1-Brom-dodecafluor-6-iod-hexan | 2378-61-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: 1-Brom-dodecafluor-6-iod-hexan
• 英文别名: 1-iodo-6-bromoperfluorohexane；1-Bromo-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-6-iodohexane
• CAS: 2378-61-2
• 化学式: C₆BrF₁₂I
• 分子量: 506.855
• InChiKey: UBHMDWWSILLBDK-UHFFFAOYSA-N

物化性质

• 沸点：
  182.8±8.0 °C(Predicted)
• 密度：
  2.250±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1-Brom-dodecafluor-6-iod-hexan 、 苯硫酚 以56%的产率得到
  参考文献：
  名称：

  SU, DEBAO;CHEN, QINGYUN;ZHU, RONGXIAN, ORG. CHEM., 1986, N 2, 112-120

  摘要：

  DOI：

文献信息

• FLUORINE-CONTAINING CROSSLINKABLE ELASTOMER COMPOSITION AND CROSSLINKED PRODUCT THEREOF
  申请人：Asahi Glass Company, Limited

  公开号：EP3031856A1

  公开（公告）日：2016-06-15

  To provide a crosslinkable fluorinated elastomer composition which is excellent in crosslinking reactivity and of which a crosslinked product is excellent in heat resistance and chemical resistance. The crosslinkable fluorinated elastomer composition comprises a fluorinated elastomer (e.g. a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer) and an aromatic compound having at least two crosslinkable unsaturated double bonds (e.g. a compound represented by the formula (A-1)), and the crosslinked product is one obtained by crosslinking the crosslinkable fluorinated elastomer composition.

  提供一种可交联含氟弹性体组合物，该组合物具有优异的交联反应性，其交联产品具有优异的耐热性和耐化学性。可交联含氟弹性体组合物由含氟弹性体（例如四氟乙烯/全氟（烷基乙烯基醚）共聚物）和至少具有两个可交联不饱和双键的芳香族化合物（例如由式（A-1）表示的化合物）组成，交联产物是通过交联该可交联含氟弹性体组合物获得的。
• FLUORORUBBER MOLDED ARTICLE
  申请人：Asahi Glass Company, Limited

  公开号：EP3124542A1

  公开（公告）日：2017-02-01

  To provide a fluororubber molded article which is inexpensive and excellent in fuel barrier properties against an alcohol-containing fuel. A fluororubber molded article obtained by molding and crosslinking a cross-linkable composition comprising a fluoroelastomer (A) and a fluoroelastomer (B), wherein the fluoroelastomer (A) is a copolymer comprising tetrafluoroethylene units and perfluorovinyl ether units represented by CF2=CF-O-Rf (Rf is a C1-20 perfluoroalkyl group or a C2-20 perfluoroalkyl group having an etheric oxygen atom between carbon atoms), the fluoroelastomer (B) is a copolymer comprising tetrafluoroethylene units, propylene units and vinylidene fluoride units, and the mass ratio of (A)/(B) is from 99/1 to 30/70.

  提供一种价格低廉且对含酒精燃料具有优异阻燃性能的氟橡胶模制件。通过模塑和交联由氟橡胶（A）和氟弹性体（B）组成的可交联组合物而获得的氟橡胶模塑制品，其中氟橡胶（A）是由四氟乙烯单元和全氟乙烯基醚单元组成的共聚物，全氟乙烯基醚单元用 CF2=CF-O-Rf 表示（Rf 是 C1-20 全氟烷基或在碳原子之间有一个醚氧原子的 C2-20 全氟烷基）、氟弹性体 (B) 是由四氟乙烯单元、丙烯单元和偏氟乙烯单元组成的共聚物，(A)/(B) 的质量比为 99/1 至 30/70。
• METHOD FOR PRODUCING CROSSLINKED PRODUCT AND FLUOROELASTOMER COMPOSITION
  申请人：Asahi Glass Company, Limited

  公开号：EP3366721A1

  公开（公告）日：2018-08-29

  To provide a method for producing a crosslinked product of a fluoroelastomer having no hydrogen atom bonded to a carbon atom, by which formation of white foreign matters is suppressed, and a fluoroelastomer composition suitable for the production method. A method for producing a crosslinked product, which comprises crosslinking a fluoroelastomer composition containing a fluoroelastomer having no hydrogen atom bonded to a carbon atom, such as a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, and a fatty acid metal salt having a melting point of less than 200°C, at a crosslinking temperature higher than the melting point of the fatty acid metal salt, and a fluoroelastomer composition containing the fluoroelastomer and a fatty acid metal salt having a melting point of less than 200°C.

