| 190125-33-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• CAS: 190125-33-8
• 化学式: C₁₂H₂₄KO₆*C₄₅H₄₅MnN₅
• 分子量: 1014.24
• InChiKey: AHPOJVHGKWEAKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  乙二醇二甲醚 、 以 乙二醇二甲醚 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, derivatization, and structural characterization of [Mn(CNC6H3Me2-2,6)5] −, a five-coordinate isonitrilate complex containing Mn−I

  摘要：

  萘还原 [锰(数控 6 H 3 我 2 -2,6) 5 Cl]形式 三方双锥解 [锰(数控 6 H 3 我 2 -2,6) 5 ] - ，通过 X 射线衍射研究确定 [K(18-C-6)(dme)] + 盐和衍生化 氯化亚锡 3 给予 [锰(数控 6 H 3 我 2 -2,6) 5 (SnPh 3 )]。

  DOI：

  10.1039/a700089h
• 作为产物：
  描述：

  potassium naphthalenide 、 三苯基氯化锡 、 18-冠醚-6 、 以 四氢呋喃 为溶剂， 以53%的产率得到
  参考文献：
  名称：

  Synthesis, derivatization, and structural characterization of [Mn(CNC6H3Me2-2,6)5] −, a five-coordinate isonitrilate complex containing Mn−I

  摘要：

  萘还原 [锰(数控 6 H 3 我 2 -2,6) 5 Cl]形式 三方双锥解 [锰(数控 6 H 3 我 2 -2,6) 5 ] - ，通过 X 射线衍射研究确定 [K(18-C-6)(dme)] + 盐和衍生化 氯化亚锡 3 给予 [锰(数控 6 H 3 我 2 -2,6) 5 (SnPh 3 )]。

  DOI：

  10.1039/a700089h

文献信息

• Formation of the 1,4-Diazabutadien-2-yl Complex [Mn(CNPh*)₄{C(NPh*)C(CH₃)N(Ph*)}] through Methylation of a Manganese(−I) Isonitrilate
  作者：Tracy L. Utz、Patricia A. Leach、Steven J. Geib、N. John Cooper

  DOI：10.1021/om970287h

  日期：1997.9.1

  Alkylation of [Mn(CNPh*)(5)](-) with CH3I gives the 1,4-diazabutadien-2-yl complex [Mn(CNPh*)(4)C(=NPh*)C(CH3)=N(Ph*)}] (2) in a 30% yield, as established by a single-crystal X-ray diffraction study. The same product can be obtained in poor yield when CH3OSO2CF3 is used as the alkylating agent,;Ind use of ethyl iodide gives the corresponding ethyl complex [Mn(CNPh*)(4)C(=NPh*)C(CH2CH3)=N(Ph*)}] (3). It is proposed that the first step in the formation of 2 is alkylation at manganese: transient [Mn(CNPh*)(5)CH3] is then converted into an iminoacyl complex by isonitrile/alkyl insertion. Insertion of a second isonitrile into the metal-iminoacyl bond leads to the 1,4-diazabutadien-2-yl complex. The addition of free CNPh* to the reaction solution leads to only a modest increase in the yield of 2, but the importance of exogenous isonitrile is supported by the formation of [Mn((CNBu)-Bu-t)(CNPh*)(3)C(=NPh*)C(CH3)=N(Ph*)}] (4), in which 1 equiv of (CNBu)-Bu-t is coordinated to Mn, when (CNBu)-Bu-t is added to a solution of 1(-) before reaction with CH3I.