6-O-imidazoylthiocarbonylpseudokobusine | 136904-50-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 6-O-imidazoylthiocarbonylpseudokobusine
• CAS: 136904-50-2
• 化学式: C₂₄H₂₉N₃O₃S
• 分子量: 439.579
• InChiKey: PRNWCTNRHGRBEB-AMONMNIJSA-N

反应信息

• 作为反应物：
  描述：

  6-O-imidazoylthiocarbonylpseudokobusine 在 三正丁基氢锡 作用下， 以 二氯甲烷 为溶剂， 反应 7.0h， 以89%的产率得到kobusine
  参考文献：
  名称：

  Studies on Aconitum Species. XIV. Deoxygenation of Pseudokobusine to Kobusine

  摘要：

  Pseudokobusine (1) was deoxygenated through conversion into the imidazoylthiocarbonyl derivative with N,N'-thiocarbonyldiimidazole and then treated with tri-n-butylstannane. This reaction sequence produced kobusine (2) in a good yield.

  DOI：

  10.3987/com-91-5705
• 作为产物：
  描述：

  Pseudokobusine 、 N,N'-硫羰基二咪唑 以 二氯甲烷 为溶剂， 反应 21.0h， 以94%的产率得到6-O-imidazoylthiocarbonylpseudokobusine
  参考文献：
  名称：

  Studies on Aconitum Species. XIV. Deoxygenation of Pseudokobusine to Kobusine

  摘要：

  Pseudokobusine (1) was deoxygenated through conversion into the imidazoylthiocarbonyl derivative with N,N'-thiocarbonyldiimidazole and then treated with tri-n-butylstannane. This reaction sequence produced kobusine (2) in a good yield.

  DOI：

  10.3987/com-91-5705