(E)-1-Iodo-2-dodecen | 94400-36-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: (E)-1-Iodo-2-dodecen
• 英文别名: (E)-1-iodododec-2-ene
• CAS: 94400-36-9
• 化学式: C₁₂H₂₃I
• 分子量: 294.219
• InChiKey: WXIPEPMRHITCKV-ZHACJKMWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-1-Iodo-2-dodecen 在 samarium diiodide 、 重水 作用下， 生成 3-deutero-1-dodecen 、 (2E) 1-deutero-2-dodecen
  参考文献：
  名称：

  Organosamariums: preparation using diiodosamarium and reactivity in tetrahydropyran

  摘要：

  Diiodosamarium prepared in tetrahydropyran reduces allylic, benzylic and alkyl halides at 0 or -15 degrees C to give organosamariums which are stable under these conditions. The reactivity of these organometallics has been explored, showing that they are very selective reagents. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00666-4
• 作为产物：
  描述：

  十二碳烯-3-醇 在 magnesium iodide 作用下， 以 苯 为溶剂， 反应 5.0h， 生成 (Z)-1-Iodo-2-dodecen 、 (E)-1-Iodo-2-dodecen
  参考文献：
  名称：

  Regiospezifische Herstellung von primären Allylacetaten (2-Alkenyl-acetaten)

  摘要：

  一级烯丙基乙酸酯（2-烯基乙酸酯）的区域特异性制备方法： 一级、二级和三级烯丙醇1与无水碘化镁在苯中反应，区域特异性生成一级烯丙基碘2。通过2与无水醋酸钠在二甲基甲酰胺中的反应，可以同样区域特异性地获得相应的一级烯丙基乙酸酯3。

  DOI：

  10.1055/s-1988-27464

文献信息

• Generation and reactivity of allylic and benzylic samarium compounds using diiodosamarium in tetrahydropyran
  作者：Béatrice Hamann-Gaudinet、Jean-Louis Namy、Henri B. Kagan

  DOI：10.1016/s0040-4039(97)01506-2

  日期：1997.9

  Diiodosamarium prepared in THP reduces allylic iodides and bromides at 0 or -15 degrees C to give organosamarium compounds which are stable under these conditions. These allylic samarium compounds react with many functionalities including the keto group of keto esters. Benzylic samarium compounds were prepared similarly from benzylic bromides. (C) 1997 Elsevier Science Ltd.
• Garcia Martinezi, Antonio; Oliver Ruiz, Manuel, Synthesis, 1984, # 7, p. 608 - 610
  作者：Garcia Martinezi, Antonio、Oliver Ruiz, Manuel

  DOI：——

  日期：——
• [EN] COPOLYMERS OF ETHYLENE AND/OR alpha-OLEFINS AND VICINALLY DISUBSTITUTED OLEFINS<br/>[FR] COPOLYMERES D'ETHYLENE ET/OU D'ALPHA-OLEFINES ET OLEFINES A DISUBSTITUTION VICINALE
  申请人：EXXONMOBIL CHEM PATENTS INC

  公开号：WO2004106394A1

  公开（公告）日：2004-12-09

  Substantially random ethylene and/or α-olefin copolymers containing units derived from vicinally disubstituted olefin monomers are described. The vicinally disubstituted olefin monomers may be represented by the generic formula (R1)CH=CH(R2), where R1 and R2 independently comprise hydrocarbyl or silyl-hydrocarbyl groups containing 1 or more carbon atoms, or may be linear, branched or cyclic substituted or unsubstituted hydrocarbyl groups having from 1-100 carbon atoms, or they may contain 30 or less carbon atoms. The copolymers may be prepared by coordination polymerization by means of contacting at least one vicinally disubstituted olefin monomer and ethylene and/or α-olefin, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl heteroatom-containing Group 4 transition metal catalyst component.