| 1215023-49-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• CAS: 1215023-49-6
• 化学式: C₃₁H₃₄O₄
• 分子量: 470.609
• InChiKey: OILNONKEVSCNAB-KFWFGDKJSA-N

反应信息

• 作为反应物：
  描述：

  、 氯化苄 在 四丁基溴化铵 、 sodium hydroxide 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 48.0h， 以430 mg的产率得到(1R,2S,3R,3aS,4R,7aS)-1,2,3-tris(phenylmethoxy)-4-(phenylmethoxymethyl)-2,3,3a,4,5,7a-hexahydro-1H-indene
  参考文献：
  名称：

  Sugar allyltins in the synthesis of carbohydrate mimics. Study on the cis-hydroxylation of the bicyclo[4.3.0]nonenes derived from d-mannose

  摘要：

  Sugar allyltin derivatives were applied in the synthesis of highly oxygenated hydrindane system. The transformation of organometallic derived from D-mannose into two diastereoisomeric bicyclo[4.3.0]nonenes with the trans geometry between both the rings was realized in a few well-defined steps. The functionalization of these synthons provided a wide range of polyhydroxylated hydrindane derivatives. The stereochemical aspects of these processes are discussed. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2009.11.008
• 作为产物：
  描述：

  1(S),5(R),6(R),7(R),8(S),9(R)-7,8,9-tri-benzyloxy-5-methoxycarbonyl-bicyclo[4,3,0]non-2-ene 在 lithium aluminium tetrahydride 、 水 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Sugar allyltins in the synthesis of carbohydrate mimics. Study on the cis-hydroxylation of the bicyclo[4.3.0]nonenes derived from d-mannose

  摘要：

  Sugar allyltin derivatives were applied in the synthesis of highly oxygenated hydrindane system. The transformation of organometallic derived from D-mannose into two diastereoisomeric bicyclo[4.3.0]nonenes with the trans geometry between both the rings was realized in a few well-defined steps. The functionalization of these synthons provided a wide range of polyhydroxylated hydrindane derivatives. The stereochemical aspects of these processes are discussed. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2009.11.008