全氟辛基丙基丙烯酸酯 | 1652-60-4

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 全氟辛基丙基丙烯酸酯
• 英文名称: 3-Perfluoroctyl-propylacrylat
• 英文别名: 3-perfluorooctylpropyl acrylate；4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyl Prop-2-enoate
• CAS: 1652-60-4
• 化学式: C₁₄H₉F₁₇O₂
• 分子量: 532.197
• InChiKey: GHAHNTDCKCXNGO-UHFFFAOYSA-N

物化性质

• 沸点：
  72-76 °C(Press: 0.02 Torr)
• 密度：
  1.515±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  33
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  19

文献信息

• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• Compositions for providing abherent coatings; poly (fluorooyalkylene) urethane acrylates
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0040923A2

  公开（公告）日：1981-12-02

  Radiation-curable compositions for providing solvent-resistant adhesive coatings. The coating comprises a polyfluorinated acrylate or methacrylate, a polyethylenically unsaturated crosslinking agent and a film-forming organic polymer. Several of the poly(fluoro-oxyalkylene)urethane acrylate compounds are novel. Also disclosed is a method of transferring indicia produced by printing, silk-screening, stenciling, electrography, electrophotography or xerography from a support coated with a release agent to virtually any receiver surface. The release agent is a cured composition of the present invention. The indicia are removed with adhesive tape, which is then applied to the receiver, providing a protected image.

  用于提供耐溶剂粘合涂层的辐射固化组合物。涂层由聚氟丙烯酸酯或甲基丙烯酸酯、聚乙烯不饱和交联剂和成膜有机聚合物组成。其中有几种聚（氟氧烷基）聚氨酯丙烯酸酯化合物是新型的。还公开了一种方法，可将通过印刷、丝网印刷、模版印刷、电雕刻、电照相术或 Xerography 技术制作的标识从涂有脱模剂的支撑物转移到几乎任何接收表面。脱模剂是本发明的固化组合物。然后用胶带将标记撕下，再将胶带贴在接收器上，从而提供受保护的图像。
• Unsaturated group-containing ester compound, polymer, thermosetting resin composition, and cured film
  申请人：KYOEISHA CHEMICAL CO., LTD.

  公开号：US11155705B2

  公开（公告）日：2021-10-26

  It is an object of the present invention to provide an unsaturated group-containing ester compound which can be used as a raw material of a curable composition using transesterification reaction and which is inexpensive and has a good curability, and a polymer, a thermosetting resin composition, and a curable composition which containing the unsaturated group-containing ester compound, respectively. An unsaturated group-containing ester compound having a chemical structure represented by the following general formula (1): n1: 1 to 10 (in the formula, R1, R2, and R3 are the same or different and each is a hydrogen, an alkyl group, a carboxyl group, an alkyl ester group or a structure represented by R4-[COOR5]n1; R4 is an aliphatic, an alicyclic or an aromatic alkylene group with a number of atoms of 50 or less in the main chain, which may have one or more functional groups selected from the group consisting of an ester group, an ether group, an amide group, and a urethane and may have a side chain; R5 is an alkyl group having 50 or less carbon atoms; and in the compound represented by the general formula (1), the R4-[COOR5] group may be a lactone structure represented by the following general formula (1-1). (Rx is a hydrocarbon group having 2 to 10 carbon atoms which may have a branched chain.

  本发明的目的是提供一种可用作使用酯交换反应的可固化组合物的原料、价格低廉且具有良好固化性的含不饱和基团酯化合物，以及分别含有该含不饱和基团酯化合物的聚合物、热固性树脂组合物和可固化组合物。 含不饱和基团酯化合物的化学结构由以下通式（1）表示： N1：1 至 10 (式中，R1、R2 和 R3 相同或不同，且各自为氢、烷基、羧基、烷基酯基或由 R4-[COOR5]n1 表示的结构； R4 是脂肪族、脂环族或芳香族亚烷基，其主链上的原子数不超过 50 个，可带有一个或多个官能团，这些官能团可从酯基、醚基、酰胺基和氨基甲酸乙酯组成的组中选出，并可带有侧链； R5 是具有 50 个或更少碳原子的烷基；在通式（1）所代表的化合物中，R4-[COOR5] 基团可以是由以下通式（1-1）所代表的内酯结构。 (Rx 是具有 2 至 10 个碳原子的烃基，可以是支链。
• METHOD FOR SEPARATING POLYMER SOLUTION AND WATER
  申请人：Zeon Corporation

  公开号：EP3275523B1

  公开（公告）日：2020-06-17
• JP2001040249A
  申请人：——

  公开号：JP2001040249A

  公开（公告）日：2001-02-13