4-[(4-dodecoxyphenyl)methoxy]-2-hydroxybenzaldehyde | 191987-85-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-[(4-dodecoxyphenyl)methoxy]-2-hydroxybenzaldehyde
• CAS: 191987-85-6
• 化学式: C₂₆H₃₆O₄
• 分子量: 412.569
• InChiKey: AEIMAUHARZMWIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.08
• 重原子数：
  30.0
• 可旋转键数：
  16.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  55.76
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  3-氨基-1-丙醇 、 4-[(4-dodecoxyphenyl)methoxy]-2-hydroxybenzaldehyde 以 乙醇 为溶剂， 反应 3.0h， 以92%的产率得到
  参考文献：
  名称：

  Smectic Bimetallomesogens: Synthesis and Mesomorphic Properties in Oxygen-Bridged Dicopper and Divanadyl Complexes

  摘要：

  AbstractThe synthesis and mesomorphic properties of a homologous series of N‐(3‐hydroxypropyl)‐4‐alkoxylsalicylaldimine, N‐(3‐hydroxypropyl)‐4‐(4′‐alkoxybenzoxy)salicylaldimine, and their dicopper(II) and di‐oxovanadium(VI) complexes are reported. Copper complexes exhibited monotropic smectic A phases; however, vanadyl complexes showed no mesomorphism. A systematic comparison revealed that the meso‐genie behaviors of these bimetallic complexes are induced by the weak intermolecular force and determined mainly by the central metal. The effects on the structural variations near the metal central cores and side chain density are also discussed.

  DOI：

  10.1002/jccs.199700014
• 作为产物：
  描述：

  4-正十二烷氧基苯甲酸甲酯 在 lithium aluminium tetrahydride 、 氯化亚砜 、 potassium hydrogencarbonate 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 反应 25.67h， 生成 4-[(4-dodecoxyphenyl)methoxy]-2-hydroxybenzaldehyde
  参考文献：
  名称：

  Smectic Bimetallomesogens: Synthesis and Mesomorphic Properties in Oxygen-Bridged Dicopper and Divanadyl Complexes

  摘要：

  AbstractThe synthesis and mesomorphic properties of a homologous series of N‐(3‐hydroxypropyl)‐4‐alkoxylsalicylaldimine, N‐(3‐hydroxypropyl)‐4‐(4′‐alkoxybenzoxy)salicylaldimine, and their dicopper(II) and di‐oxovanadium(VI) complexes are reported. Copper complexes exhibited monotropic smectic A phases; however, vanadyl complexes showed no mesomorphism. A systematic comparison revealed that the meso‐genie behaviors of these bimetallic complexes are induced by the weak intermolecular force and determined mainly by the central metal. The effects on the structural variations near the metal central cores and side chain density are also discussed.

  DOI：

  10.1002/jccs.199700014