ruthenium(II) 10-(2-hydroxymethyleneoxyphenylene)-2,18-diethyl-3,17-dimethylporphyrinate (CO)(H2O) | 1444310-70-6

• 英文名称: ruthenium(II) 10-(2-hydroxymethyleneoxyphenylene)-2,18-diethyl-3,17-dimethylporphyrinate (CO)(H2O)
• 英文别名: ruthenium(II) 10-(2-hydroxymethyleneoxyphenylene)-2,18-diethyl-3,17-dimethylporphyrinate (CO)(H₂O)
• CAS: 1444310-70-6
• 化学式: C₃₄H₃₂N₄O₄Ru
• 分子量: 661.722
• InChiKey: QSBAQGJYOKWMQR-VXXZREKLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,4'-diethyl-3,3'-dimethyl-5,5'-methanediyl-bis-pyrrole-2-carbaldehyde 在 氢溴酸 、 苯酚 作用下， 以 乙醇 为溶剂， 反应 2.05h， 生成 ruthenium(II) 10-(2-hydroxymethyleneoxyphenylene)-2,18-diethyl-3,17-dimethylporphyrinate (CO)(H2O)
  参考文献：
  名称：

  Complexation of zinc(II) and ruthenium(II) porphyrinates with methyl glycinate and methyl m-aminobenzoate

  摘要：

  Zinc(II) and ruthenium(II) monohydroxyporphyrinates with a different arrangement of the reaction center in the meso-aryl moiety of the macrocycle were synthesized, and their ability of complexing with the methyl esters of glycine and m-aminobenzoic acid in toluene were studied using the methods of spectrophotometric titration and H-1 NMR spectroscopy. The stability constants of the resulting complexes and concentration ranges of their existence were determined.

  DOI：

  10.1134/s1070363213050204