6,7-di-O-methylipecoside tetraacetate | 73590-01-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 6,7-di-O-methylipecoside tetraacetate
• 英文别名: 6-Di-O-methylipecoside tetraacetate；Dimethyltetraacetylipecosid；(4S)-4r-((R)-2-acetyl-6,7-dimethoxy-1,2,3,4-tetrahydro-[1]isoquinolylmethyl)-6t-(tetra-O-acetyl-β-D-glucopyranosyloxy)-5c-vinyl-5,6-dihydro-4H-pyran-3-carboxylic acid methyl ester；(4S)-4r-((R)-2-Acetyl-6,7-dimethoxy-1,2,3,4-tetrahydro-[1]isochinolylmethyl)-6t-(tetra-O-acetyl-β-D-glucopyranosyloxy)-5c-vinyl-5,6-dihydro-4H-pyran-3-carbonsaeure-methylester
• CAS: 73590-01-9
• 化学式: C₃₇H₄₇NO₁₆
• 分子量: 761.777
• InChiKey: YHMQETZOEUFOJF-KMZJXKSMSA-N

反应信息

• 作为反应物：
  描述：

  6,7-di-O-methylipecoside tetraacetate 在 lead(IV) acetate 作用下， 以 溶剂黄146 为溶剂， 反应 6.0h， 生成 (4S,5R,6S)-4-((R)-2-Acetyl-4-hydroxy-6,7-dimethoxy-1,2,3,4-tetrahydro-isoquinolin-1-ylmethyl)-6-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-5-vinyl-5,6-dihydro-4H-pyran-3-carboxylic acid methyl ester
  参考文献：
  名称：

  Tetrahydroisoquinoline-monoterpene glycosides from Cephaelis acuminata

  摘要：

  From the dried roots of Cephaelis acuminata, five tetrahydroisoquinoline-monoterpene glycosides, 2-O-beta-D-glucopyranosyldemethylalangiside, demethylisoalangiside, 6"-O-beta-D-glucopyranosylipecoside, 6"-O-alpha-D-glucopyranosylipecoside and (4R)4-hydroxyipecoside, were isolated. The structures of these glycosides were determined by spectroscopic and chemical means. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(01)00418-6
• 作为产物：
  描述：

  乙酸酐 、 6,7-Di-O-methylipecoside 以 吡啶 为溶剂， 以23%的产率得到6,7-di-O-methylipecoside tetraacetate
  参考文献：
  名称：

  Hoefle, Gerhard; Nagakura, Naotaka; Zenk, Meinhart H., Chemische Berichte, 1980, vol. 113, # 2, p. 566 - 576

  摘要：

  DOI：

文献信息

• Bellet, Annales Pharmaceutiques Francaises, 1954, vol. 12, p. 466,467
  作者：Bellet

  DOI：——

  日期：——
• Hoefle et al., Chemische Berichte, <hi>1980</hi>, vol. 113, p. 566,575
  作者：Hoefle et al.

  DOI：——

  日期：——