Gallium-Yttrium | 12160-65-5

• 分子结构分类: 有机化合物
• 英文名称: Gallium-Yttrium
• 英文别名: yttrium-gallium；Gallium--yttrium (1/1)；gallane;yttrium
• CAS: 12160-65-5
• 化学式: GaY
• 分子量: 158.629
• InChiKey: WSRFNIFADKLLHM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.19
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氢化镓 、 氢化钇 以 melt 为溶剂， 生成 Gallium-Yttrium
  参考文献：
  名称：

  Synthesis, structures and properties of CaGa, YGa and Y(Ga,Z) phases: a model for the transformation of a CrB to a MoB-type structure in doped YGa phases

  摘要：

  RGa compounds for R=Ca, Y and Y(Ga(1-x)Z(x)) for Z=Cu or Zn have been synthesized by either are-melting or direct reactions in sealed Ta containers. The CrB structures of the binary phases have been identified by Guinier powder diffraction, and the MoB-type structure of the new ternary line phase Y(Ga0.8Zn0.2) has been refined by single crystal means: 14(1)/amd, Z=8, a=4.1787(5), c=21.856(4) Angstrom, R(F)/R-w = 3.8/2.7%. A comparable compound is obtained for YGa0.8Cu0.2, but not for Z=Cd or for RGa(Zn) with R=Tb or Er. Resistivity and magnetic susceptibility measurements on the CrB-type CaGa and YGa demonstrate their metallic properties and the non-applicability of a literal Zintl phase assignment of oxidation states to the latter. A qualitative bonding model is developed for the transformation of CrB-type YGa into the MoB structure of Y(Ga0.8Zn0.2) in terms of interchain sigma* interactions of the pi-states on the separate chains. (C) 2002 Elsevier Science BY All rights reserved.

  DOI：

  10.1016/s0925-8388(01)01784-4

文献信息

• Standard enthalpies of formation of yttrium gallides by high temperature reaction calorimetry
  作者：R Babu、K Nagarajan、V Venugopal

  DOI：10.1016/s0925-8388(00)01132-4

  日期：2000.10

  The standard enthalpies of formation (Delta(f)H(298.15)(0)) of Y5Ga3, YGa and YGa2 at 298.15 were determined by high temperature liquid gallium solution calorimetry to be -59.6+/-3.6, -68.9+/-2.8 and -64.4+/-2.5 kJ gatom(-1) respectively. The enthalpy of formation of YGa2 at 1125 K was determined by using precipitation calorimetry, to be -61.8+/-2.8. The partial enthalpy of solution of yttrium in liquid gallium at infinite dilution (Delta (H) over bar(y)(x)) was determined to be -184.4+/-5.3 kJ gatom(-1). (C) 2000 Elsevier Science S.A. All rights reserved.
• The Y–Ag–Ga system
  作者：T. Krachan、B. Stel’makhovych、Yu. Kuz’ma

  DOI：10.1016/j.jallcom.2004.05.053

  日期：2005.1

  The isothermal section at 670 K of the Y-Ag-Ga system in the region of 0-33 at.% Y has been constructed using X-ray diffraction data. The existence of earlier known ternary gallides has been confirmed. Their homogeneity regions, atomic coordinates and distribution of atoms in the structures have been determined: Y3Ag2.55Ga8.45 (La3Al11-type structure, a = 0.4310(1) nm, b = 1.2865(3) nm, c = 0.9552(3) nm, R-F = 0.043), YAg0.22Ga1.78 (CaIn2-type structure, a = 0.44565(1) nm, c = 0.72032(2) nm, R-1 = 0.081), YAg0.74Ga1.26 (KHg3-type structure, a = 0.45302(2) nm, b = 0.70805(3) nm, c = 0.78056(3) nm, R-1 = 0.059). The crystal structure of the new ternary compound YAg1.1Ga1.9 (beta-YbAgGa2-type structure, Pnma, a = 0.69654(3) nm, b = 0.43391(2) nm, c = 1.02126(5) nm, R-1 = 0.087) has been studied for the first time. (C) 2004 Elsevier B.V. All rights reserved.
• Enthalpies of formation of some GaY intermetallic compounds
  作者：P. Merker

  DOI：10.1016/0022-5088(91)90065-c

  日期：1991.5