-N

物化性质

• 沸点：
  297.7±23.0 °C(Predicted)
• 密度：
  1.143±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(3-fluorophenyl)-N-(3-methylphenyl)amine 在 tris(dibenzylideneacetone)dipalladium (0) 4-二甲氨基吡啶 、 1,1'-双(二苯基膦)二茂铁 、 甲酸 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 乙醚 、 甲苯 为溶剂， 反应 4.34h， 生成 3-[4-(3-fluoro{4'-[3-fluoro(3-methylphenyl)anilino][1,1'-biphenyl]-4-yl}anilino)phenoxy]propyl methacrylate
  参考文献：
  名称：

  Synthesis of Photo-Crosslinkable Hole-Transport Polymers with Tunable Oxidation Potentials And Their Use In Organic Light-Emitting Diodes

  摘要：

  已经合成了一系列可光交联的芳胺基孔导电共聚物。所采用的合成方法允许通过引入电子供体或吸电子基团来调节聚合物的红氧还原电位。在紫外线辐射照射下，聚合物变得不溶，用UV/Vis吸收光谱学证明了这一点，这一特性对通过溶液处理技术制造多层有机发光二极管（OLED）非常有用。基于这些孔导电聚合物的OLED已经被制造，并对器件性能进行了评估。光交联过程已得到优化，以至于不再对器件性能产生负面影响。

  DOI：

  10.1055/s-2002-32533
• 作为产物：
  描述：

  3-氟苯胺 、 3-溴甲基苯 在 1,1'-双(二苯基膦)二茂铁 、 tris(dibenzylideneacetone)dipalladium (0) 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以94%的产率得到N-(3-fluorophenyl)-N-(3-methylphenyl)amine
  参考文献：
  名称：

  Designing Interfaces That Function to Facilitate Charge Injection in Organic Light-Emitting Diodes

  摘要：

  Layer-by-layer (LbL) assembly of triarylamine (TAA)-containing polymers has been applied for anode functionalizations in organic light-emitting diodes (OLEDs). Surface work function of the ITO electrodes was significantly altered with the functionalizations, and the values changed depending on electron affinity of the substituents (X) on the TAA units. When the functionalized ITO electrodes were utilized for the conventional TPD/Alq OLED, the multilayers of P1 (X = 4-OMe) and P2 (X = none) were found to promote better energy matching at the ITO/TPD interface to reduce the hole injection barrier. Furthermore, the multilayers having heterodeposited structure of several TAA polymers provided stepped and graded electronic profiles to facilitate hole mobility from ITO to TPD, so that the resulting OLED devices can exhibit appreciably reduced turn-on voltage and higher luminous intensities.

  DOI：

  10.1021/ja052170n

文献信息

• Palladate Precatalysts for the Formation of C–N and C–C Bonds
  作者：Caroline M. Zinser、Katie G. Warren、Fady Nahra、Abdullah Al-Majid、Assem Barakat、Mohammad Shahidul Islam、Steven P. Nolan、Catherine S. J. Cazin

  DOI：10.1021/acs.organomet.9b00326

  日期：2019.7.22

  A series of imidazolium-based palladate precatalysts has been synthesized and the catalytic activity of these air- and moisture-stable complexes evaluated as a function of the nature of the imidazolium counterion. These precatalysts can be converted under catalytic conditions to Pd-NHC species capable of enabling the Buchwald-Hartwig aryl amination and the alpha-arylation of ketones. Both reactions can be carried out efficiently under very mild operating conditions. The effectiveness of the protocol was tested on functionality-laden substrates.
• Palladium-Catalyzed Direct Synthesis of Carbazoles via One-Pot <i>N</i>-Arylation and Oxidative Biaryl Coupling: Synthesis and Mechanistic Study
  作者：Toshiaki Watanabe、Shinya Oishi、Nobutaka Fujii、Hiroaki Ohno

  DOI：10.1021/jo9003376

  日期：2009.7.3

  An efficient catalytic system has been developed for the synthesis of carbazoles by one-pot N-arylation and oxidative biaryl coupling. A significant substituent effect of the diarylamine intermediate on oxidative Coupling was observed. Mechanistic studies of oxidative coupling, including trapping of reaction intermediates and kinetic isotope effect experiments, are also presented.
• COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME AND ELECTRONIC DEVICE THEREFOR
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US20190296244A1

  公开（公告）日：2019-09-26

  Provided are an organic electronic element and an electronic device therefor, the organic electronic element having a mixture of a compound according to the present invention used as a material therefor, thereby enabling the achievement of high light-emitting efficiency and low driving voltage of the organic electronic element, and enabling the life of the element to be greatly extended.
• [EN] COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME AND ELECTRONIC DEVICE THEREFOR<br/>[FR] COMPOSÉ POUR ÉLÉMENT ÉLECTRONIQUE ORGANIQUE, ÉLÉMENT ÉLECTRONIQUE ORGANIQUE L'UTILISANT ET DISPOSITIF ÉLECTRONIQUE ASSOCIÉ<br/>[KO] 유기전기소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO LTD

  公开号：WO2017204557A1

  公开（公告）日：2017-11-30

  본 발명에 따른 화합물의 혼합물을 유기전기소자의 재료로 이용함으로써, 유기전기소자의 높은 발광효율, 낮은 구동전압을 달성할 수 있으며, 또한 소자의 수명을 크게 향상시킬 수 있는 유기전기소자, 그 전자장치를 제공한다.