5-(4-salicylideneaminophenyl)-10,15,20-triphenylporphyrinatonickel(II) | 288370-60-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 5-(4-salicylideneaminophenyl)-10,15,20-triphenylporphyrinatonickel(II)
• CAS: 288370-60-5
• 化学式: C₅₁H₃₃N₅NiO
• 分子量: 790.546
• InChiKey: HKJPWZHWLQEWRX-NJLIRLSYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5-(p-aminophenyl)-10,15,20-triphenylporphine 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 生成 5-(4-salicylideneaminophenyl)-10,15,20-triphenylporphyrinatonickel(II)
  参考文献：
  名称：

  Synthesis and characterization of unsymmetrically tetrasubstituted porphyrin and their nickel (II) complexes with the crystal structure of 5,15-bis(4-aminophenyl)-10, 20-diphenylporphyrinatonickel(II)

  摘要：

  New unsymmetrically tetrasubstituted porphyrin-Schiff base ligands (8-10) containing recognition sites for alkali and transition metal quest cations have been synthesized by the condensations of 5-(4-aminophenyl)-10,15,20- triphenylporphyrin (5) with salycylaldehyde, 2-hydroxy-1-naphthaldehyde and 4'-hydroxy-5'-formyl-benzo-15-crown-5. Homonuclear crystalline 1:1 [Ni(II): ligand] complexes (8a-10a) of the ligands with Ni(CH2COO)(2). 4H(2)O have been obtained. The porphyrin ligands and their complexes have been characterized by elemental analysis, IR, UV-VIS, H-1, C-13 NMR and MS, and the structure of trans-5,15-bis(4-aminophenyl)-10,20-diphenylporphyrinato-nickel(II) (7a) has been examined crystallographically. It crystallizes in the monoclinic space group C2/c with a = 22.096(2), b = 13.455(1), c = 15.599(1) Angstrom, beta = 134.81(1)degrees, V = 3290.6(2) Angstrom(3), Z = 4 and D-x = 1.42 g cm(-3). The molecule is centrosymmetric and the porphine nucleus is non-planar. The average value for the diameter of the hole has been estimated as 3.830(4) Angstrom. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(00)00417-8