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羟乙酸镍 | 41587-84-2

中文名称
羟乙酸镍
中文别名
——
英文名称
Nickel hydroxyacetate
英文别名
2-hydroxyacetate;nickel(2+)
羟乙酸镍化学式
CAS
41587-84-2
化学式
C4H6NiO6
mdl
——
分子量
208.78
InChiKey
OZHLXQFAHIYYDJ-UHFFFAOYSA-L
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 稳定性/保质期:
    常规情况下不会分解,也没有任何危险反应。

计算性质

  • 辛醇/水分配系数(LogP):
    -4.55
  • 重原子数:
    11
  • 可旋转键数:
    0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.5
  • 拓扑面积:
    121
  • 氢给体数:
    2
  • 氢受体数:
    6

安全信息

  • 危险等级:
    9

SDS

SDS:c094f1ef4d7880e8803f4bff3d67ba41
查看

Section 1: Product Identification
Chemical Name: Nickel (II) hydroxyacetate
CAS Registry Number: 41587-84-2
Formula: Ni(OOCCH2OH)2
EINECS Number: None
Chemical Family: metal acetate salt
Synonym: Hydroxyacetic acid, nickel salt; glycolic acid, nickel salt.

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 41587-84-2 100% 0.1mg/m3 (as Ni) 1mg/m3 (as Ni)

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. May cause headaches, sore throat, shortness of breath and lung
Emergency Overview:
damage. May cause cancer.
Primary Routes of Exposure: Ingestion, inhalation of dust
Eye Contact: Causes irritation of the eyes, redness and pain.
Skin Contact: Causes irritation of the skin with redness or rash. Prolonged contact with nickel salts may lead to dermatitis.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Irritating to skin, eyes and respiratory tract. May cause intestinal disorders, convulsions, asphyxia,
Acute Health Affects:
sensitization dermatitis, allergic asthma and pneumonitis.
Prolonged exposure to nickel and nickel compounds may lead to skin irritation and dermatitis, and affect
Chronic Health Affects:
kidney, liver, and lung function. May cause cancer.
NTP: Yes
IARC: Yes
OSHA: No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form: green pwdr.
Molecular Weight: 208.75
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: no data
Odor: none
Solubility in Water: soluble

SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: none
Decomposition Products: nickel oxide.

SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: Carcinogen 9as Ni)
Mutagenic Effects: No data
Tetratogenic Effects: No data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound: See category code N495 for reporting.
Second Ingredient: None


SECTION 16 - ADDITIONAL INFORMATION
N/A

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