4-甲基丙烯酰氨基苯磺酰胺 | 56992-87-1

• 物质功能分类: 有机原料 - 氨基化合物 - 酰胺类化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-甲基丙烯酰氨基苯磺酰胺
• 英文名称: N-[4-sulfonamidophenyl]methacrylamide
• 英文别名: 4-sulfamoylphenylmethacrylamide；N-<4-(Sulfamoyl)-phenyl>-methacrylamid；N-(p-aminosulfonylphenyl)-methacrylamide；N-(4-sulfamoylphenyl)methacrylamide；N-(p-aminosulfonylphenyl)methacrylamide；2-methyl-N-(4-sulfamoylphenyl)prop-2-enamide
• CAS: 56992-87-1
• 化学式: C₁₀H₁₂N₂O₃S
• 分子量: 240.283
• InChiKey: NQRAOOGLFRBSHM-UHFFFAOYSA-N

物化性质

• 密度：
  1.339±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  97.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  磺胺 、 甲基丙烯酸甲酯 在 吡啶 、 aluminum (III) chloride 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 2.0h， 以93.5%的产率得到4-甲基丙烯酰氨基苯磺酰胺
  参考文献：
  名称：

  一种N-[4-(磺酰胺)苯基]甲基丙烯酰胺的合成方法

  摘要：

  本发明涉及有机化学合成领域，公开了一种N‑[4‑(磺酰胺)苯基]甲基丙烯酰胺的合成方法，其以甲基丙烯酸酯、4‑氨基苯磺酰胺为原料，选乙醇、四氢呋喃、丙酮、丁酮、N,N‑二甲基甲酰胺、二甲亚砜、N,N‑二甲基乙酰胺等有机溶液为反应体系，加无水氯化铝作催化剂，三乙胺或吡啶作助催化剂，在20～100℃下反应2～6小时，合成N‑[4‑(磺酰胺)苯基]甲基丙烯酰胺，通过IR、1HNMR对产物结构进行了确认。本发明反应条件温和、后处理简单，产品收率和纯度高，适于工业化生产。

  公开号：

  CN109608367A

文献信息

• [EN] POLYMERIZABLE COMPOUNDS WITH QUADRUPLE HYDROGEN BOND FORMING GROUPS<br/>[FR] COMPOSES POLYMERISABLES AVEC GROUPES FORMANT DES LIAISONS HYDROGENE QUADRUPLES
  申请人：KODAK POLYCHROME GRAPHICS LLC

  公开号：WO2004043935A1

  公开（公告）日：2004-05-27

  QHB-Modified free radical polymerizable compounds and free radical polymerizable compositions that comprise these compounds are disclosed. A QBH-modified free radical polymerizable compound has at least one moiety that comprises at least one free radical polymerizable group; a supporting backbone, and at least one and preferably at least two moieties capable of forming four or more, typically four, hydrogen bonds with similar or complementary units on other molecules or portions of molecules. Free radical polymerizable compositions that contain these compounds may be used in any of the well-knows applications for free radical polymerizable compositions. They are especially useful for the formation of imageable elements useful as lithographic printing plate precursors.

  修改后的自由基可聚合化合物和包含这些化合物的自由基可聚合化组合物已被披露。一种QBH修饰的自由基可聚合化合物至少具有一个包含至少一个自由基可聚合基团的基团；一个支撑骨架，以及至少一个并且最好至少两个能够与其他分子或分子部分上的类似或互补单元形成四个或更多，通常为四个，氢键的基团。包含这些化合物的自由基可聚合化组合物可用于任何已知的自由基可聚合化组合物的应用中。它们特别适用于形成可用作平版印刷版前体的可成像元素。
• Image forming material and ammonium compound
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030143481A1

  公开（公告）日：2003-07-31

  An image forming material includes an image forming layer containing a water-insoluble and alkali-soluble resin, a light-heat converting agent and a compound represented by the following general formula (1). In general formula (1), R 1 to R 3 independently represent an organic group, where R 1 represents a residue forming a ring containing a N 1 atom, R 2 and R 3 may bond to each other to form a ring or at least one of R 2 and R 3 may bond to R 1 to form a ring and X − represents a conjugate base of an organic acid or inorganic acid. The ring containing the N 1 atom is preferably a piperidine ring. 1

  一种图像形成材料包括一个图像形成层，其中包含一种水不溶性且碱溶性的树脂、一种光热转换剂和一种由下列通式（1）表示的化合物。在通式（1）中，R1到R3独立地表示有机基团，其中R1表示形成一个含有N1原子的环的残基，R2和R3可以结合形成一个环，或者R2和R3中至少一个可以与R1结合形成一个环，X-表示有机酸或无机酸的共轭碱基。含有N1原子的环最好是吡啶环。
• Image-formation material and infrared absorber
  申请人：——

