bornan-2-one semicarbazone | 4581-48-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: bornan-2-one semicarbazone
• 英文别名: (+/-)-bornanone-(2)-semicarbazone；(+/-)-Bornanon-(2)-semicarbazon；dl-Bornyl-semicarbazon；[[(1S,4S)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanylidene]amino]urea
• CAS: 4581-48-0；10281-41-1；72059-63-3；120522-07-8；121702-12-3；124815-32-3
• 化学式: C₁₁H₁₉N₃O
• 分子量: 209.291
• InChiKey: QCEFOIDJHJPYIB-WRWORJQWSA-N

物化性质

• 熔点：
  245 °C
• 密度：
  1.27±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  67.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bornan-2-one semicarbazone 在 potassium permanganate 、 silica gel 作用下， 以 水 为溶剂， 反应 0.5h， 以80%的产率得到左旋樟脑
  参考文献：
  名称：

  Wet Silica-Supported Permanganate for the Cleavage of Semicarbazones and Phenylhydrazones under Solvent-Free Conditions

  摘要：

  Wet silica-supported potassium permanganate was used as an inexpensive and efficient reagent for conversion of semicarbazones and phenylhydrazones to the corresponding carbonyl compounds under solid-state conditions.

  DOI：

  10.1021/jo034217y
• 作为产物：
  描述：

  左旋樟脑 生成 bornan-2-one semicarbazone
  参考文献：
  名称：

  Alder; Windemuth, Justus Liebigs Annalen der Chemie, 1940, vol. 543, p. 56,60, 67

  摘要：

  DOI：

文献信息

• SYNTHESIS, CHARACTERIZATION AND ANTIOXIDANT ACTIVITY OF SOME TRANSITION METAL COMPLEXES WITH TERPENOID DERIVATIVES
  作者：ALKA CHOUDHARY、RENU SHARMA、MEENA NAGAR、MOHAMMED MOHSIN、HAR SAHAY MEENA

  DOI：10.4067/s0717-97072011000400019

  日期：——

  A series of transition metal complexes of Fe(III), Co(II) and Cu(II) containing the bidentate N,O and N,S donor ligand, camphor semicarbazone (1,7,7-trimethylbicyclo [2,2,1]heptanesemicarbazone, TBHSC) and camphor thiosemicarbazone (1,7,7- trimethylbicyclo [2,2,1]heptanethiosemicarbazone, TBHTSC) have been synthesized and characterized by elemental analysis, molar conductance measurement and various spectral studies (IR, electronic and FAB Mass) and thermogravimetric analysis (TGA). All the metal complexes (1-8) are [M(LH)Cl-2] and [M(LH)(2)Cl-2] type, where M = Fe(III), Co(11) and Cu(II); LH = TBHSC and TBHTSC. TBHSC and TBHTSC act as neutral bidentate ligands in all the complexes. FAB mass spectroscopic studies of the three representative complexes (1), (2), (4), (5) and (8) suggest their monomeric nature. The proposed geometries of the complexes were octahedral geometry for 1:2 complexes, square planar for I:I complexes and distorted octahedral for Cu(II) complexes (1:2). The free radical scavenging activity of newly synthesized ligands (TBHSC, TBHTSC) and their metal complexes have been determined at the concentration range of 50-1000 mu g/ml by means of their interaction with the stable free radical 1,1-diphenyl-2-picrylhydrazyl (DPPH). All the compounds have shown encouraging antioxidant activities. The least IC50 value (111.0 mu g/ml) for compound (5) showed the potent scavenging property compared to other test compounds.
• Photolyse von 2-oxo-2,5-dihydro-1 ,3,4-oxadiazolen in gegenwart von olefinen
  作者：Dimitra Daniil、Herbert Meier

  DOI：10.1016/s0040-4039(01)83185-3

  日期：1977.1
• Baruah, Akashi; Nath, Utpal; Das, Satya Sandhya, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2006, vol. 45, # 9, p. 2157 - 2160
  作者：Baruah, Akashi、Nath, Utpal、Das, Satya Sandhya、Das, Pranab Jyoti

  DOI：——

  日期：——
• Sen, Journal of the Indian Chemical Society, 1935, vol. 12, p. 647,650
  作者：Sen

  DOI：——

  日期：——
• Paine,A.J.; Warkentin,J., Canadian Journal of Chemistry, 1979, vol. 57, p. 2681 - 2695
  作者：Paine,A.J.、Warkentin,J.

  DOI：——

  日期：——