(E,Z)-6,8-tetradecadiene | 72858-65-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: (E,Z)-6,8-tetradecadiene
• 英文别名: (6Z,8E)-tetradeca-6,8-diene
• CAS: 72858-65-2
• 化学式: C₁₄H₂₆
• 分子量: 194.36
• InChiKey: MQFIWEBAWCLIQO-HEEUSZRZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E,Z)-6,8-tetradecadiene 、 甲醇 、 臭氧 、 乙酸酐 、 三乙胺 生成 己酸甲酯
  参考文献：
  名称：

  WANG, ZHAOYIN;ZVILICHOVSKY, GURY, TETRAHEDRON LETT., 31,(1990) N9, C. 5579-5582

  摘要：

  DOI：
• 作为产物：
  描述：

  (2R,5R)-2,5-Dipentyl-2,5-dihydro-thiophene 1,1-dioxide 以84%的产率得到
  参考文献：
  名称：

  CHOU TA-SHUE; YOU MEI-LI, J. ORG. CHEM., 52,(1987) N 11, 2224-2226

  摘要：

  DOI：

文献信息

• Nickel-Catalyzed Electrochemical Couplings of Vinyl Halides:  Synthetic and Stereochemical Aspects
  作者：C. Cannes、S. Condon、M. Durandetti、J. Périchon、J.-Y. Nédélec

  DOI：10.1021/jo000182f

  日期：2000.7.1

  Homo- and cross-coupling involving alkenyl halides have been performed efficiently using an electroassisted nickel-complex catalysis. Valuable product such as conjugated dienes, beta,gamma- or gamma,delta-unsaturated esters, ketones, or nitriles, as well as alkenylated aryl compounds are thus prepared with high yields and high stereoselectivity. Partial isomerization is only observed in a few cases, when the alkenyl halide is involved in a late step of the catalytic cycle. This is the case in the preparation of (Z,Z)-1,3-diene.
• Highly Stereoselective Hydrocarbation of Terminal Alkynes via Pt-Catalyzed Hydrosilylation/Pd-Catalyzed Cross-Coupling Reactions
  作者：Scott E. Denmark、Zhigang Wang

  DOI：10.1021/ol0156751

  日期：2001.4.1

  [GRAPHICS]The formal addition of an aryl-H or alkenyl-H bond across a terminal alkyne has been accomplished by the combination of platinum-catalyzed hydrosilylation followed by palladium-catalyzed cross-coupling, The use of the t-Bu3P-Pt(DVDS) catalyst in combination with tetramethyldisiloxane gave excellent regio- and stereoselectivity with a number of alkyne substrates, Subsequent, fluoride-promoted cross-coupling proceeded in high yield and stereospecificity for a variety of aryl halides.
• Palladium-catalyzed and organozinc-promoted synthesis of dienes from allylic esters possessing an acyloxy or alkoxy group
  作者：Hatsuhiko Hattori、Masahiro Katsukawa、Yuichi Kobayashi

  DOI：10.1016/j.tetlet.2005.06.146

  日期：2005.8

  Organozinc and a Pd catalyst promoted formation of dienes from allylic esters possessing a leaving group such as acyloxy and alkoxy groups next to the allyl moiety. The reaction proceeded with high regio- and stereoselectivity when applied to secondary allylic substrates. (c) 2005 Elsevier Ltd. All rights reserved.
• Ultrasonically dispersed potassium in organic synthesis. Reactions with unsaturated cyclic sulfones
  作者：Ta Shue Chou、Mei Li You

  DOI：10.1021/jo00387a022

  日期：1987.5