  公开号：US20020015911A1

  公开（公告）日：2002-02-07

  A heat mode-applicable image-formation material having high sensitivity and excellent image-forming property, and a novel infrared absorber which can be suitably used in this material. The present invention relates to a substrate carrying thereon an image-formation layer which contains an infrared absorption agent. The agent has at least one surface orientation group in the molecule, and solubility of the image-formation layer in an alkaline aqueous solution is changed by action of radiation in the near-infrared range. Preferable as the infrared absorbing agent is an infrared absorber comprising, in a molecule thereof, a fluorine-containing substituent which have at least 5 fluorine atoms, or a polymethine chain of at least 5 carbon atoms and an alkyl group of at least 8 carbon atoms, said alkyl group being connected to the polymethine chain via any of nitrogen, oxygen and sulfur.

  一种适用于热模式的高灵敏度和优异成像性能的图像形成材料，以及一种新型红外吸收剂，可适当地用于该材料中。本发明涉及一种携带有图像形成层的基板，该层含有红外吸收剂。该剂分子中至少有一个表面取向基团，并且通过近红外范围的辐射作用，可以改变碱性水溶液中图像形成层的溶解度。作为红外吸收剂，最好选用含有至少5个氟原子的含氟取代基或至少5个碳原子的聚甲烷链和至少8个碳原子的烷基，所述烷基通过氮、氧和硫中的任何一种与聚甲烷链连接。
• [EN] INFRARED ABSORBING COMPOUNDS AND THEIR USE IN IMAGEABLE ELEMENTS<br/>[FR] COMPOSES ABSORBEURS D'UV ET LEUR UTILISATION DANS DES ELEMENTS IMAGEABLES
  申请人：KODAK POLYCHROME GRAPHICS LLC

  公开号：WO2004069938A1

  公开（公告）日：2004-08-19

  Infrared absorbing compounds in which both the anion and the cation absorb infrared radiation, imageable elements that contain these compounds, and methods for forming images using the imageable elements are disclosed. The compounds have the structure (I) and (II) in which Y1 and Y2 are each independently hydrogen, halo, alkyl, diphenylamino, or phenylthio; R1, R2, R3 and R4 are each independently hydrogen, methyl, or SO3-, with the proviso that two fo R1, R2, R3, and R4 are SO3-; R5 and R6 are each independently an alkyl group; Z1, Z2, Z4 and Z5 are each independently a benzo group or a nophtho group; Z3 and Z6 are each independently two hydrogen atoms, a cyclohexene residue, or a cyclopentene residue; X1, X2, X3, and X4 are each independently S, O, NH, CH2, or C(CH3)2; and n1 and n2 are each independently 0 to 4.

  本发明涉及吸收红外辐射的化合物，其中阴离子和阳离子均吸收红外辐射，包含这些化合物的可成像元素以及使用可成像元素形成图像的方法。化合物具有结构（I）和（II），其中Y1和Y2分别独立地为氢、卤素、烷基、二苯胺或苯硫醚；R1、R2、R3和R4分别独立地为氢、甲基或SO3-，但其中两个为SO3-；R5和R6分别独立地为烷基；Z1、Z2、Z4和Z5分别独立地为苯并环或萘并环；Z3和Z6分别独立地为两个氢原子、环己烯残基或环戊烯残基；X1、X2、X3和X4分别独立地为S、O、NH、CH2或C（CH3）2；n1和n2分别独立地为0至4。
• Method for replenishing development replenisher in automatic developing machine for photosensitive lithographic printing plate
  申请人：Takamiya Shuichi

  公开号：US20050238349A1

  公开（公告）日：2005-10-27

  The electric conductivity of the developer is measured in a constant cycle and after replenishing the aging replenishment amount setting value at constant time intervals and replenishing the processing replenishment amount setting value every each processing of plates in a fixed area by using a development replenisher containing an electric conductivity adjusting agent of elevating the electric conductivity, the electric conductivity calculated value is calculated from the aging replenishment amount and the processing replenishment amount and based on the results of comparison between the electric conductivity calculated value and the electric conductivity measured value, the values of aging replenishment amount setting value and processing replenishment amount setting value each is increased or decreased.

  开发剂的电导率是在恒定的周期内测量的，每隔一定时间间隔补充老化补给量设定值，并使用含有提高电导率的电导率调节剂的开发补充剂，在固定区域内处理每个版的处理补给量设定值，从老化补给量和处理补给量计算出电导率计算值，并根据电导率计算值和电导率测量值之间的比较结果，增加或减少老化补给量设定值和处理补给量设定值的值。