(3R,3aR,5bR,9aR,10bS)-3a,5b-Dimethyl-3-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-1,2,3,3a,4,5,5b,6,7,9,9a,10b-dodecahydro-10-oxa-cyclopenta[a]fluoren-8-one | 116359-72-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (3R,3aR,5bR,9aR,10bS)-3a,5b-Dimethyl-3-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-1,2,3,3a,4,5,5b,6,7,9,9a,10b-dodecahydro-10-oxa-cyclopenta[a]fluoren-8-one
• CAS: 116359-72-9
• 化学式: C₂₆H₄₀O₂
• 分子量: 384.602
• InChiKey: NIIOJEQPPAWOLW-LPFOVQRFSA-N

反应信息

• 作为反应物：
  描述：

  (3R,3aR,5bR,9aR,10bS)-3a,5b-Dimethyl-3-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-1,2,3,3a,4,5,5b,6,7,9,9a,10b-dodecahydro-10-oxa-cyclopenta[a]fluoren-8-one 在 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 反应 4.0h， 生成 (1R,3aS,5aR,9aS,12aR)-9a,12a-Dimethyl-1-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-decahydro-5-oxa-benzo[a]cyclopenta[e]cyclononene-4,7,10-trione
  参考文献：
  名称：

  Heterosteroids via Organoiron Complexes: Enantioselectine Synthesis of the 9-(4-Keto-1-methylcyclohex-2-enyl)-8-keto-des-AB-ergosta-14,15-22,23-diene; An Easy Rearrangement of the Title Compound into a 6-Oxo-B-nor-heterosteroid Structure

  摘要：

  DOI：

  10.3987/com-87-4402
• 作为产物：
  描述：

  (1R,3aS,5S,7aR)-7a-Methyl-5-((S)-1-methyl-4-oxo-cyclohex-2-enyl)-1-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-octahydro-inden-4-one 在 sodium methylate 作用下， 以 甲醇 为溶剂， 反应 3.0h， 生成 (3R,3aR,5bR,9aR,10bS)-3a,5b-Dimethyl-3-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-1,2,3,3a,4,5,5b,6,7,9,9a,10b-dodecahydro-10-oxa-cyclopenta[a]fluoren-8-one
  参考文献：
  名称：

  Heterosteroids via Organoiron Complexes: Enantioselectine Synthesis of the 9-(4-Keto-1-methylcyclohex-2-enyl)-8-keto-des-AB-ergosta-14,15-22,23-diene; An Easy Rearrangement of the Title Compound into a 6-Oxo-B-nor-heterosteroid Structure

  摘要：

  DOI：

  10.3987/com-87-4402