(5S,7S)-5-{(S)-[(1R,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-2,3,5,6,7,7a-hexahydro-1H-inden-4-yl]-hydroxy-methyl}-7-hydroxy-2-phenyl-5,6,7,8,9,10-hexahydro-[1,2,4]triazolo[1,2-b]phthalazine-1,3-dione | 82890-35-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (5S,7S)-5-{(S)-[(1R,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-2,3,5,6,7,7a-hexahydro-1H-inden-4-yl]-hydroxy-methyl}-7-hydroxy-2-phenyl-5,6,7,8,9,10-hexahydro-[1,2,4]triazolo[1,2-b]phthalazine-1,3-dione
• CAS: 82890-35-5
• 化学式: C₃₅H₄₉N₃O₄
• 分子量: 575.792
• InChiKey: RZJVQKDEYAQUQX-NZOBIKPJSA-N

反应信息

• 作为产物：
  描述：

  (5S,7S)-5-[(1R,2'R,3aR,4R,7aR)-7a-methyl-1-[(2R)-6-methylheptan-2-yl]spiro[2,3,3a,5,6,7-hexahydro-1H-indene-4,3'-oxirane]-2'-yl]-7-hydroxy-2-phenyl-5,6,7,8,9,10-hexahydro-[1,2,4]triazolo[1,2-b]phthalazine-1,3-dione 在 溶剂黄146 、 sodium iodide 、 锌 作用下， 以 乙二醇二甲醚 为溶剂， 反应 6.0h， 以40%的产率得到(5S,7S)-5-{(S)-[(1R,7aR)-1-((R)-1,5-Dimethyl-hexyl)-7a-methyl-2,3,5,6,7,7a-hexahydro-1H-inden-4-yl]-hydroxy-methyl}-7-hydroxy-2-phenyl-5,6,7,8,9,10-hexahydro-[1,2,4]triazolo[1,2-b]phthalazine-1,3-dione
  参考文献：
  名称：

  Zur gezielten Oxidation der ?7-Doppelbindung in den 4-Phenyl-1,2,4-triazolin-3,5-dion-Addukten des Vitamin D3

  摘要：

  DOI：

  10.1007/bf00799919