gibberellin A₄-17-yl-1'-(1'-thia)propan-3'-ol | 142629-28-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: gibberellin A₄-17-yl-1'-(1'-thia)propan-3'-ol
• CAS: 142629-28-5
• 化学式: C₂₁H₃₀O₆S
• 分子量: 410.532
• InChiKey: JRPZPENTUKNJQQ-ZXLXPPNOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.92
• 重原子数：
  28.0
• 可旋转键数：
  5.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  104.06
• 氢给体数：
  3.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  gibberellin A₄-17-yl-1'-(1'-thia)propan-3'-ol 在 三乙胺 chloroamine-T 、 sodium iodide 作用下， 以 水 、 乙腈 为溶剂， 反应 41.0h， 生成 gibberellin A₄-17-yl-1'-(1'-thia)propan-3'-ol-4-azido-5-iodosalicylate
  参考文献：
  名称：

  Photoaffinity probes for gibberellin-binding proteins

  摘要：

  A rational approach to the design, synthesis and radiolabelling, with either H-3 or I-125, of gibberellin A4 (GA4) derivatives containing C-17-arylazido functionalities is described. The potential of these compounds as photoaffinity reagents for GA-binding proteins and GA receptors in Avena fatua aleurone protoplasts has been evaluated and is compared with that of the enone derived from GA3.

  DOI：

  10.1016/0031-9422(92)83087-f
• 作为产物：
  描述：

  赤霉素 A4 、 2-巯基乙醇 在 α-azoisobutyronitrile 、 三丁基氧化锡 作用下， 生成 gibberellin A₄-17-yl-1'-(1'-thia)propan-3'-ol
  参考文献：
  名称：

  Photoaffinity probes for gibberellin-binding proteins

  摘要：

  A rational approach to the design, synthesis and radiolabelling, with either H-3 or I-125, of gibberellin A4 (GA4) derivatives containing C-17-arylazido functionalities is described. The potential of these compounds as photoaffinity reagents for GA-binding proteins and GA receptors in Avena fatua aleurone protoplasts has been evaluated and is compared with that of the enone derived from GA3.

  DOI：

  10.1016/0031-9422(92)83087-f