1-(4-(1,4-dioxaspiro[4.5]decan-8-yl)cyclohex-1-enyl)pyrrolidine | 1268275-20-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(4-(1,4-dioxaspiro[4.5]decan-8-yl)cyclohex-1-enyl)pyrrolidine
• 英文别名: 1-[4-(1,4-dioxaspiro[4.5]decan-8-yl)cyclohexen-1-yl]pyrrolidine
• CAS: 1268275-20-2
• 化学式: C₁₈H₂₉NO₂
• 分子量: 291.434
• InChiKey: YLGAEJWPHAIISE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(4-(1,4-dioxaspiro[4.5]decan-8-yl)cyclohex-1-enyl)pyrrolidine 在 palladium on activated charcoal 甲酸 、 potassium tert-butylate 、 氨 、 氢气 、 lithium 作用下， 以 四氢呋喃 、 乙醇 、 甲苯 为溶剂， 反应 32.5h， 生成 2-(4-(methoxymethylene)cyclohexyl)-6-propyldecahydronaphthalene
  参考文献：
  名称：

  DECAHYDRONAPHTHALENE COMPOUNDS, LIQUID CRYSTAL COMPOSITIONS CONTAINING THE COMPOUNDS, AND LIQUID CRYSTAL DISPLAY DEVICES CONTAINING THE LIQUID CRYSTAL COMPOSITIONS

  摘要：

  公开号：

  EP2468707B1
• 作为产物：
  描述：

  四氢吡咯 、 双环己酮乙二醇单缩酮 以 甲苯 为溶剂， 反应 3.0h， 生成 1-(4-(1,4-dioxaspiro[4.5]decan-8-yl)cyclohex-1-enyl)pyrrolidine
  参考文献：
  名称：

  DECAHYDRONAPHTHALENE COMPOUNDS, LIQUID CRYSTAL COMPOSITIONS CONTAINING THE COMPOUNDS, AND LIQUID CRYSTAL DISPLAY DEVICES CONTAINING THE LIQUID CRYSTAL COMPOSITIONS

  摘要：

  公开号：

  EP2468707B1

文献信息

• DECAHYDRONAPHTHALENE COMPOUND, LIQUID CRYSTAL COMPOSITION INCLUDING THE COMPOUND AND LIQUID CRYSTAL DISPLAY DEVICE CONTAINING THE LIQUID CRYSTAL COMPOSITION
  申请人：Masukawa Tokifumi

  公开号：US20120145959A1

  公开（公告）日：2012-06-14

  A compound represented by the formula (1) is provided. In the formula (1), for example, R 1 and R 2 are alkyl having 1 to 10 carbons, alkoxy having 1 to 9 carbons or alkenyl having 2 to 10 carbons; the ring A and the ring B are 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 2 are a single bond and Z 3 is —CH 2 O— or —OCH 2 —; Y 1 and Y 2 are halogen, —CF 3 , —CHF 2 , —CH 2 F, —OCF 3 , —OCHF 2 or —OCH 2 F; and m and n is 0, 1 or 2, p is 1 or 2, and the sum of m, n and p is 1, 2 or 3.

  提供了一个由式（1）表示的化合物。在式（1）中，例如，R1和R2是具有1至10个碳的烷基，具有1至9个碳的烷氧基或具有2至10个碳的烯基；环A和环B是1,4-环己基或1,4-苯基；Z1和Z2是单键，Z3是—CH2O—或—OCH2—；Y1和Y2是卤素，—CF3，—CHF2，—CH2F，—O ，—O 或—O ；m和n为0、1或2，p为1或2，m、n和p的总和为1、2或3。
• Decahydronaphthalene compound, liquid crystal composition including the compound and liquid crystal display device containing the liquid crystal composition
  申请人：Masukawa Tokifumi

  公开号：US08465674B2

  公开（公告）日：2013-06-18

  A compound represented by the formula (1) is provided. In the formula (1), for example, R1 and R2 are alkyl having 1 to 10 carbons, alkoxy having 1 to 9 carbons or alkenyl having 2 to 10 carbons; the ring A and the ring B are 1,4-cyclohexylene or 1,4-phenylene; Z1 and Z2 are a single bond and Z3 is —CH2O— or —OCH2—; Y1 and Y2 are halogen, —CF3, —CHF2, —CH2F, —OCF3, —OCHF2 or —OCH2F; and m and n is 0, 1 or 2, p is 1 or 2, and the sum of m, n and p is 1, 2 or 3.

  提供一种由公式（1）表示的化合物。在公式（1）中，例如，R1和R2是具有1至10个碳的烷基，具有1至9个碳的烷氧基或具有2至10个碳的烯基;环A和环B是1,4-环己烯基或1,4-苯基;Z1和Z2是单键，Z3是-CH2O-或-OCH2-;Y1和Y2是卤素，-CF3，-CHF2，-CH2F，-O ，-O 或-O ; m和n为0、1或2，p为1或2，m、n和p的和为1、2或3。
• DECAHYDRONAPHTHALENE COMPOUNDS, LIQUID CRYSTAL COMPOSITIONS CONTAINING THE COMPOUNDS, AND LIQUID CRYSTAL DISPLAY ELEMENTS CONTAINING THE LIQUID CRYSTAL COMPOSITIONS
  申请人：JNC Corporation

  公开号：EP2468707A1

  公开（公告）日：2012-06-27

  Subject The subject is to provide a liquid crystal compound not only having a large negative dielectric anisotropy (Δε) and a high maximum temperature of a nematic phase (TNI), but also having at least one of characteristics such as stability to heat, light or the like, a suitable refractive index anisotropy (Δn) and an excellent compatibility with other liquid crystal compounds. Means for Solving the Subject The invention provides a compound represented by the formula (1). In the formula (1), for example, R1 and R2 are alkyl having 1 to 10 carbons, alkoxy having 1 to 9 carbons or alkenyl having 2 to 10 carbons; the ring A and the ring B are 1,4-cyclohexylene or 1,4-phenylene; Z1 and Z2 are a single bond and Z3 is -CH2O- or -OCH2 -; Y1 and Y2 are halogen, -CF3, -CHF2, -CH2F, -OCF3, -OCHF2 or -OCH2F; and m and n is 0, 1 or 2, p is 1 or 2, and the sum of m, n and p is 1, 2 or 3.

  主题 本课题旨在提供一种液晶化合物，该化合物不仅具有较大的负介电各向异性（Δε）和较高的向列相（TNI）最高温度，而且还具有对热、光或类似物的稳定性、适当的折射率各向异性（Δn）以及与其他液晶化合物的良好兼容性等特性中的至少一种。 解决本课题的方法 本发明提供了一种由式（1）表示的化合物。 例如，在式 (1) 中，R1 和 R2 是具有 1 至 10 个碳原子的烷基、具有 1 至 9 个碳原子的烷氧基或具有 2 至 10 个碳原子的烯基；环 A 和环 B 是 1,4-环己烯或 1,4-亚苯基；Z1和Z2为单键，Z3为-CH2O-或-OCH2-；Y1和Y2为卤素、-CF3、-CHF2、-CH2F、-O 、-O 或-O ；m和n为0、1或2，p为1或2，m、n和p之和为1、2或3。
• US8465674B2
  申请人：——

  公开号：US8465674B2

  公开（公告）日：2013-06-18