O-acetyl-α-elemolic acid | 98166-55-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: O-acetyl-α-elemolic acid
• 英文别名: O-Acetyl-α-elemolsaeure；(2S)-2-[(3R,5R,9R,10R,13S,14S,17S)-3-acetyloxy-4,4,10,13,14-pentamethyl-2,3,5,6,9,11,12,15,16,17-decahydro-1H-cyclopenta[a]phenanthren-17-yl]-6-methylhept-5-enoic acid
• CAS: 98166-55-3
• 化学式: C₃₂H₅₀O₄
• 分子量: 498.747
• InChiKey: OCCMMQNWHUARRP-PFTIPHQLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  36
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

上下游信息

• 上游原料

  中文名称	英文名称	CAS号	化学式	分子量
  ——	3α-hydroxytirucalla-7,24-dien-21-oic acid	82509-40-8	C30H48O3	456.709

反应信息

• 作为反应物：
  描述：

  O-acetyl-α-elemolic acid 在 溶剂黄146 、 铂 作用下， 生成 Acetoxy-dihydro-'α-elemolsaeure'
  参考文献：
  名称：

  Zur Kenntnis der Triterpene。（68.米特隆）。üα-Elemolsäure

  摘要：

  DOI：

  10.1002/hlca.19420250626
• 作为产物：
  描述：

  3α-hydroxytirucalla-7,24-dien-21-oic acid 、 乙酸酐 在 吡啶 作用下， 生成 O-acetyl-α-elemolic acid
  参考文献：
  名称：

  Über die Elemisäure aus Manila-Elemiharz

  摘要：

  DOI：

  10.1007/bf01532293

文献信息

• Zur Kenntnis der Triterpene. (68. Mitteilung). �ber die ?-Elemols�ure
  作者：L. Ruzicka、Ed. Rey、M. Spillmann

  DOI：10.1002/hlca.19420250626

  日期：1942.10.15
• Mladenovic, Monatshefte fur Chemie, 1932, vol. 59, p. 228,232
  作者：Mladenovic

  DOI：——

  日期：——
• 844. The chemistry of the triterpenes and related compounds. Part XXI. Some aspects of the chemistry of the elemi acids
  作者：T. G. Halsall、G. D. Meakins、R. E. H. Swayne

  DOI：10.1039/jr9530004139

  日期：——
• Photo- and roentgenoluminescence of ZnSe
  作者：V. Ya. Degoda、B. R. Kiyak、V. S. Manzhara、V. E. Rodionov、A. I. Proskura

  DOI：10.1007/bf02758061

  日期：2000.5

  The photoluminescence (PL), roentgenoluminescence (RL), and optical absorption of ZnSe were measured near the fundamental edge in the temperature range from 80 to 400 K. Because of the much smaller absorption coefficient for x-rays as compared to visible light, the contribution to RL from emitting centers located deeper in the sample is higher. The quality of ZnSe can be assessed by correlating its near-edge PL and RL spectra. The temperature dependences of the peak positions of the blue PL and RL bands indicate that these emissions are due to the same center. The blue RL band is redshifted by 18 meV in comparison with Pt,, and its intensity is lower than that of the longer wavelength bands. The different positions of the PL and RL bands are interpreted in terms of thermal spike formation under x-ray excitation and reabsorption of the emitted light.
• Über die Elemisäure aus Manila-Elemiharz
  作者：Hans Lieb、Miloš Mladenović

  DOI：10.1007/bf01532293

  日期：1931.12