2-Cyclohexene-1-methanol, 4-(1-methylethenyl)- | 58940-40-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-Cyclohexene-1-methanol, 4-(1-methylethenyl)-
• 英文别名: (4-prop-1-en-2-ylcyclohex-2-en-1-yl)methanol
• CAS: 58940-40-2
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: BJSHXSUMHHKJEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  cis-p-Menth-2,8-dienal 在 甲酸 、 iron(II) tetrafluoroborate hexahydrate 、 三[2-(二苯基磷)乙基]磷 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以99%的产率得到2-Cyclohexene-1-methanol, 4-(1-methylethenyl)-
  参考文献：
  名称：

  Fast and selective iron-catalyzed transfer hydrogenations of aldehydes

  摘要：

  An efficient iron-based catalyst system consisting of Fe(BF)(4)center dot 6H(2)O and P(CH2CH2PPh2)(3) [tetraphos, (PP3)] is presented for the highly selective transfer hydrogenation of aromatic, aliphatic, and alpha,beta-unsaturated aldehydes. A wide range of substrates including aldehydes with other reducible functional groups gave the corresponding alcohols in good yields. Formic acid is applied as a cheap, environmentally benign and easy to handle hydrogen source. Notable features of the presented methodology are the fast reactions under mild conditions. Advantageously compared to most transfer hydrogenations, no stoichiometric amounts of base additives are required. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.06.010