copper(II) tartrate trihydrate | 815-82-7

• 物质功能分类: 有机原料 - 有机金属盐
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: copper(II) tartrate trihydrate
• 英文别名: copper tartrate trihydrate；Copper(II) tartrate hydrate；copper;2,3-dihydroxybutanedioate;hydrate
• CAS: 815-82-7；17263-56-8
• 化学式: C₄H₄O₆*Cu*3H₂O
• 分子量: 265.664
• InChiKey: MAUZTCHAIPUZJB-UHFFFAOYSA-L

物化性质

• 熔点：
  ~275 °C (dec.)(lit.)
• 物理描述：
  Cupric tartrate appears as a green to blue odorless powder. Insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is noncombustible. Used for electroplating metals.
• 颜色/状态：
  LIGHT BLUE POWDER
• 沸点：
  Trihydrate decomposes on heating (USCG, 1999)
• 密度：
  greater than 1 (USCG, 1999)

计算性质

• 辛醇/水分配系数(LogP)：
  -5.62
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  122
• 氢给体数：
  3
• 氢受体数：
  7

ADMET

毒理性

• 人类毒性摘录

症状学：迅速呕吐（通常在摄入后5到10分钟内）。口腔、食道和胃部有灼痛感。口腔中有金属味。腹泻，可能伴有腹痛。便便中有黑色或隐血。头痛、冷汗、脉搏弱和其它休克的迹象。

SYMPTOMATOLOGY: PROMPT EMESIS (USUALLY WITHIN 5 TO 10 MIN /AFTER INGESTION/). ... BURNING PAIN IN MOUTH, ESOPHAGUS, & STOMACH. METALLIC TASTE IN MOUTH. DIARRHEA WITH OR WITHOUT COLICKY ABDOMINAL PAIN ... MELENA OR OCCULT BLOOD IN FECES. ... HEADACHE, COLD SWEAT, WEAK PULSE & OTHER SIGNS OF SHOCK ... .

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 人类毒性摘录

黄疸...当严重时，通常是由于肝坏死伴肝肿大和疼痛。有时病变是进行性的。轻度黄疸可能是急性溶血危象的表现，但不伴随肝脏损伤。

JAUNDICE ... WHEN SEVERE, IT IS USUALLY DUE TO HEPATIC NECROSIS WITH SWOLLEN & PAINFUL LIVER. SOMETIMES LESION IS PROGRESSIVE. MILD JAUNDICE MAY EVIDENCE ACUTE HEMOLYTIC CRISIS WITHOUT LIVER INJURY.

来源:Hazardous Substances Data Bank (HSDB)

安全信息

• WGK Germany：
  3
• 危险品运输编号：
  UN 9111
• 安全说明：
  S24/25

制备方法与用途

用途 

在电镀槽中电镀铜。

反应信息

• 作为反应物：
  描述：

  copper(II) tartrate trihydrate 以 neat (no solvent) 为溶剂， 生成 copper(II) tartrate
  参考文献：
  名称：

  Ponizovskii; Studenikina; Mironenko, Russian Journal of Inorganic Chemistry, 1997, vol. 42, # 4, p. 558 - 563

  摘要：

  DOI：
• 作为产物：
  描述：

  copper(II) nitrate 、 酒石酸 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成 copper(II) tartrate trihydrate
  参考文献：
  名称：

  Singh, Mamta; Nayan, Ram, Journal of the Indian Chemical Society, 1998, vol. 75, # 1, p. 33 - 34

  摘要：

  DOI：
• 作为试剂：
  描述：

  (E)-1-((Z)-1,4-diphenylbut-3-en-1-ylidene)-2-phenylhydrazine 在 copper(II) tartrate trihydrate 、 氧气 作用下， 以 乙醇 为溶剂， 反应 20.0h， 以47%的产率得到5-Benzoyl-1.3-diphenyl-2-pyrazolin
  参考文献：
  名称：

  有氧条件下溶剂依赖性铜催化合成吡唑

  摘要：

  我们提出了利用分子氧作为化学计量的氧化剂的铜催化的小β，γ-不饱和的氧化环化。该方法只需更改反应溶剂即可提供不同种类的吡唑。三取代...

  DOI：

  10.1039/c6cc06935e

文献信息

• Spectral and Structural Studies of Transition Metal Complexes of 2-Pyridineformamide N(4)-ethylthiosemicarbazone
  作者：Elena Bermejo、Alfonso Casti�eiras、Isabel Garc�a-Santos、Larissa M. Fostiak、John K. Swearingen、Douglas X. West

  DOI：10.1002/zaac.200400345

  日期：2005.3

  The reduction of 2-cyanopyridine in the presence of N(4)-ethylthiosemicarbazide produces 2-pyridineformamide N(4)-ethylthiosemicarbazone, HAm4E. Complexes with cobalt(III), nickel(II), copper(II), palladium(II) and platinum(II) have been prepared and characterized by molar conductivity, magnetic susceptibility and spectroscopic techniques. In addition, the crystal structures of HAm4E, [Co(Am4E)2](ClO4)

  在 N(4)-乙基氨基硫脲存在下还原 2-氰基吡啶产生 2-吡啶甲酰胺 N(4)-乙基氨基硫脲，HAm4E。已经制备了钴 (III)、镍 (II)、铜 (II)、钯 (II) 和铂 (II) 的配合物，并通过摩尔电导率、磁化率和光谱技术对其进行了表征。此外，HAm4E、[Co(Am4E)2](ClO4)、[Ni(HAm4E)2]( )2 和 [Ni(HAm4E)2]Cl(OAc)·AcOH·H2O 的晶体结构获得。当分别作为中性或阴离子配体配位时，通过吡啶基氮、亚胺氮和硫酮或硫醇基硫原子发生配位。HAm4E 及其金属配合物中都存在广泛的氢键，其中酰胺氢原子是重要的贡献者。
• ——
  作者：I. I. Obraztsova、G. Yu. Simenyuk、N. K. Eremenko

  DOI：10.1023/a:1022277129015

  日期：——

  Ultradispersed powders of copper were obtained by reducing various copper salts with glycerol, and formulations on their base were prepared. The effect of various modifiers on the dispersity, stability, and electrical conductivity of copper powders was examined.
• Piria, R., Nuovo Cimento, 1855, vol. 1, p. 5 - 25
  作者：Piria, R.

  DOI：——

  日期：——
• ——
  作者：M. A Moustafa、Z. A. Omran、W. A. A. Bayoumy、M. A. Mousa

  DOI：10.1023/a:1010174828300

  日期：——

  The kinetic description and mechanism of the solid-state reactions between metal basic carbonate (M=Co2+, Cu2+ and Zn2+) and aliphatic carboxylic acids (oxalic, tartaric, succinic and citric acids) were studied using non-isothermal analysis (TG, DTA) and capillary techniques. The reactions were found to proceed in all cases (except citric acid) by one mole of metal carbonate and two moles of metal carbonate and two moles of organic acid. The kinetic analyses of non-isothermal data were best described by each of the dimensional phase boundary R-2 and two-dimensional diffusion controlled reactions D-2. While the capillary technique showed that the initial reaction occurs at the phase boundary of the reactants and kinetically of the reacting controlled by diffusion mechanism in which the diffusion species through the product layers are the organic acids.
• Electrochemical synthesis of copper(II) carboxylates
  作者：J.S. Banait、P.K. Pahil

  DOI：10.1016/s0277-5387(00)84076-0

  日期：1985.1