  提供一种生产碳原子上无氢原子键的氟弹性体交联产品的方法，通过该方法可抑制白色异物的形成，并提供一种适用于该生产方法的氟弹性体组合物。 一种生产交联产品的方法，包括在高于脂肪酸金属盐熔点的交联温度下，交联含有无氢原子键合碳原子的氟弹性体（如四氟乙烯/全氟（烷基乙烯基醚）共聚物）和熔点低于 200°C 的脂肪酸金属盐的氟弹性体组合物，以及含有氟弹性体和熔点低于 200°C 的脂肪酸金属盐的氟弹性体组合物。
• FLUORINE-CONTAINING ELASTIC COPOLYMER COMPOSITION, PAINT, AND PAINTED ARTICLE
  申请人：AGC Inc.

  公开号：EP3696226A1

  公开（公告）日：2020-08-19

  To provide a fluorinated elastic copolymer composition such that solubility of a fluorinated elastic copolymer in a solvent is excellent, the solvent is easily removed, and the solvent is easily available. A fluorinated elastic copolymer composition comprising a fluorinated elastic copolymer having units based tetrafluoroethylene and units based on CF2=CFORf1 (wherein Rf1 is a C1-10 perfluoroalkyl group), and a fluorinated solvent having a perfluorohydrocarbon group, wherein the perfluorohydrocarbon group having the largest number of carbon atoms in the fluorinated solvent has from 3 to 7 carbon atoms, the fluorinated solvent has a boiling point of from 50 to 160°C, and the fluorinated solvent has a fluorine atom content (fluorine atom content (mass%) = (19 × number of fluorine atoms in the fluorinated solvent/molecular weight of the fluorinated solvent) × 100) of from 69 to 80 mass%.

  提供一种氟化弹性共聚物组合物，使氟化弹性共聚物在溶剂中的溶解性极佳，溶剂易于去除，且溶剂易于获得。 一种含氟弹性共聚物组合物，包括一种含氟弹性共聚物，该共聚物具有以四氟乙烯为基础的单元和以 CF2=CFORf1 （其中 Rf1 为 C1-10 全氟烷基）为基础的单元，以及一种具有全氟烃基的含氟溶剂，其中在含氟溶剂中碳原子数最多的全氟烃基具有 3 至 7 个碳原子、氟化溶剂的沸点为 50 至 160°C，氟化溶剂的氟原子含量（氟原子含量（质量％）＝（19×氟化溶剂中的氟原子数/氟化溶剂的分子量）×100）为 69 至 80 质量％。
• PRODUCTION METHOD FOR LAMINATE, AND LAMINATE
  申请人：AGC Inc.

  公开号：EP3693161A1

  公开（公告）日：2020-08-12

  To provide a laminate excellent in alkali resistance and interlaminar strength at high temperature, and a process for producing the laminate. A process for producing a laminate, comprising producing a non-crosslinked laminate having a layer of a first composition containing a copolymer having fluorine atoms and a layer of a second composition containing a non-fluorinated elastic polymer, and crosslinking the first composition and the second composition to produce a laminate having a first layer formed of a crosslinked product of the first composition and a second layer formed of a crosslinked product of the second composition, wherein when the first composition and the second composition contains a common crosslinking aid, the absolute value of the crosslinking rate difference between the first composition and the second composition is at most 0.30.

  提供一种在高温下具有优异耐碱性和层间强度的层压板，以及一种生产该层压板的工艺。 一种生产层压板的工艺，包括生产一种非交联层压板，该层压板具有一层含有氟原子的共聚物的第一组合物和一层含有非氟弹性聚合物的第二组合物、和交联第一组合物和第二组合物，以生产具有由第一组合物的交联产物形成的第一层和由第二组合物的交联产物形成的第二层的层压板，其中当第一组合物和第二组合物含有共同的交联助剂时，第一组合物和第二组合物之间的交联速率差的绝对值至多为 0。30.