[SnBr4(piperidine)2] | 660851-87-6

• 英文名称: [SnBr4(piperidine)2]
• CAS: 660851-87-6
• 化学式: C₁₀H₂₂Br₄N₂Sn
• 分子量: 608.624
• InChiKey: HJEVUNUJWZDBFR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  哌啶 、 溴化锡 以 乙醇 为溶剂， 以79%的产率得到[SnBr4(piperidine)2]
  参考文献：
  名称：

  Thermochemistry of adducts of tin(IV) bromide with heterocyclic bases

  摘要：

  The compounds [SnBr4(L)(n)] (where L is pyridine (py), 3-methylpyridine (beta-pico), 4-methylpyridine (gamma-pico), piperidine (pipd), morpholine (morph), piperazine (pipz), 3-cyanopyridine (3-cyanopy), 4-cyanopyridine (4-cyanopy), quinoline (quin) or 2.2'-bipyridine (bipy) and n = 1 or 2) were synthesized and characterized by elemental analysis, melting points, thermal studies and IR spectroscopy. The enthalpies of dissolution of adducts, tin(IV) bromide and ligands in 25% (v/v) aqueous 1.2 M HCl in methanol were measured and, by thermochemical cycles, the standard enthalpies for the Lewis acid/base reaction (Delta(r)H(theta)), the standard enthalpies of formation (Delta(f)H(theta)), the standard enthalpies of decomposition (Delta(D)H(theta)), the lattice standard enthalpies (Delta(M)H(theta)) and the standard enthalpies for the Lewis acid/base reaction in the gaseous phase (Delta(r)H(theta)(g)) are determined. The mean standard enthalpies of the tin-nitrogen coordinated bonds D(Sn-N) are estimated. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0040-6031(03)00102-3