3-ethyl-7,11-dimethyl-dodecan-1-ol | 1218784-37-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3-ethyl-7,11-dimethyl-dodecan-1-ol
• 英文别名: 3-Ethyl-7,11-dimethyldodecan-1-ol
• CAS: 1218784-37-2
• 化学式: C₁₆H₃₄O
• 分子量: 242.445
• InChiKey: DOHYQMCRXQZSMU-UHFFFAOYSA-N

物化性质

• 沸点：
  293.7±8.0 °C(Predicted)
• 密度：
  0.832±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-ethyl-7,11-dimethyl-dodecanal 在 Nickel on Kieselguhr 氢气 作用下， 以 四氢呋喃 为溶剂， 150.0 ℃ 、7.0 MPa 条件下， 反应 16.0h， 生成 3-ethyl-7,11-dimethyl-dodecan-1-ol
  参考文献：
  名称：

  [EN] SPECIFIC POLYBRANCHED ALDEHYDES, ALCOHOLS SURFACTANTS AND CONSUMER PRODUCTS BASED THEREON
  [FR] ALDÉHYDES RAMIFIÉS SPÉCIFIQUES ALCOOLS, TENSIOACTIFS ET PRODUITS DE CONSOMMATION À BASE DE CEUX-CI

  摘要：

  公开号：

  WO2010033976A3

文献信息

• METHOD FOR THE HYDROFORMYLATION OF 2-SUBSTITUTED BUTADIENES AND THE PRODUCTION OF SECONDARY PRODUCTS THEREOF, ESPECIALLY AMBROX
  申请人：BASF SE

  公开号：US20180273458A1

  公开（公告）日：2018-09-27

  The present invention relates to a method for the regioselective hydroformylation of polyunsaturated acyclic hydrocarbons, which are 1, 3 butadienes, which, in the 2 position, bear a saturated or monounsaturated or polyunsaturated acyclic hydrocarbon radical. The present invention also relates to the production of secondary products of these hydroformylation products, especially of ambrox.

  本发明涉及一种用于对多不饱和非环烃进行区域选择性氢甲酰化的方法，这些非环烃是1,3-丁二烯，在2位上带有饱和、单不饱和或多不饱和非环烃基团。本发明还涉及这些氢甲酰化产物的次级产物的生产，特别是龙涎香。
• Specific polybranched surfactants and consumer products based thereon
  申请人：The Procter & Gamble Company

  公开号：EP2650280A1

  公开（公告）日：2013-10-16

  A process for preparing a detergent alcohol mixture comprising the steps of providing one or more poly-branched poly-olefins, wherein the poly-branched poly-olefins must contain one non-branched terminal olefin and one or more additional branched olefins in the molecule; hydroformylating said poly-branched poly-olefins to produce a poly-branched olefin containing aldehyde product with one or more olefins or mixture thereof; reducing the aldehyde product of step (b) in the presence of hydrogen and a hydrogenation catalyst to form a poly-branched detergent alcohol mixture; and removing said poly-branched alcohol mixture from said catalyst and branched aldehydes, alcohols and surfactants produced from the products of this process.

  一种制备洗涤剂醇混合物的工艺，包括以下步骤 提供一种或多种多支链聚烯烃，其中多支链聚烯烃分子中必须含有一种非支链末端烯烃和一种或多种额外的支链烯烃； 使所述多支链聚烯烃加氢甲酰化，生成含有一种或多种烯烃或其混合物的多支链烯烃醛产物；在氢气和氢化催化剂存在下还原步骤(b)的醛产物，形成多支链洗涤剂醇混合物；从所述催化剂和由该工艺产物产生的支链醛、醇和表面活性剂中除去所述多支链醇混合物。
• Specific polybranched alcohols and consumer products based thereon
  申请人：The Procter & Gamble Company

  公开号：EP2650275A1

  公开（公告）日：2013-10-16

  A detergent alcohol composition comprising at least one acyclic alcohol having 11, 16, or 21 carbon atoms, also comprising at least three branches wherein the branches are methyl, ethyl or mixtures thereof wherein the alcohol is obtainable from a starting polybranched polyolefin selected from the group consisting of: a. natural derived famesene extracted from pre-existing plants and organisms; b. famesene obtained via genetically modified organisms; c. synthetically derived trimers of isoprene; and d. mixtures thereof.

  一种洗涤醇组合物，包含至少一种具有 11、16 或 21 个碳原子的无环醇，还包含至少三个分支 其中支链为甲基、乙基或其混合物 其中，该醇可从选自以下组别的起始多支链聚烯烃中获得 a. 从现有植物和生物中提取的天然法墨烯； b. 通过转基因生物获得的法墨烯 c. 人工合成的异戊二烯三聚体；以及 d. 它们的混合物。
• Method for the hydroformylation of 2-substituted butadienes and the production of secondary products thereof, especially ambrox
  申请人：BASF SE

  公开号：US10315975B2

  公开（公告）日：2019-06-11

  The present invention relates to a method for the regioselective hydroformylation of polyunsaturated acyclic hydrocarbons, which are 1, 3 butadienes, which, in the 2 position, bear a saturated or monounsaturated or polyunsaturated acyclic hydrocarbon radical. The present invention also relates to the production of secondary products of these hydroformylation products, especially of ambrox.

  本发明涉及一种对多不饱和无环烃进行区域选择性加氢甲酰化的方法，这些多不饱和无环烃是 1, 3 丁二烯，在 2 位上带有饱和或单不饱和或多不饱和无环烃基。本发明还涉及这些加氢甲酰化产物，特别是氨溴索的次级产品的生产。
• SPECIFIC BRANCHED ALDEHYDES, ALCOHOLS, SURFACTANTS AND CONSUMER PRODUCTS BASED THEREON
  申请人：The Procter & Gamble Company

  公开号：EP2328856A2

  公开（公告）日：2011-06-08