(3R,3aR,5aS,7aR,8S,11aS,13aS,13bR)-3-Isopropyl-3a,5a,8,11a,13a-pentamethyl-6,12-dioxo-2,3,3a,4,5,5a,6,7,7a,8,9,10,11,11a,12,13,13a,13b-octadecahydro-1H-cyclopenta[a]chrysene-8-carboxylic acid methyl ester | 5132-62-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (3R,3aR,5aS,7aR,8S,11aS,13aS,13bR)-3-Isopropyl-3a,5a,8,11a,13a-pentamethyl-6,12-dioxo-2,3,3a,4,5,5a,6,7,7a,8,9,10,11,11a,12,13,13a,13b-octadecahydro-1H-cyclopenta[a]chrysene-8-carboxylic acid methyl ester
• CAS: 5132-62-7
• 化学式: C₃₁H₄₆O₄
• 分子量: 482.704
• InChiKey: HTDMAJWWEUYRTF-FDEHVSPNSA-N

反应信息

• 作为反应物：
  描述：

  (3R,3aR,5aS,7aR,8S,11aS,13aS,13bR)-3-Isopropyl-3a,5a,8,11a,13a-pentamethyl-6,12-dioxo-2,3,3a,4,5,5a,6,7,7a,8,9,10,11,11a,12,13,13a,13b-octadecahydro-1H-cyclopenta[a]chrysene-8-carboxylic acid methyl ester 在 selenium(IV) oxide 、 乙酸酐 、 溶剂黄146 作用下， 生成 (3R,3aR,5aS,8S,11aS,13aS,13bR)-3-Isopropyl-3a,5a,8,11a,13a-pentamethyl-6,12,13-trioxo-2,3,3a,4,5,5a,6,8,9,10,11,11a,12,13,13a,13b-hexadecahydro-1H-cyclopenta[a]chrysene-8-carboxylic acid methyl ester
  参考文献：
  名称：

  The Structure of Davallic Acid

  摘要：

  The structure of davallic acid has been estabished as shown by I on the basis of chemical reactions and various physico-chemical data. The structure has received support from independent studies.

  DOI：

  10.1248/cpb.13.986
• 作为产物：
  描述：

  Methyl-isodavallat-I 在 chromium(VI) oxide 、 溶剂黄146 作用下， 生成 (3R,3aR,5aS,7aR,8S,11aS,13aS,13bR)-3-Isopropyl-3a,5a,8,11a,13a-pentamethyl-6,12-dioxo-2,3,3a,4,5,5a,6,7,7a,8,9,10,11,11a,12,13,13a,13b-octadecahydro-1H-cyclopenta[a]chrysene-8-carboxylic acid methyl ester
  参考文献：
  名称：

  The Structure of Davallic Acid

  摘要：

  The structure of davallic acid has been estabished as shown by I on the basis of chemical reactions and various physico-chemical data. The structure has received support from independent studies.

  DOI：

  10.1248/cpb.13.986